8-coordinate: ③₂-●-2 bent metallocene

OPPh₃ (triphenylphosphane oxide)

Attached groups:

Cl (chloro)

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 19

Summary of calculated classifications:

U«V³C⁸O^IIIE¹⁹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[U(Cl)(OPMe₃){η⁵-C₅H₃(Buᵗ)₂}₂]

Formula Unicode styled:

[U(Cl)(OPMe₃){η⁵-C₅H₃(Buᵗ)₂}₂]

Compound name(s):

bis(1,3-di-t-butyl-cyclopentadienyl)-chloro-(trimethylphosphine oxide)-uranium

Central atom:

OPMe₃ (trimethylphosphane oxide)

Attached groups:

Cl (chloro)

C₅H₃(Buᵗ)₂ (η⁵-bis(t-butyl)cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 19

Summary of calculated classifications:

U«V³C⁸O^IIIE¹⁹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[U(OPMe₃)₂{η⁵-C₅H₃(SiMe₃)₂}₂]⊕

Formula Unicode styled:

[U(OPMe₃)₂{η⁵-C₅H₃(SiMe₃)₂}₂]⊕

Compound name(s):

bis(1,3-bis(trimethylsilyl)cyclopentadienyl)-bis(trimethylphosphine oxide)-uranium(1+)

Central atom:

OPMe₃ (trimethylphosphane oxide)

Attached groups:

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 19

Summary of calculated classifications:

U«V³C⁸O^IIIE¹⁹B⁸Z⁰X²L⁶»^⊕

[MLXZ]𝘲 class:

[MX₂L₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[U(AsHMes)₂(Cp*)₂]

Formula Unicode styled:

[U(AsHMes)₂(Cp*)₂]

Compound name(s):

bis(mesityl-arsenido)-bis(pentamethylcyclopentadienyl)-uranium

Central atom:

Attached groups:

AsHMes (mesitylarsanyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

U«V⁴C⁸O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[U(SPh)₂{η⁵-C₅H₂(Buᵗ)₃}₂]

Formula Unicode styled:

[U(SPh)₂{η⁵-C₅H₂(Buᵗ)₃}₂]

Compound name(s):

bis(benzenethiolato)-bis(1,2,4-tri-t-butylcyclopentadienyl)-uranium

Central atom:

C₅H₂(Buᵗ)₃ (η⁵-tris(t-butyl)cyclopentadienyl)

Attached groups:

SPh (phenylthio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

U«V⁴C⁸O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Th(AsHMes)₂(Cp*)₂]

Formula Unicode styled:

[Th(AsHMes)₂(Cp*)₂]

Compound name(s):

bis[(mesityl)arsenido]-bis(pentamethylcyclopentadienyl)-thorium

Central atom:

Thorium

Attached groups:

AsHMes (mesitylarsanyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Th«V⁴C⁸O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Sm(μ₂-OH){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Formula Unicode styled:

[Sm(μ₂-OH){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Compound name(s):

bis-[(μ₂-hydroxo)-bis(bis(η⁵-1,3-bis(trimethylsilyl)-cyclopentadienyl)-samarium]

Central atom:

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Attached groups:

OH (μ₂-hydroxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(μ₂-O₂CPh)(Cp*)₂]₂

Formula Unicode styled:

[Sm(μ₂-O₂CPh)(Cp*)₂]₂

Compound name(s):

bis-[(μ₂-benzoato)-bis(η⁵-pentamethyl-cyclopentadienyl)-samarium]

Central atom:

Attached groups:

O₂CPh (μ₂-benzoato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(μ₂-Me){η⁵-C₅H₄(SiMe₃)}₂]₂

Formula Unicode styled:

[Sm(μ₂-Me){η⁵-C₅H₄(SiMe₃)}₂]₂

Compound name(s):

bis-[(μ₂-methyl)-bis((η⁵-(trimethylsilyl)-cyclopentadienyl)-samarium]

Central atom:

Attached groups:

Me (μ₂-methyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(μ₂-H)(Cp*)₂]₂

Formula Unicode styled:

[Sm(μ₂-H)(Cp*)₂]₂

Compound name(s):

bis-[μ₂-hydrido)-bis(η⁵-pentamethyl-cyclopentadienyl)-samarium]

Central atom:

Attached groups:

H (μ₂-hydrido)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(μ₂-F){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Formula Unicode styled:

[Sm(μ₂-F){η⁵-C₅H₃(SiMe₃)₂}₂]₂

Compound name(s):

bis-[(μ₂-fluoro)-bis(η⁵-1,3-bis(trimethylsilyl)cyclopentadienyl)-samarium]

Central atom:

C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)

Attached groups:

F (μ₂-fluoro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Sm(μ₂-Cl){η⁵-C₅H₄(SiMe₃)}₂]₂

Formula Unicode styled:

[Sm(μ₂-Cl){η⁵-C₅H₄(SiMe₃)}₂]₂

Compound name(s):

bis-[(μ₂-chloro)-bis((η⁵-(trimethylsilyl)-cyclopentadienyl)-samarium]

Central atom:

Attached groups:

Cl (μ₂-chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Sm«V³C⁸O^IIIE²¹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Gd(μ₂-Cl)(η⁵-C₅H₄Buᵗ)₂]₂

Formula Unicode styled:

[Gd(μ₂-Cl)(η⁵-C₅H₄Buᵗ)₂]₂

Compound name(s):

bis-[(μ₂-chloro)-(η⁵-t-butyl-cyclopentadienyl)-gadolinium]

Central atom:

C₅H₄Buᵗ (η⁵-t-butyl-cyclopentadienyl)

Attached groups:

Cl (μ₂-chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Gd«V³C⁸O^IIIE²³B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Gd(μ₂-C≡CPh)(η⁵-C₅H₄Buᵗ)₂]₂

Formula Unicode styled:

[Gd(μ₂-C≡CPh)(η⁵-C₅H₄Buᵗ)₂]₂

Compound name(s):

bis-[(μ₂-phenylethynylidene)-bis(η⁵-t-butyl-cyclopentadienyl)-gadolinium]

Central atom:

C₅H₄Buᵗ (η⁵-t-butyl-cyclopentadienyl)

Attached groups:

C≡CPh (μ₂-phenylethynyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Gd«V³C⁸O^IIIE²³B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Gd(μ₂-C≡CPh)(η⁵-C₅H₃Me₂)₂]₂

Formula Unicode styled:

[Gd(μ₂-C≡CPh)(η⁵-C₅H₃Me₂)₂]₂

Compound name(s):

bis-[(μ₂-phenylethynylidene)-bis(η⁵-2,4-dimethylpentadienyl)-gadolinium]

Central atom:

C₅H₃Me₂ (η⁵-dimethylcyclopentadienyl)

Attached groups:

C≡CPh (μ₂-phenylethynyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Gd«V³C⁸O^IIIE²³B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Gd(μ₂-Br)(Cp)₂]₂

Formula Unicode styled:

[Gd(μ₂-Br)(Cp)₂]₂

Compound name(s):

bis-[(μ₂-cromo)-bis(η⁵-cyclopentadienyl)-gadolinium]

Central atom:

Attached groups:

Br (μ₂-bromo)

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Gd«V³C⁸O^IIIE²³B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Dy(μ₂-OH)(η⁵-C₅H₄Buᵗ)₂]₂

Formula Unicode styled:

[Dy(μ₂-OH)(η⁵-C₅H₄Buᵗ)₂]₂

Compound name(s):

bis-[(μ₂-hydroxo)-bis(η⁵-t-butylcyclopentadienyl)-dysprosium]

Central atom:

C₅H₄Buᵗ (η⁵-t-butyl-cyclopentadienyl)

Attached groups:

OH (μ₂-hydroxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Dy«V³C⁸O^IIIE²⁵B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Dy(μ₂-NH₂)(Cp)₂]₂

Formula Unicode styled:

[Dy(μ₂-NH₂)(Cp)₂]₂

Compound name(s):

bis-[(μ₂-amino)-bis(η⁵-cyclopentadienyl)-dysprosium]

Central atom:

Attached groups:

NH₂ (μ₂-amino)

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Dy«V³C⁸O^IIIE²⁵B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Dy(μ₂-Me){η⁵-C₅H₄(SiMe₃)}₂]₂

Formula Unicode styled:

[Dy(μ₂-Me){η⁵-C₅H₄(SiMe₃)}₂]₂

Compound name(s):

bis-[(μ-methyl)-bis((trimethylsilyl)cyclopentadienyl)-dysprosium]

Central atom:

Attached groups:

Me (μ₂-methyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Dy«V³C⁸O^IIIE²⁵B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Dy(μ₂-I){η⁵-C₅H₄(SiMe₃)}₂]₂

Formula Unicode styled:

[Dy(μ₂-I){η⁵-C₅H₄(SiMe₃)}₂]₂

Compound name(s):

bis-[(μ₂-iodo)-bis(η⁵-cyclopentadienyl)-dysprosium]

Central atom:

Attached groups:

I (μ₂-iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: