5-coordinate: square-based pyramid (SPY-5)

Attached groups:

NO (nitrosyl X)

Oep (octaethylporphyrin)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(NO)(Diars-κ²As)₂]²⊕

Formula Unicode styled:

[Fe(NO)(Diars-κ²As)₂]²⊕

Compound name(s):

Nitrosyl-(o-phenylenebis(dimethylarsine)) iron(2+)

Central atom:

Diars (1,2-bis-(dimethylarsino)benzene-κ²As)

Attached groups:

NO (nitrosyl, linear)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Fe«V⁵C⁵O^IE¹⁷B⁷X¹L⁵Z¹»^2⊕

[MLXZ]𝘲 class:

[MX₁L₅Z₁]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Fe(NO)([14]aneN₄-Me₄-κ⁴N)]⊕

Formula Unicode styled:

[Fe(NO)([14]aneN₄-Me₄-κ⁴N)]⊕

Compound name(s):

Nitrosyl-(1,4,8,11-tetramethyl-tetra-azacyclotetradecane)-iron(1+)

Central atom:

[14]aneN₄-Me₄ (tetramethyl-1,4,8,11-tetraazacyclotetradecane-κ⁴N)

Attached groups:

NO (nitrosyl, linear)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁴C⁵O^OE¹⁸B⁷X¹L⁵Z¹»^⊕

[MLXZ]𝘲 class:

[MX₁L₅Z₁]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Fe(NCS-κN)(Oep)]

Formula Unicode styled:

[Fe(NCS-κN)(Oep)]

Compound name(s):

Isothiocyanato-octaethylporphinato-pyridine-iron

Central atom:

Attached groups:

NCS (isothiocyanato-κN)

Oep (octaethylporphyrin)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(NCS-κN)(Dedtc)₂]

Formula Unicode styled:

[Fe(NCS-κN)(Dedtc)₂]

Compound name(s):

bis(N,N-Diethyldithiocarbamato)-(isothiocyanato)-iron

Central atom:

Dedtc (diethyldithiocarbamato-κ²S)

Attached groups:

NCS (isothiocyanato-κN)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(N₃)(Tpp)]

Formula Unicode styled:

[Fe(N₃)(Tpp)]

Compound name(s):

(Triazido-N)-(5,10,15,20-tetraphenylporphyrinato)-iron

Central atom:

Tpp (tetraphenylporphyrin)

Attached groups:

N₃ (azido)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(N₂)(Depe)₂]

Formula Unicode styled:

[Fe(N₂)(Depe)₂]

Compound name(s):

bis(1,2-bis(Diethylphosphino)ethane)-dinitrogen-iron

Central atom:

Depe (1,2-bis-(diethylphosphino)ethane)

Attached groups:

N₂ (dinitrogen)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Fe(I)(Tpp)]

Formula Unicode styled:

[Fe(I)(Tpp)]

Compound name(s):

Iodo-(meso-tetraphenyl-porphinato)-iron

Central atom:

Tpp (tetraphenylporphyrin)

Attached groups:

I (iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(I)(Pc)]

Formula Unicode styled:

[Fe(I)(Pc)]

Compound name(s):

Iodo-phthalocyaninato-iron

Central atom:

Attached groups:

I (iodo)

Pc (phthalocyaninato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(I)(Dedtc)₂]

Formula Unicode styled:

[Fe(I)(Dedtc)₂]

Compound name(s):

Iodo-bis(N,N-diethyldithiocarbamato)-iron

Central atom:

Dedtc (diethyldithiocarbamato-κ²S)

Attached groups:

I (iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(Dmdtc)₂(NO)]

Formula Unicode styled:

[Fe(Dmdtc)₂(NO)]

Compound name(s):

bis(N,N-Dimethyldithiocarbamato)-nitrosyl-iron

Central atom:

Dmdtc (dimethyldithiocarbamato-κ²S)

Attached groups:

NO (nitrosyl, linear)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Fe«V⁵C⁵O^IE¹⁷B⁷X³L³Z¹»

[MLXZ]𝘲 class:

[MX₃L₃Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Fe(CS)(Oep)]

Formula Unicode styled:

[Fe(CS)(Oep)]

Compound name(s):

Thiocarbonyl-(octaethylporphinato)-iron

Central atom:

Attached groups:

CS (thiocarbonyl)

Oep (octaethylporphyrin)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Fe«V²C⁵O^IIE¹⁶B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Fe(CO)₃{η⁴-C₆H₆CO}]

Formula Unicode styled:

[Fe(CO)₃{η⁴-C₆H₆CO}]

Compound name(s):

(η⁴-Tropone)-tricarbonyl-iron

Central atom:

Attached groups:

O=CC₆H₆ (η⁴-tropone)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Fe(CO)₃(η⁴-Cot)]

Formula Unicode styled:

[Fe(CO)₃(η⁴-Cot)]

Compound name(s):

(Cyclo-octatetraene)-tricarbonyl-iron

Central atom:

Attached groups:

Cot (η⁴-cyclooctatetraene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Fe(CO)₃(η⁴-Cod)]

Formula Unicode styled:

[Fe(CO)₃(η⁴-Cod)]

Compound name(s):

Tricarbonyl-(η⁴-1,5-cyclo-octadiene)-iron

Central atom:

Attached groups:

Cod (η²,η²-cycloocta-1,5-diene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Fe(CO)₃(η⁴-C₄H₆)]

Formula Unicode styled:

[Fe(CO)₃(η⁴-C₄H₆)]

Compound name(s):

Butadiene iron tricarbonyl

Central atom:

Attached groups:

C₄H₆ (η⁴-butadiene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Fe(CO)₃(C₆H₈)]

Formula Unicode styled:

[Fe(CO)₃(C₆H₈)]

Compound name(s):

(η⁴-1,3-Cyclohexadiene)-tricarbonyl-iron

Central atom:

Attached groups:

C₆H₈ (cyclohexadiene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Fe(CO)₂(PPh₃)(η⁴-Nbd)]

Formula Unicode styled:

[Fe(CO)₂(PPh₃)(η⁴-Nbd)]

Compound name(s):

(η⁴-Norbornadiene)-dicarbonyl-triphenylphosphine-iron

Central atom:

Attached groups:

PPh₃ (triphenylphosphane)

Nbd (η⁴-norbornadiene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Fe(CO)₂(PPh₃)(C₆H₈)]

Formula Unicode styled:

[Fe(CO)₂(PPh₃)(C₆H₈)]

Compound name(s):

(η⁴-Cyclohexadiene)-dicarbonyl-triphenylphosphine-iron

Central atom:

Attached groups:

PPh₃ (triphenylphosphane)

C₆H₈ (cyclohexadiene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Fe(CO)₂(NCEt)(C₆H₈)]

Formula Unicode styled:

[Fe(CO)₂(NCEt)(C₆H₈)]

Compound name(s):

(η⁴-Cyclohexa-1,3-diene)-dicarbonyl-ethylisonitrile-iron

Central atom:

Attached groups:

NCEt (ethylnitrile)

C₆H₈ (cyclohexadiene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: