5-coordinate: square-based pyramid (SPY-5)

Attached groups:

PPrⁱ₃ (triisopropylphosphane)

COPh (benzoyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

trans,trans–[Rh(Cl)₂(CF₂H)(PPh₃)₂]

Formula Unicode styled:

trans,trans–[Rh(Cl)₂(CF₂H)(PPh₃)₂]

Compound name(s):

Dichloro-difluoromethyl-bis(triphenylphosphine)-rhodium

Central atom:

Attached groups:

CF₂H (difluoromethyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

trans–[Rh(Cl)(H)(OSiEt₃)(PPh₃)₂]

Formula Unicode styled:

trans–[Rh(Cl)(H)(OSiEt₃)(PPh₃)₂]

Compound name(s):

Chloro-hydrido-triethoxysilyl-bis(triphenylphosphine)-rhodium

Central atom:

Attached groups:

H (hydrido)

OSiEt₃ (triethylsiloxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

trans–[Rh(C₆F₅)₃(PEt₃)₂]

Formula Unicode styled:

trans–[Rh(C₆F₅)₃(PEt₃)₂]

Compound name(s):

bis(Triethylphosphine)-tris(pentafluorophenyl)-rhodium

Central atom:

Attached groups:

C₆F₅ (pentafluorophenyl)

PEt₃ (triethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

trans–[Rh(C₆F₅)₃(AsPh₃)₂]

Formula Unicode styled:

trans–[Rh(C₆F₅)₃(AsPh₃)₂]

Compound name(s):

bis(Triphenylarsine)-tris(pentafluorophenyl)-rhodium

Central atom:

Attached groups:

C₆F₅ (pentafluorophenyl)

AsPh₃ (triphenylarsane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Rh(η⁴-C₄H₆)₂(PPrⁱ₃)]⊕

Formula Unicode styled:

[Rh(η⁴-C₄H₆)₂(PPrⁱ₃)]⊕

Compound name(s):

bis(η⁴--Butadiene)-tri-isopropylphosphine-rhodium(1+)

Central atom:

PPrⁱ₃ (triisopropylphosphane)

Attached groups:

C₄H₆ (η⁴-butadiene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X⁰L⁵»^⊕

[MLXZ]𝘲 class:

[ML₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Rh(SnCl₃)(Tpp)]

Formula Unicode styled:

[Rh(SnCl₃)(Tpp)]

Compound name(s):

(Tetraphenylporphyrinato)-(trichloro-tin)-rhodium

Central atom:

Tpp (tetraphenylporphyrin)

Attached groups:

SnCl₃ (trichlorostannyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Rh(SiEt₃)(Oep)]

Formula Unicode styled:

[Rh(SiEt₃)(Oep)]

Compound name(s):

Octaethylporphyrinato)-triethylsilyl-rhodium

Central atom:

Attached groups:

SiEt₃ (triethylsilyl)

Oep (octaethylporphyrin)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Rh(Ph)(Tpp)]

Formula Unicode styled:

[Rh(Ph)(Tpp)]

Compound name(s):

(5,10,15,20-Tetraphenylporphyrin)-phenyl-rhodium

Central atom:

Tpp (tetraphenylporphyrin)

Attached groups:

Ph (phenyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Rh(Me)(Tpp)]

Formula Unicode styled:

[Rh(Me)(Tpp)]

Compound name(s):

Methyl-(tetraphenylporphyrinato)-rhodium

Central atom:

Tpp (tetraphenylporphyrin)

Attached groups:

Me (methyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Rh(Me)(Oep)]

Formula Unicode styled:

[Rh(Me)(Oep)]

Compound name(s):

Octaethylporphinato-(methyl)-rhodium

Central atom:

Attached groups:

Me (methyl)

Oep (octaethylporphyrin)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Rh(CO₂Et)(Oep)]

Formula Unicode styled:

[Rh(CO₂Et)(Oep)]

Compound name(s):

Ethoxycarbonyl-octaethylporphyrinato-rhodium

Central atom:

Attached groups:

CO₂Et (ethoxycarbonyl)

Oep (octaethylporphyrin)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Rh(Cl)₂(CF₂H)(PPh₃)₂]

Formula Unicode styled:

[Rh(Cl)₂(CF₂H)(PPh₃)₂]

Compound name(s):

Dichloro-difluoromethyl-bis(triphenylphosphine)-rhodium

Central atom:

Attached groups:

CF₂H (difluoromethyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Rh(Cl)(CO)(PPh₃)₂(SO₂-κS)]

Formula Unicode styled:

[Rh(Cl)(CO)(PPh₃)₂(SO₂-κS)]

Compound name(s):

Chlorocarbonyl-(sulfur dioxide)-bis(triphenylphosphine) rhodium

Central atom:

Attached groups:

CO (carbonyl)

SO₂ (dioxo-sulfur-κS Z)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IE¹⁶B⁵X¹L³Z¹»

[MLXZ]𝘲 class:

[MX₁L₃Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Rh(Cl)(Bpy)(η⁴-Nbd)]

Formula Unicode styled:

[Rh(Cl)(Bpy)(η⁴-Nbd)]

Compound name(s):

(2,2'-Bipyridyl)-(η⁴--norbornadiene)-chloro-rhodium

Central atom:

Attached groups:

Bpy (bipyridine)

Nbd (η⁴-norbornadiene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

cis,cis–[Rh(COMe)(I)₂(Dppm-κ²P)]

Formula Unicode styled:

cis,cis–[Rh(COMe)(I)₂(Dppm-κ²P)]

Compound name(s):

Acetyl-bis(iodo)-(1,2-bis(diphenylphosphino)methane-P,P')-rhodium

Central atom:

Dppm (bis-(diphenylphosphino)methane-κ²P)

Attached groups:

COMe (acetyl)

I (iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

cis,cis–[Rh(COMe)(I)₂(Dppe-κ²P)]

Formula Unicode styled:

cis,cis–[Rh(COMe)(I)₂(Dppe-κ²P)]

Compound name(s):

Acetyl-bis(iodo)-(1,2-bis(diphenylphosphino)ethane-P,P')-rhodium

Central atom:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Attached groups:

COMe (acetyl)

I (iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

cis,cis–[Rh(Cl)(η⁴-C₄H₆)₂]

Formula Unicode styled:

cis,cis–[Rh(Cl)(η⁴-C₄H₆)₂]

Compound name(s):

bis(η⁴--Butadiene)-chloro-rhodium

Central atom:

Attached groups:

C₄H₆ (η⁴-butadiene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Rh«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

cis,cis–[Rh(Br)₂(Ph)(PPh₃)₂]

Formula Unicode styled:

cis,cis–[Rh(Br)₂(Ph)(PPh₃)₂]

Compound name(s):

Dibromo-bis(triphenylphosphine)-phenyl-rhodium

Central atom:

Attached groups:

Br (bromo)

Ph (phenyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Rh«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

cis–[Rh(Br)₂(NO){P(OPh)₃}₂]

Formula Unicode styled:

cis–[Rh(Br)₂(NO){P(OPh)₃}₂]

Compound name(s):

Dibromo-nitrosyl-bis(triphenylphosphite)-rhodium

Central atom:

P(OPh)₃ (triphenylphosphite)

Attached groups:

Br (bromo)

NO (nitrosyl X)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: