5-coordinate: trigonal bipyramid (TBPY-5)

Attached groups:

Cl (chloro)

Charge on central atom:

-3

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Fe«V²C⁵O^IIE¹⁶B⁵Z⁰L⁰X⁵»^3⊖

[MLXZ]𝘲 class:

[MX₅]^3-

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Fe(C₂H₄)(CO)₃(PPh₃)]

Formula Unicode styled:

[Fe(C₂H₄)(CO)₃(PPh₃)]

Compound name(s):

(η²-Ethylene)-tricarbonyl-triphenylphosphine-iron

Central atom:

Attached groups:

C₂H₄ (ethene)

PPh₃ (triphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

[Fe(C₂H₄)(CO)₂{P(OMe)₃}₂]

Formula Unicode styled:

[Fe(C₂H₄)(CO)₂{P(OMe)₃}₂]

Compound name(s):

Dicarbonyl-(η²-ethene)-bis(trimethylphosphite)-iron

Central atom:

Attached groups:

C₂H₄ (ethene)

P(OMe)₃ (trimethylphosphite)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

equatorial–[Fe(CO)₄(CF₂=C=CF₂)]

Formula Unicode styled:

equatorial–[Fe(CO)₄(CF₂=C=CF₂)]

Compound name(s):

Tetracarbonyl-(η²-1,1,3,3-tetrafluoroallene)-iron

Central atom:

Attached groups:

CF₂=C=CF₂ (tetrafluoroallene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

equatorial–[Fe(CO)(Depe)₂]

Formula Unicode styled:

equatorial–[Fe(CO)(Depe)₂]

Compound name(s):

Carbonyl-bis(1,2-bis(diethylphosphino)ethane)-iron

Central atom:

Attached groups:

Depe (1,2-bis-(diethylphosphino)ethane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

equatorial–[Fe(CH₂=C=CH₂)(CO)₄]

Formula Unicode styled:

equatorial–[Fe(CH₂=C=CH₂)(CO)₄]

Compound name(s):

Tetracarbonyl-(η²-1,1-difluoroallene)-iron

Central atom:

Attached groups:

CH₂=C=CH₂ (allene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Fe(SPh)(CO)₄]⊖

Formula Unicode styled:

axial–[Fe(SPh)(CO)₄]⊖

Compound name(s):

tetracarbonyl-phenylthiolato-iron(1-)

Central atom:

Attached groups:

SPh (phenylthio)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X¹L⁴»^⊖

[MLXZ]𝘲 class:

[MX₁L₄]^-

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Fe(Prⁿ)(CO)₄]⊖

Formula Unicode styled:

axial–[Fe(Prⁿ)(CO)₄]⊖

Compound name(s):

tetracarbonyl-n-propyl-iron(1-)

Central atom:

Attached groups:

Prⁿ (propyl)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X¹L⁴»^⊖

[MLXZ]𝘲 class:

[MX₁L₄]^-

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Fe(H)(CO)₄{Cr(CO)₅}]⊖

Formula Unicode styled:

axial–[Fe(H)(CO)₄{Cr(CO)₅}]⊖

Compound name(s):

(pentacarbonylchromium)tetracarbonyl-hydrido-iron(1-)

Central atom:

Attached groups:

H (hydrido)

Cr(CO)₅ (pentacarbonylchromium)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 6

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V²C⁶O^OE¹⁸B⁶X¹L⁴Z¹»^⊖

[MLXZ]𝘲 class:

[MX₁L₄Z₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

axial–[Fe(H)(CO)₄]⊖

Formula Unicode styled:

axial–[Fe(H)(CO)₄]⊖

Compound name(s):

(tetracarbonyl-hydrido-iron(1-)

Central atom:

Attached groups:

H (hydrido)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X¹L⁴»^⊖

[MLXZ]𝘲 class:

[MX₁L₄]^-

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Fe(GaCp*)(CO)₄]

Formula Unicode styled:

axial–[Fe(GaCp*)(CO)₄]

Compound name(s):

Tetracarbonyl-(η⁵-pentamethyl-cyclopentadienyl)-gallium-iron

Central atom:

GaCp* (pentamethylcyclopentadienylgallium)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Fe(CO)₄{P(SiMe₃)₃}]

Formula Unicode styled:

axial–[Fe(CO)₄{P(SiMe₃)₃}]

Compound name(s):

Tetracarbonyl-(tris(trimethylsilyl)phosphine)-iron

Central atom:

Attached groups:

P(SiMe₃)₃ (tris-(trimethylsilyl)-phosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Fe(CO)₄{N(CH)₄N}]

Formula Unicode styled:

axial–[Fe(CO)₄{N(CH)₄N}]

Compound name(s):

Pyrazine-tetracarbonyl iron

Central atom:

Attached groups:

Pyz (pyrazine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Fe(CO)₄{Cr(CO)₅}]²⊖

Formula Unicode styled:

axial–[Fe(CO)₄{Cr(CO)₅}]²⊖

Compound name(s):

(pentachromium)-tetracarbonyl-iron(2-)

Central atom:

Attached groups:

Cr(CO)₅ (pentacarbonylchromium)

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (-II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^-IIE¹⁸B⁵X⁰L⁴Z¹»^2⊖

[MLXZ]𝘲 class:

[ML₄Z₁]^2-

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Fe(CO)₄]₂²⊖

Formula Unicode styled:

axial–[Fe(CO)₄]₂²⊖

Compound name(s):

bis-[tetracarbonyl-iron(1-)]

Central atom:

(CO)₄ (tetracarbonyl, (C≡O)₄ trigonal bipyramidal C3v Ⓢ)

Attached groups:

Charge on central atom:

-1

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (-I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁴C⁵O^-IE¹⁸B⁷X¹L⁴Z²»^⊖

[MLXZ]𝘲 class:

[MX₁L₄Z₂]^-

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

axial–[Fe(CO)₄(Dppm-κP)]

Formula Unicode styled:

axial–[Fe(CO)₄(Dppm-κP)]

Compound name(s):

(bis(Diphenylphosphino)methane-P)-tetracarbonyl-iron

Central atom:

Attached groups:

Dppm (bis-(diphenylphosphino)methane-κP)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Fe(CO)₄(SbPh₃)]

Formula Unicode styled:

axial–[Fe(CO)₄(SbPh₃)]

Compound name(s):

Tetracarbonyl-(triphenylstibine)-iron

Central atom:

Attached groups:

SbPh₃ (triphenylstibane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Fe(CO)₄(SbBuᵗ₃)]

Formula Unicode styled:

axial–[Fe(CO)₄(SbBuᵗ₃)]

Compound name(s):

Tetracarbonyl-(tri-t-butylstibine)-iron

Central atom:

Attached groups:

SbBuᵗ₃ (tri-t-butylstibane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Fe(CO)₄(Py)]

Formula Unicode styled:

axial–[Fe(CO)₄(Py)]

Compound name(s):

Pyridine-tetracarbonyl iron

Central atom:

Attached groups:

Py (pyridine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Fe(CO)₄(PTol-o₃)]

Formula Unicode styled:

axial–[Fe(CO)₄(PTol-o₃)]

Compound name(s):

Tetracarbonyl-tris(o-tolyl)phosphine-iron

Central atom:

Attached groups:

PTol-o₃ (tri-o-tolylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: