5-coordinate: square-based pyramid (SPY-5)

CH₂SiMe₃ (trimethylsilylmethyl)

Attached groups:

Py (pyridine)

N (nitrido; ≡N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁶C⁵O^VIE¹⁶B⁷Z⁰X⁶L¹»

[MLXZ]𝘲 class:

[MX₆L₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

[Ru(CH₂SiMe₃)₂(μ₂-OH)(N)]₂

Formula Unicode styled:

[Ru(CH₂SiMe₃)₂(μ₂-OH)(N)]₂

Compound name(s):

bis-[(μ₂-Hydroxo)-nitrido-bis(trimethylsilylmethyl)-ruthenium]

Central atom:

CH₂SiMe₃ (trimethylsilylmethyl)

Attached groups:

OH (μ₂-hydroxy)

N (nitrido; ≡N)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁶C⁵O^VIE¹⁶B⁷Z⁰X⁶L¹»

[MLXZ]𝘲 class:

[MX₆L₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

[Ru(Br)₄(N)]⊖

Formula Unicode styled:

[Ru(Br)₄(N)]⊖

Compound name(s):

tetrabromonitrido-ruthenium(1-)

Central atom:

Attached groups:

Br (bromo)

N (nitrido; ≡N)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁶C⁵O^VIE¹⁶B⁷Z⁰L⁰X⁷»^⊖

[MLXZ]𝘲 class:

[MX₇]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

[Ru(Br)₂(PPh₃)₃]

Formula Unicode styled:

[Ru(Br)₂(PPh₃)₃]

Compound name(s):

Dibromo-tris(triphenylphosphine)-ruthenium

Central atom:

PPh₃ (triphenylphosphane)

Attached groups:

Br (bromo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V²C⁵O^IIE¹⁶B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Fe(SPh)(Tpp)]

Formula Unicode styled:

[Fe(SPh)(Tpp)]

Compound name(s):

Benzenethiolato-tetraphenylporphyrin-iron

Central atom:

Attached groups:

SPh (phenylthio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(SPh)(Oep)]

Formula Unicode styled:

[Fe(SPh)(Oep)]

Compound name(s):

Benzenethiolato-2,3,7,8,12,13,17,18-octaethylporphinato-iron

Central atom:

Attached groups:

SPh (phenylthio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(SbF₆)(Tpp)]

Formula Unicode styled:

[Fe(SbF₆)(Tpp)]

Compound name(s):

(Hexafluoro-antimony)-(meso-tetraphenylporphinato)-iron

Central atom:

FSbF₅ (hexafluoroantimonato)

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X²L³»^⊕

[MLXZ]𝘲 class:

[MX₂L₃]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(S₂C₆H₄-κ²S)₂(PMe₃)]

Formula Unicode styled:

[Fe(S₂C₆H₄-κ²S)₂(PMe₃)]

Compound name(s):

bis(1,2-Benzenedithiolato-S,S')-trimethylphosphine-iron

Central atom:

S₂C₆H₄ (benzene-1,2-dithiolato-κ²S)

Attached groups:

PMe₃ (trimethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Fe«V⁴C⁵O^IVE¹⁴B⁵Z⁰X⁴L¹»

[MLXZ]𝘲 class:

[MX₄L₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₁

[Fe(Ph)(Tpp)]

Formula Unicode styled:

[Fe(Ph)(Tpp)]

Compound name(s):

Phenyl-(meso-tetraphenylporphyrinato)-iron

Central atom:

Attached groups:

Ph (phenyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(Ph)(Oec)]

Formula Unicode styled:

[Fe(Ph)(Oec)]

Compound name(s):

Phenyl-(2,3,7,8,12,13,17,18-octaethylcorrolato)-iron

Central atom:

Attached groups:

Ph (phenyl)

Oec (octaethylcorrelato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(PEt₃)(η⁴-C₄H₆)(η⁴-Cod)]

Formula Unicode styled:

[Fe(PEt₃)(η⁴-C₄H₆)(η⁴-Cod)]

Compound name(s):

(η⁴-Buta-1,3-diene)-(η⁴-cyclo-octa-1,5-diene)-triethylphosphine-iron

Central atom:

Cod (η²,η²-cycloocta-1,5-diene)

Attached groups:

PEt₃ (triethylphosphane)

C₄H₆ (η⁴-butadiene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Fe(SO₃CF₃-κO)(Tpp)]

Formula Unicode styled:

[Fe(SO₃CF₃-κO)(Tpp)]

Compound name(s):

(tetraphenylporphyrinato)-(trifluoromethanesulfonato-O)-iron

Central atom:

OSO₂CF₃ (trifluoromethanesulfonato-κO)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(OPh)(Tpp)]

Formula Unicode styled:

[Fe(OPh)(Tpp)]

Compound name(s):

Phenolato-tetraphenylporphyrin-iron

Central atom:

Attached groups:

OPh (phenoxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(ONO₂-κO)(Oep)]

Formula Unicode styled:

[Fe(ONO₂-κO)(Oep)]

Compound name(s):

Nitrato-(octaethylporphyrinato)-iron

Central atom:

Attached groups:

NO₃ (nitrato-κO)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(OMe)(Tpp)]

Formula Unicode styled:

[Fe(OMe)(Tpp)]

Compound name(s):

Tetraphenylporphinato-methoxy-iron

Central atom:

Attached groups:

OMe (methoxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(OMe)(Oep)]

Formula Unicode styled:

[Fe(OMe)(Oep)]

Compound name(s):

Methoxy-octaethylporphinato-iron

Central atom:

Attached groups:

OMe (methoxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(OH₂)(Oep)]⊕

Formula Unicode styled:

[Fe(OH₂)(Oep)]⊕

Compound name(s):

Aqua-(octaethylporphyrinato)-iron(1+)

Central atom:

Attached groups:

OH₂ (aqua)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X²L³»^⊕

[MLXZ]𝘲 class:

[MX₂L₃]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(ClO₄-κO)(Oep)]

Formula Unicode styled:

[Fe(ClO₄-κO)(Oep)]

Compound name(s):

Octaethylporphinato-perchlorato-iron

Central atom:

Attached groups:

ClO₄ (perchlorato-κO)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Fe(O₂NO-κ²O)(Tpp)]

Formula Unicode styled:

[Fe(O₂NO-κ²O)(Tpp)]

Compound name(s):

(Nitrato-O,O')-tetraphenylporphyrinato-iron

Central atom:

Attached groups:

NO₃ (nitrato-κ²O)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 6

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Fe«V³C⁶O^IIIE¹⁷B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Fe(NO)(Oep)]⊕

Formula Unicode styled:

[Fe(NO)(Oep)]⊕

Compound name(s):

Nitrosyl-octaethylporphinato-iron(1+)

Central atom:

Attached groups:

NO (nitrosyl, linear)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: