5-coordinate: square-based pyramid (SPY-5)

[14]aneN₄-Me₄ (tetramethyl-1,4,8,11-tetraazacyclotetradecane-κ⁴N)

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 7

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

CN: 6

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Re«V⁷C⁶O^VIE¹⁸B⁹Z⁰X⁷L²»

[MLXZ]𝘲 class:

[MX₇L₂]

MLXZ class (ENC, equivalent neutral class):

MX₇L₂

[Ag(NCMe)([14]aneN₄-Me₄-κ⁴N)]²⊕

Formula Unicode styled:

[Ag(NCMe)([14]aneN₄-Me₄-κ⁴N)]²⊕

Compound name(s):

(Acetonitrile)-(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)-silver(2+)

Central atom:

Silver

Attached groups:

NCMe (acetonitrile)

Charge on central atom:

2

Compound type:

Molecular

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 19

Summary of calculated classifications:

Ag«V²C⁵O^IIE¹⁹B⁵Z⁰X⁰L⁵»^2⊕

[MLXZ]𝘲 class:

[ML₅]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Zr(Cl)(μ₂-Cl){N(SiMe₃)₂}₂]₂

Formula Unicode styled:

[Zr(Cl)(μ₂-Cl){N(SiMe₃)₂}₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-chloro-bis(bis(dimethylsilyl)amido)-zirconium]

Central atom:

Zirconium

Attached groups:

N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar)

Cl (μ₂-chloro)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Zr«V⁴C⁵O^IVE¹⁴B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[W(μ₂-O₂CEt)₂]₂

Formula Unicode styled:

[W(μ₂-O₂CEt)₂]₂

Compound name(s):

bis-[bis-(μ₂-Propionato-O,O')-tungsten(W≣W)]

Central atom:

Attached groups:

O₂CEt (μ₂-propanoato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁵O^IIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(O₂CCF₃-κO)(O₂CCF₃-κ²O)(PBuⁿ₃)]₂

Formula Unicode styled:

[W(O₂CCF₃-κO)(O₂CCF₃-κ²O)(PBuⁿ₃)]₂

Compound name(s):

bis-[(μ₂-Trifluoroacetato)-trifluoroacetato-(tri-n-butylphosphine)-tungsten(W≣W)]

Central atom:

O₂CCF₃ (trifluoroacetato-κO)

Attached groups:

O₂CCF₃ (trifluoroacetato-κ²O)

PBuⁿ₃ (tri-n-butylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁵O^IIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(S)(μ₂-S)(S₄)]₂²⊖

Formula Unicode styled:

[W(S)(μ₂-S)(S₄)]₂²⊖

Compound name(s):

bis-[(μ₂-sulfido)-(tetrasulfido)-sulfido-tungsten(1-)]

Central atom:

S₄ (tetrasulfanediyl-κ²S)

Attached groups:

S (thio; ⭀S)

S (μ₂-thio)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

W«V⁶C⁵O^VE¹⁸B⁹Z⁰X⁷L²»^⊖

[MLXZ]𝘲 class:

[MX₇L₂]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[W(OPrⁱ)₃(Py)]₂

Formula Unicode styled:

[W(OPrⁱ)₃(Py)]₂

Compound name(s):

bis-[tri(isopropoxy)-pyridine)-tungsten(W≡W)]

Central atom:

Attached groups:

OPrⁱ (isopropoxy)

Py (pyridine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

W«V⁶C⁵O^IIIE¹⁴B⁷Z⁰X⁶L¹»

[MLXZ]𝘲 class:

[MX₆L₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

[W(μ₂-O₂CPrⁿ)₂]₂

Formula Unicode styled:

[W(μ₂-O₂CPrⁿ)₂]₂

Compound name(s):

bis-[bis((μ₂-Propionato-O,O')-tungsten(W≣W)]

Central atom:

Attached groups:

O₂CPrⁿ (μ₂-propionato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁵O^IIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(Cl)₄]₂⁴⊖

Formula Unicode styled:

[W(Cl)₄]₂⁴⊖

Compound name(s):

bis-[tetrachloro-tungsten(2-)(W≣W)]

Central atom:

Attached groups:

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁵O^IIE¹⁶B⁸Z⁰L⁰X⁸»^2⊖

[MLXZ]𝘲 class:

[MX₈]^2-

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(Cl)₂(NHBuᵗ)(PMe₃)]₂

Formula Unicode styled:

[W(Cl)₂(NHBuᵗ)(PMe₃)]₂

Compound name(s):

bis-[(t-Butylamido)-(trimethylphosphine)-dichloro-tungsten(W≡W)]

Central atom:

Attached groups:

NHBuᵗ (t-butylamino: planar)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁵O^IIIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(Cl)₂(NHBuᵗ)(NH₂Buᵗ)]₂

Formula Unicode styled:

[W(Cl)₂(NHBuᵗ)(NH₂Buᵗ)]₂

Compound name(s):

bis-[dichloro-(t-butylamido)-(t-butylamine)-tungsten(W≡W)]

Central atom:

Attached groups:

NHBuᵗ (t-butylamino: planar)

NH₂Buᵗ (t-butylamine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁵O^IIIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(Cl)₂(PMe₃)₂]₂

Formula Unicode styled:

[W(Cl)₂(PMe₃)₂]₂

Compound name(s):

bis-[(Dichloro-bis(trimethylphosphine)-tungsten(W≣W)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁵O^IIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(Cl)₂(NHEt)(PMe₃)]₂

Formula Unicode styled:

[W(Cl)₂(NHEt)(PMe₃)]₂

Compound name(s):

bis-[(Ethylamido)-dichloro-(trimethylphosphine)-tungsten(W≡W)]

Central atom:

Attached groups:

NHEt (ethylamino: planar)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁵O^IIIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(Cl)₂(NEt₂)(PMe₃)]₂

Formula Unicode styled:

[W(Cl)₂(NEt₂)(PMe₃)]₂

Compound name(s):

bis-[dichloro-diethylamido-(trimethylphosphine)-tungsten(W≡W)]

Central atom:

Attached groups:

NEt₂ (diethylamino: planar)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁵O^IIIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(Cl)₂(NC₅H₄Buᵗ)₂]₂

Formula Unicode styled:

[W(Cl)₂(NC₅H₄Buᵗ)₂]₂

Compound name(s):

bis-[bis(4-t-Butylpyridine)-dichloro-tungsten(W≣W)]

Central atom:

Attached groups:

NC₅H₄Buᵗ (4-t-butylpyridine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁵O^IIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(Cl)₂(Dppe-κ²P)]₂

Formula Unicode styled:

[W(Cl)₂(Dppe-κ²P)]₂

Compound name(s):

bis-[(Diphenylphosphino)ethane)-dichloro-tungsten(W≣W)]

Central atom:

Attached groups:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁵O^IIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(Cl)₂(Dmpe)]₂

Formula Unicode styled:

[W(Cl)₂(Dmpe)]₂

Compound name(s):

bis-[(Diethylphosphino)ethane)-dichloro-tungsten(W≣W)]

Central atom:

Attached groups:

Dmpe (1,2-bis-(dimethylphosphino)ethane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁵O^IIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(Cl)₂(Depe)]₂

Formula Unicode styled:

[W(Cl)₂(Depe)]₂

Compound name(s):

bis-[(Diethylphosphino)ethane)-dichloro-tungsten(W≣W)]

Central atom:

Attached groups:

Depe (1,2-bis-(diethylphosphino)ethane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁵O^IIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[V(μ₂-OMe)(Acac)(O)]₂

Formula Unicode styled:

[V(μ₂-OMe)(Acac)(O)]₂

Compound name(s):

bis-[(μ₂-methoxo)-(acetylacetonato)-oxo-vanadium]

Central atom:

Vanadium

Attached groups:

OMe (μ₂-methoxy)

Acac (acetylacetonato)

O (oxo ⭀O X₂L)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

V«V⁴C⁵O^IVE¹⁵B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[V(μ₂-OEt)(Acac)(O)]₂

Formula Unicode styled:

[V(μ₂-OEt)(Acac)(O)]₂

Compound name(s):

bis-[(μ₂-Ethoxo)-(acetylacetonato)-oxo-vanadium]

Central atom:

Vanadium

Attached groups:

OEt (μ₂-ethoxy)

Acac (acetylacetonato)

O (oxo ⭀O X₂L)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):