Zirconium

Attached groups:

PBuⁿ₃ (tri-n-butylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁷O^IIIE¹⁴B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Zr(Cl)₂(μ₂-Cl)(Dppe-κ²P)]₂

Formula Unicode styled:

[Zr(Cl)₂(μ₂-Cl)(Dppe-κ²P)]₂

Compound name(s):

bis-[μ₂-Chloro)-dichloro-(diphenylphosphino)ethane-P,P')-zirconium(Zr-Zr)]

Central atom:

Attached groups:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁷O^IIIE¹⁴B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Zr(Cl)₂(μ₂-Cl)(Cp*)]₂

Formula Unicode styled:

[Zr(Cl)₂(μ₂-Cl)(Cp*)]₂

Compound name(s):

bis-[(μ₂-Chloro)-dichloro-(η⁵-pentamethyl-cyclopentadienyl)-zirconium]

Central atom:

Attached groups:

Cp* (η⁵-pentamethylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁷O^IVE¹⁴B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Zr(Cl)₃(μ₂-NSiMe₃)]₂²⊖

Formula Unicode styled:

[Zr(Cl)₃(μ₂-NSiMe₃)]₂²⊖

Compound name(s):

bis-[(μ₂-trimethylsilylimido)-trichloro-titanium(1-)]

Central atom:

Attached groups:

NSiMe₃ (μ₂-trimethylsilylimino X₂L)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁵O^IVE¹²B⁶Z⁰X⁵L¹»^⊖

[MLXZ]𝘲 class:

[MX₅L₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

[Zr(Cl)(μ₂-Cl){N(SiMe₃)₂}₂]₂

Formula Unicode styled:

[Zr(Cl)(μ₂-Cl){N(SiMe₃)₂}₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-chloro-bis(bis(dimethylsilyl)amido)-zirconium]

Central atom:

Attached groups:

N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁵O^IVE¹⁴B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Zr(μ₂-Cl){η⁵-C₅H₄(SiMe₃)}₂]₂

Formula Unicode styled:

[Zr(μ₂-Cl){η⁵-C₅H₄(SiMe₃)}₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-bis(η⁵-methylcyclopentadienyl)-zirconium]

Central atom:

Attached groups:

C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Zr«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Zr(Cl){N(PPh₂)₂}(Cp)₂]

Formula Unicode styled:

[Zr(Cl){N(PPh₂)₂}(Cp)₂]

Compound name(s):

Chloro-bis(η⁵-cyclopentadienyl)-(bis(diphenylphosphino)amido)-zirconium

Central atom:

Attached groups:

N(PPh₂)₂ (bis(diphenylphosphanyl)amino XL)

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

0

Compound type:

Molecular

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Zr«V⁴C⁸O^IVE¹⁸B⁹Z⁰X⁴L⁵»

[MLXZ]𝘲 class:

[MX₄L₅]

MLXZ class (ENC, equivalent neutral class):

MX₄L₅

[Zr(μ₂-Cl)(η⁵-C₅H₄Me)₂]₂²⊕

Formula Unicode styled:

[Zr(μ₂-Cl)(η⁵-C₅H₄Me)₂]₂²⊕

Compound name(s):

bis-[(μ₂-Chloro)-bis(η⁵-methylcyclopentadienyl)-zirconium(1+)]

Central atom:

Attached groups:

C₅H₄Me (η⁵-methylcyclopentadienyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁸O^IVE¹⁶B⁸Z⁰X³L⁵»^⊕

[MLXZ]𝘲 class:

[MX₃L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Zr(Cl)(Tp*-κ²N(η⁸-Cot)]

Formula Unicode styled:

[Zr(Cl)(Tp*-κ²N(η⁸-Cot)]

Compound name(s):

Chloro-(η⁸-cyclo-octatetraene)-(hydrogen tris(3,5-dimethylpyrazolato)borato-N,N')-zirconium

Central atom:

Attached groups:

Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ²N)

Cot (η⁸-cyclooctatetraene)

Charge on central atom:

0

Compound type:

Molecular

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁷O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Zr(Cl)(Pz₂BH₂-κ²N)(η⁸-Cot)]

Formula Unicode styled:

[Zr(Cl)(Pz₂BH₂-κ²N)(η⁸-Cot)]

Compound name(s):

Chloro-(η⁸-cyclo-octatetraene)-(dihydrogen bis(pyrazolato)borato)-zirconium

Central atom:

Attached groups:

Pz₂BH₂ (dihydro-di(pyrazolyl)borato-κ²N)

Cot (η⁸-cyclooctatetraene)

Charge on central atom:

0

Compound type:

Molecular

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁷O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Zr(Cl)(NMe₂)(μ₂-NMe₂)₂]₂

Formula Unicode styled:

[Zr(Cl)(NMe₂)(μ₂-NMe₂)₂]₂

Compound name(s):

bis-[(μ₂-Dimethylamido)-chloro-dimethylamido-zirconium]

Central atom:

Attached groups:

NMe₂ (dimethylamino)

NMe₂ (μ₂-dimethylamino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁶O^IVE¹²B⁶Z⁰X⁴L²»

[MLXZ]𝘲 class:

[MX₄L₂]

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

[Zr(μ₂-Cl)(Cp)₂]₂²⊕

Formula Unicode styled:

[Zr(μ₂-Cl)(Cp)₂]₂²⊕

Compound name(s):

bis-[(μ₂-Chloro)-bis(η⁵-cyclopentadienyl)-zirconium(1+)]

Central atom:

Attached groups:

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁸O^IVE¹⁶B⁸Z⁰X³L⁵»^⊕

[MLXZ]𝘲 class:

[MX₃L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Zr(μ₂-C≡CSiMe₃)(Cp)₂]₂

Formula Unicode styled:

[Zr(μ₂-C≡CSiMe₃)(Cp)₂]₂

Compound name(s):

bis-[(μ₂-η²-Trimethylsilylethynyl)-bis(η⁵-cyclopentadienyl)-zirconium]

Central atom:

C≡CSiMe₃ (μ₂-trimethylsilylalkynyl)

Attached groups:

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Zr«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Zr(μ₂-C≡CPh)(η⁵-C₅H₄Me)₂]₂

Formula Unicode styled:

[Zr(μ₂-C≡CPh)(η⁵-C₅H₄Me)₂]₂

Compound name(s):

bis-[(μ₂-η²,σ¹-Phenylethynyl)-bis(η⁵-methylcyclopentadienyl)-zirconium]

Central atom:

C₅H₄Me (η⁵-methylcyclopentadienyl)

Attached groups:

C≡CPh (μ₂-phenylethynyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Zr«V³C⁸O^IIIE¹⁷B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Zr(Br)₄(μ₂-Br)]₂²⊖

Formula Unicode styled:

[Zr(Br)₄(μ₂-Br)]₂²⊖

Compound name(s):

bis-[(μ₂-bromo)-tetrabromo-zirconium(1-)]

Central atom:

Attached groups:

Br (bromo)

Br (μ₂-bromo)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁶O^IVE¹²B⁶Z⁰X⁵L¹»^⊖

[MLXZ]𝘲 class:

[MX₅L₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

[Zr(Br)₂(μ₂-Br)(PMe₃)₂]₂

Formula Unicode styled:

[Zr(Br)₂(μ₂-Br)(PMe₃)₂]₂

Compound name(s):

bis-[(μ₂-Bromo)-dibromo-bis(trimethylphosphine)-zirconium(Zr—Zr)]

Central atom:

PMe₃ (trimethylphosphane)

Attached groups:

Br (bromo)

Br (μ₂-bromo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁷O^IIIE¹⁴B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

[Zr(μ₂-NXy){η⁸-C₈H₆(SiMe₃)₂}]₂

Formula Unicode styled:

[Zr(μ₂-NXy){η⁸-C₈H₆(SiMe₃)₂}]₂

Compound name(s):

bis-[(μ₂-2,6-dimethylphenylamido-N,N)-(η⁸-1,4-bis(trimethylsilyl)cyclooctatetraene)-zirconium]

Central atom:

C₈H₆(SiMe₃)₂ (η⁸-bistrimethylsilyl-cyclooctatetraene)

Attached groups:

NXy (μ₂-xylylimino X₂L)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁶O^IVE¹⁶B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

catena–1D-trans–[Zr(μ₂-Cl)(CH₂Buᵗ)₃]

Formula Unicode styled:

catena–1D-trans–[Zr(μ₂-Cl)(CH₂Buᵗ)₃]

Compound name(s):

catena-[(μ₂-Chloro)-tris(neopentyl)-zirconium]

Central atom:

Attached groups:

CH₂Buᵗ (t-butylmethyl)

Charge on central atom:

0

Compound type:

Catena-1D

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 10

Summary of calculated classifications:

Zr«V⁴C⁵O^IVE¹⁰B⁵Z⁰X⁴L¹»

[MLXZ]𝘲 class:

[MX₄L₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₁

cis,cis,trans–[Zr(Cl)₂(μ₂-NPh)(Thf)₂]₂

Formula Unicode styled:

cis,cis,trans–[Zr(Cl)₂(μ₂-NPh)(Thf)₂]₂

Compound name(s):

bis-[(μ₂-Phenylimido)-dichloro-bis(tetrahydrofuran)-zirconium]

Central atom:

Attached groups:

NPh (μ₂-phenylimino X₂L)

Thf (tetrahydrofuran)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Zr«V⁴C⁶O^IVE¹⁴B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

cis,cis,trans–[Zr(Cl)₂(=NC₆H₃Prⁱⁱ₂)(Thf)₂]₂

Formula Unicode styled:

cis,cis,trans–[Zr(Cl)₂(=NC₆H₃Prⁱ₂)(Thf)₂]₂

Compound name(s):

bis-[(μ₂-2,6-Di-isopropylphenylimido)-dichloro-bis(tetrahydrofuran)-zirconium]

Central atom:

Attached groups:

=NC₆H₃Prⁱ₂ (2,6-di-isopropylphenylimino)

Thf (tetrahydrofuran)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: