5-coordinate: square-based pyramid (SPY-5)

Attached groups:

SEt₂ (diethylthioether)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁵O^IIE¹⁴B⁷Z⁰X⁶L¹»

[MLXZ]𝘲 class:

[MX₆L₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

[Mo(Cl)₂(PMe₃)₂]₂

Formula Unicode styled:

[Mo(Cl)₂(PMe₃)₂]₂

Compound name(s):

bis-[dichloro-bis(trimethylphosphine)-molybdenum(Mo≣Mo)]

Central atom:

Attached groups:

PMe₃ (trimethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁵O^IIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Mo(Cl)₂(OHMe)(PPh₃)]₂

Formula Unicode styled:

[Mo(Cl)₂(OHMe)(PPh₃)]₂

Compound name(s):

bis-[Dichloro-(methanol)-(triphenylphosphine)-molybdenum(Mo≣Mo)]

Central atom:

Attached groups:

PPh₃ (triphenylphosphane)

OHMe (methanol)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁵O^IIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Mo(Cl)₂(Dppm-κ²P)]₂

Formula Unicode styled:

[Mo(Cl)₂(Dppm-κ²P)]₂

Compound name(s):

bis-[dichloro-(diphenylphosphino)methane-molybdenum(Mo≣Mo)]

Central atom:

Attached groups:

Dppm (bis-(diphenylphosphino)methane-κ²P)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁵O^IIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Mo(CH₂SiMe₃)(μ₂-O₂CMe)(PMe₃)₂]₂

Formula Unicode styled:

[Mo(CH₂SiMe₃)(μ₂-O₂CMe)(PMe₃)₂]₂

Compound name(s):

bis-[(μ-Acetato)-bis((trimethylphosphine)-(trimethylsilylmethyl)-molybdenum(Mo≣Mo)]

Central atom:

CH₂SiMe₃ (trimethylsilylmethyl)

Attached groups:

O₂CMe (μ₂-acetato)

PMe₃ (trimethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Mo«V⁶C⁵O^IIE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[Mo(Br)₄]₂⁴⊖

Formula Unicode styled:

[Mo(Br)₄]₂⁴⊖

Compound name(s):

bis-[tetrabromo-molybdenum(Mo≣Mo)(2-)]

Central atom:

Attached groups:

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁵O^IIE¹⁶B⁸Z⁰L⁰X⁸»^2⊖

[MLXZ]𝘲 class:

[MX₈]^2-

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Mo(Br)₃(OH₂)]₂²⊖

Formula Unicode styled:

[Mo(Br)₃(OH₂)]₂²⊖

Compound name(s):

bis-[tribromo-aqua-molybdenum(Mo≣Mo)(1-)]

Central atom:

Attached groups:

OH₂ (aqua)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁵O^IIE¹⁶B⁸Z⁰X⁷L¹»^⊖

[MLXZ]𝘲 class:

[MX₇L₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Mo(Br)₂(O₂CCF₃-κO)]₂²⊖

Formula Unicode styled:

[Mo(Br)₂(O₂CCF₃-κO)]₂²⊖

Compound name(s):

bis-[dibromo-(μ₂-trifluoroacetato)-molybdenum(Mo≣Mo)(1-)]

Central atom:

Attached groups:

O₂CCF₃ (trifluoroacetato-κO)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁶C⁵O^IIE¹⁴B⁷Z⁰L⁰X⁷»^⊖

[MLXZ]𝘲 class:

[MX₇]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

[Mo(Br)₂(PMe₃)₂]₂

Formula Unicode styled:

[Mo(Br)₂(PMe₃)₂]₂

Compound name(s):

bis-[dibromo-bis(trimethylphosphine)-molybdenum(Mo≣Mo)]

Central atom:

Attached groups:

PMe₃ (trimethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

NMe₂ (dimethylamino: planar)

Summary of calculated classifications:

Mo«V⁶C⁵O^IIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Hf(NMe₂)₃(μ₂-NMe₂)]₂

Formula Unicode styled:

[Hf(NMe₂)₃(μ₂-NMe₂)]₂

Compound name(s):

bis-[(μ₂-dimethylamido)-tris(dimethylamido)-hafnium]

Central atom:

Hafnium

Attached groups:

NMe₂ (μ₂-dimethylamino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

=NC₆H₃Prⁱ₂ (2,6-di-isopropylphenylimino)

Summary of calculated classifications:

Hf«V⁴C⁵O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Hf(=NC₆H₃Prⁱⁱ₂)(Ttp)]

Formula Unicode styled:

[Hf(=NC₆H₃Prⁱ₂)(Ttp)]

Compound name(s):

(Tetra-p-tolylporphyrinato)-(2,6-di-isopropylphenylimido)-hafnium

Central atom:

Hafnium

Attached groups:

Ttp (tetratolylporphyrin)

Charge on central atom:

0

Compound type:

Molecular

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 12

Summary of calculated classifications:

Hf«V⁴C⁵O^IVE¹²B⁶Z⁰X⁴L²»

[MLXZ]𝘲 class:

[MX₄L₂]

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

[Cr{(CH₂)₂PMe₂}₂]₂

Formula Unicode styled:

[Cr{(CH₂)₂PMe₂}₂]₂

Compound name(s):

bis-[bis(μ₂-Dimethylphosphonium-dimethylide)-chromium(Cr≣Cr)]

Central atom:

(CH₂)₂PMe₂ (dimethylphosphino-bis-ylide)

Attached groups:

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cr«V⁶C⁵O^IIE¹⁶B⁸Z⁰L⁰X⁸»^2⊖

[MLXZ]𝘲 class:

[MX₈]^2-

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Cr(O₂CBuᵗ-κ²O)₂]₂

Formula Unicode styled:

[Cr(O₂CBuᵗ-κ²O)₂]₂

Compound name(s):

bis-[bis-(μ₂-Pivalato-O,O')-chromium(Cr≣Cr)]

Central atom:

Attached groups:

O₂CBuᵗ (pivalato-κ²O)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cr«V⁶C⁵O^IIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[Cr(Cl)₂(μ₂-Cl)(O)]₂

Formula Unicode styled:

[Cr(Cl)₂(μ₂-Cl)(O)]₂

Compound name(s):

bis-[(μ₂-Chloro)-dichloro-oxo]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Cr«V⁵C⁵O^VE¹⁵B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Cr(Cl)(μ₂-Cl)(TMEDA-κ²N)]₂

Formula Unicode styled:

[Cr(Cl)(μ₂-Cl)(TMEDA-κ²N)]₂

Compound name(s):

bis-[(μ₂-Chloro)-chloro-(tetramethylethylenediamine)-chromium]

Central atom:

Attached groups:

TMEDA (tetramethylethylenediamine-κ²N)

Cl (μ₂-chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cr«V²C⁵O^IIE¹⁴B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Cr(μ₂-Cl)(Tpm*-κ³N)]₂²⊕

Formula Unicode styled:

[Cr(μ₂-Cl)(Tpm*-κ³N)]₂²⊕

Compound name(s):

bis-[(μ₂-Chloro)-(tris(3,5-dimethylpyrazolyl)methane-N,N',N'')-chromium(1+)]

Central atom:

Tpm* (tris(3,5-dimethylpyrazolyl)methane-κ³N)

Attached groups:

Cl (μ₂-chloro)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Cr«V²C⁵O^IIE¹⁴B⁵Z⁰X¹L⁴»^⊕

[MLXZ]𝘲 class:

[MX₁L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[V₂(O)₄(O)]

Formula Unicode styled:

[V₂(O)₄(O)]

Compound name(s):

[pentaoxo-divanadium]

divanadium pentoxide

Central atom:

Vanadium

Attached groups:

O (oxo X₂)

O (oxo ⭀O X₂L)

Charge on central atom:

Compound type:

Lattice

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

OC₆H₃Buᵗ₂-2,6 (di-t-butylphenoxy-2,6)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 0

Summary of calculated classifications:

V«V⁵C⁵O^V»

[MLXZ]𝘲 class:

MLXZ class (ENC, equivalent neutral class):

[Sr(OC₆H₃Buᵗ₂-2,6)₂(Py)₃]

Formula Unicode styled:

[Sr(OC₆H₃Buᵗ₂-2,6)₂(Py)₃]

Compound name(s):

bis(2,6-di-t-butylphenolato)(tris(pyridine))-strontium

Central atom:

Strontium

Attached groups:

Py (pyridine)

Charge on central atom:

0

Compound type:

Molecular

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 10

Summary of calculated classifications:

Sr«V²C⁵O^IIE¹⁰B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[K₂(S₂)]

Formula Unicode styled:

[K₂(S₂)]

Compound name(s):

persulfido dipotassium|persulphido dipotassium|dipotassium persulphide|dipotassium disulfide

Central atom:

Potassium

Attached groups:

S₂ (disulfanediyl-κ²S)

Charge on central atom:

Compound type:

Lattice

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Ge(SiMe₃)₃ (tris(trimethylsilyl)germyl)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 0

Summary of calculated classifications:

K«V¹C⁵O^I»

[MLXZ]𝘲 class:

MLXZ class (ENC, equivalent neutral class):

[K{Ge(SiMe₃)₃}(TMEDA-κ²N)₂]

Formula Unicode styled:

[K{Ge(SiMe₃)₃}(TMEDA-κ²N)₂]

Compound name(s):

bis(N,N,N',N'-Tetramethylethylenediamine)-(tris(trimethylsilyl)germyl)-potassium

Central atom:

Potassium

Attached groups:

TMEDA (tetramethylethylenediamine-κ²N)

Charge on central atom:

0

Compound type:

Molecular

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):