5-coordinate: trigonal bipyramid (TBPY-5)

Attached groups:

H (hydrido)

NO (nitrosyl, linear)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁴C⁵O^OE¹⁸B⁷X²L⁴Z¹»

[MLXZ]𝘲 class:

[MX₂L₄Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

equatorial–[Ru(CO)₄(CF₃C≡CCF₃)]

Formula Unicode styled:

equatorial–[Ru(CO)₄(CF₃C≡CCF₃)]

Compound name(s):

(η²-bis(Trifluoromethyl)acetylene)-tetracarbonyl-ruthenium

Central atom:

Attached groups:

CF₃C≡CCF₃ (bis(trifluoromethyl)ethyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

equatorial–[Ru(Cl)(Dppe-κ²P)₂]⊕

Formula Unicode styled:

equatorial–[Ru(Cl)(Dppe-κ²P)₂]⊕

Compound name(s):

Chloro-bis(1,2-bis(diphenylphosphino)ethane)-ruthenium(1+)

Central atom:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Attached groups:

Cl (chloro)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Ru«V²C⁵O^IIE¹⁶B⁵Z⁰X¹L⁴»^⊕

[MLXZ]𝘲 class:

[MX₁L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

equatorial–[Ru(C₆H₄)(PMe₃)₄]

Formula Unicode styled:

equatorial–[Ru(C₆H₄)(PMe₃)₄]

Compound name(s):

(σ₂-Benzyne)-tetrakis(trimethylphosphine)-ruthenium

Central atom:

PMe₃ (trimethylphosphane)

Attached groups:

C₆H₄ (benzyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Ru(CO)₄{P(OMe)₃}]

Formula Unicode styled:

axial–[Ru(CO)₄{P(OMe)₃}]

Compound name(s):

Tetracarbonyl-trimethylphosphite-ruthenium

Central atom:

Attached groups:

P(OMe)₃ (trimethylphosphite)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Ru(CO)₄]₂²⊖

Formula Unicode styled:

axial–[Ru(CO)₄]₂²⊖

Compound name(s):

bis-[tetracarbonyl-ruthenium(1-)]

Central atom:

Attached groups:

Charge on central atom:

-1

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (-I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁰C⁵O^-IE¹⁸B⁵Z⁰X¹L⁴»^⊖

[MLXZ]𝘲 class:

[MX₁L₄]^-

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Ru(CO)₄(SbPh₃)]

Formula Unicode styled:

axial–[Ru(CO)₄(SbPh₃)]

Compound name(s):

Tetracarbonyl-(triphenyl-stibine)-ruthenium

Central atom:

Attached groups:

SbPh₃ (triphenylstibane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Ru(CO)₄(SbMe₃)]

Formula Unicode styled:

axial–[Ru(CO)₄(SbMe₃)]

Compound name(s):

Tetracarbonyl-trimethylstibine-ruthenium

Central atom:

Attached groups:

SbMe₃ (trimethylstibane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

axial–[Ru(AsPh₃)(CO)₄]

Formula Unicode styled:

axial–[Ru(AsPh₃)(CO)₄]

Compound name(s):

Tetracarbonyl-triphenylarsine-ruthenium

Central atom:

Attached groups:

AsPh₃ (triphenylarsane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ru«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

trans–[Fe(SnPh₃)(CO)₃(NO)]

Formula Unicode styled:

trans–[Fe(SnPh₃)(CO)₃(NO)]

Compound name(s):

Tricarbonyl-nitrosyl-(triphenyl-tin)-iron

Central atom:

Attached groups:

SnPh₃ (triphenylstannyl)

NO (nitrosyl, linear)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁴C⁵O^OE¹⁸B⁷X²L⁴Z¹»

[MLXZ]𝘲 class:

[MX₂L₄Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

trans–[Fe(SiCl₃)(CO)₃{P(OPh)₃}]⊖

Formula Unicode styled:

trans–[Fe(SiCl₃)(CO)₃{P(OPh)₃}]⊖

Compound name(s):

tricarbonyl-trichlorosilyl-triphenylphosphite-iron)1-)

Central atom:

Attached groups:

SiCl₃ (trichlorosilyl)

P(OPh)₃ (triphenylphosphite)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X¹L⁴»^⊖

[MLXZ]𝘲 class:

[MX₁L₄]^-

MLXZ class (ENC, equivalent neutral class):

ML₅

trans–[Fe(SiCl₃)(CO)₃(PPh₃)]⊖

Formula Unicode styled:

trans–[Fe(SiCl₃)(CO)₃(PPh₃)]⊖

Compound name(s):

tricarbonyl-trichlorosilyl-triphenylphosphine-iron)1-)

Central atom:

Attached groups:

SiCl₃ (trichlorosilyl)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X¹L⁴»^⊖

[MLXZ]𝘲 class:

[MX₁L₄]^-

MLXZ class (ENC, equivalent neutral class):

ML₅

trans–[Fe(NCS-κN)₃(Bpy-4,4')₂]

Formula Unicode styled:

trans–[Fe(NCS-κN)₃(Bpy-4,4')₂]

Compound name(s):

[bis(4,4'-Bipyridine)-tris(isothiocyanato)-iron

Central atom:

Attached groups:

NCS (isothiocyanato-κN)

Bpy (bipyridine-4,4')

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

trans–[Fe(I)₃(AsMe₃)₂]

Formula Unicode styled:

trans–[Fe(I)₃(AsMe₃)₂]

Compound name(s):

Triiodo(bis(trimethylarsine))iron

Central atom:

Attached groups:

I (iodo)

AsMe₃ (trimethylarsane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

PMePh₂ (methyldiphenylphosphane)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Fe«V³C⁵O^IIIE¹⁵B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

trans–[Fe(I)(CO)(COMe-κC,κO)(PMePh₂)₂]

Formula Unicode styled:

trans–[Fe(I)(CO)(COMe-κC,κO)(PMePh₂)₂]

Compound name(s):

(Acetyl-C,O)-carbonyl-iodo-bis(diphenylmethylphosphine)-iron

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

CN: 6

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

trans–[Fe(CO)₃{P(OMe)₃}₂]

Formula Unicode styled:

trans–[Fe(CO)₃{P(OMe)₃}₂]

Compound name(s):

bis(Trimethylphosphite)-tricarbonyl-iron

Central atom:

Attached groups:

P(OMe)₃ (trimethylphosphite)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

trans–[Fe(CO)₃(PPh₃)₂]⊕

Formula Unicode styled:

trans–[Fe(CO)₃(PPh₃)₂]⊕

Compound name(s):

Tricarbonyl-bis(triphenylphosphine)-iron(1+)

Central atom:

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Fe«V¹C⁵O^IE¹⁷B⁵Z⁰X⁰L⁵»^⊕

[MLXZ]𝘲 class:

[ML₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

trans–[Fe(CO)₃(PPh₃)₂]

Formula Unicode styled:

trans–[Fe(CO)₃(PPh₃)₂]

Compound name(s):

Tricarbonyl-bis(triphenylphosphine)-iron

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

trans–[Fe(CO)₃(PMePh₂)₂]

Formula Unicode styled:

trans–[Fe(CO)₃(PMePh₂)₂]

Compound name(s):

bis(Diphenylmethylphosphine)-tricarbonyl-iron

Central atom:

Attached groups:

PMePh₂ (methyldiphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Fe«V⁰C⁵O^OE¹⁸B⁵Z⁰X⁰L⁵»

[MLXZ]𝘲 class:

[ML₅]

MLXZ class (ENC, equivalent neutral class):

ML₅

trans–[Fe(CO)₃(PMe₃)₂]

Formula Unicode styled:

trans–[Fe(CO)₃(PMe₃)₂]

Compound name(s):

Tricarbonyl-bis(trimethylphosphine)-iron

Central atom:

Attached groups:

PMe₃ (trimethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: