Iridium

[9]aneN₃ (1,4,7-triazacyclononane-κ³N)

Attached groups:

Charge on central atom:

3

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X⁰L⁶»^3⊕

[MLXZ]𝘲 class:

[ML₆]³⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

equatorial–[Ir(Se₂)(Dppe-κ²P)₂]⊕

Formula Unicode styled:

equatorial–[Ir(Se₂)(Dppe-κ²P)₂]⊕

Compound name(s):

bis(1,2-bis(Diphenylphosphino)-ethane)-(η²-diselenium)-iridium(1+)

Central atom:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Attached groups:

Se₂ (perseleno-κ²Se)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

equatorial–[Ir(S₂)(Dppe-κ²P)₂]⊕

Formula Unicode styled:

equatorial–[Ir(S₂)(Dppe-κ²P)₂]⊕

Compound name(s):

Disulfur-bis(bis(diphenylphosphino)ethane) iridium(1+)

Central atom:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Attached groups:

S₂ (disulfanediyl-κ²S)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

equatorial–[Ir(O₂)(PMe₂Ph)₄]⊕

Formula Unicode styled:

equatorial–[Ir(O₂)(PMe₂Ph)₄]⊕

Compound name(s):

Dioxygen-tetra(dimethylphenylphosphine)-iridium(1+)

Central atom:

PMe₂Ph (dimethylphenylphosphane)

Attached groups:

O₂ (dioxygen)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X⁰L⁵»^⊕

[MLXZ]𝘲 class:

[ML₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

cis,cis,trans–[Ir(Ph)(Py)(Acac)₂]

Formula Unicode styled:

cis,cis,trans–[Ir(Ph)(Py)(Acac)₂]

Compound name(s):

bis(Acetylacetonato-O,O')-phenyl-(pyridine-N)-iridium

Central atom:

Attached groups:

Ph (phenyl)

Py (pyridine)

Acac (acetylacetonato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis,trans–[Ir(Me)(Py)(O₂C₇H₅-κ²O)₂]

Formula Unicode styled:

cis,cis,trans–[Ir(Me)(Py)(O₂C₇H₅-κ²O)₂]

Compound name(s):

Methyl-pyridine-bis(tropolonato-O,O')-iridium

Central atom:

Attached groups:

Me (methyl)

Py (pyridine)

O₂C₇H₅ (tropolonato-κ²O)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis,trans–[Ir(Me)(I)(Acac)(η⁴-Cod)]

Formula Unicode styled:

cis,cis,trans–[Ir(Me)(I)(Acac)(η⁴-Cod)]

Compound name(s):

(η⁴-1,5-Cyclo-octadiene)-iodo-methyl-(2,4-pentanedionato-O,O')-iridium

Central atom:

Cod (η²,η²-cycloocta-1,5-diene)

Attached groups:

Me (methyl)

I (iodo)

Acac (acetylacetonato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis,trans–[Ir(Me)₂(CO)₂(PPh₃)₂]⊕

Formula Unicode styled:

cis,cis,trans–[Ir(Me)₂(CO)₂(PPh₃)₂]⊕

Compound name(s):

(Dicarbonyl-dimethyl-bis(triphenylphosphine)-iridium(1+)

Central atom:

Attached groups:

Me (methyl)

CO (carbonyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

PTol₃ (tritolylphosphane)

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis,trans–[Ir(Me)(SO₄-κ²O)(CO)(PTol₃)₂]

Formula Unicode styled:

cis,cis,trans–[Ir(Me)(SO₄-κ²O)(CO)(PTol₃)₂]

Compound name(s):

Carbonyl-methyl-(sulfato-O,O')-bis(tris(p-tolyl)phosphine)-iridium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis,trans–[Ir(I)₂(CO)(CO₂Me)(Bpy)]

Formula Unicode styled:

cis,cis,trans–[Ir(I)₂(CO)(CO₂Me)(Bpy)]

Compound name(s):

Di-iodo-carbonyl-methoxycarbonyl-(2,2'-bipyridyl)-iridium

Central atom:

Attached groups:

I (iodo)

CO (carbonyl)

CO₂Me (methoxycarbonyl)

Bpy (bipyridine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis,trans–[Ir(H)₂(Py)₂(PPh₃)₂]⊕

Formula Unicode styled:

cis,cis,trans–[Ir(H)₂(Py)₂(PPh₃)₂]⊕

Compound name(s):

dihydrido-dipyridine-bis(triphenylphosphine)-iridium(1+)

Central atom:

Attached groups:

Py (pyridine)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

PPrⁱ₃ (triisopropylphosphane)

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis,trans–[Ir(H)₂(I)(η²-H₂)(PPrⁱ₃)₂]

Formula Unicode styled:

cis,cis,trans–[Ir(H)₂(I)(η²-H₂)(PPrⁱ₃)₂]

Compound name(s):

Iodo-dihydrido-(dihydrogen)-bis(tri-isopropylphosphine)-iridium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis,trans–[Ir(H)₂(Tht)₂(PPh₃)₂]⊕

Formula Unicode styled:

cis,cis,trans–[Ir(H)₂(Tht)₂(PPh₃)₂]⊕

Compound name(s):

Dihydrido-bis(triphenylphosphino)-bis(tetrahydrothiophene)-iridium(1+)

Central atom:

Attached groups:

Tht (tetrahydrothiophene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis,trans–[Ir(H)₂(SiEt₃)(AsPh₃)(η⁴-Cod)]

Formula Unicode styled:

cis,cis,trans–[Ir(H)₂(SiEt₃)(AsPh₃)(η⁴-Cod)]

Compound name(s):

Dihydrido-triphenylarsine-triethylsilyl-(η⁴-cyclo-octa-1,5-diene)-iridium

Central atom:

Attached groups:

Cod (η²,η²-cycloocta-1,5-diene)

SiEt₃ (triethylsilyl)

AsPh₃ (triphenylarsane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis,trans–[Ir(H)₂(SC₄H₄)₂(PPh₃)₂]⊕

Formula Unicode styled:

cis,cis,trans–[Ir(H)₂(SC₄H₄)₂(PPh₃)₂]⊕

Compound name(s):

Dihydrido-bis(triphenylphosphino)-bis(thiophene)-iridium(1+)

Central atom:

Attached groups:

SC₄H₄ (thiophene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis,trans–[Ir(H)₂(PCy₃)₂(S₂CH)]

Formula Unicode styled:

cis,cis,trans–[Ir(H)₂(PCy₃)₂(S₂CH)]

Compound name(s):

Dihydrido-bis(tricyclohexylphosphino)-dithioformato-iridium

Central atom:

Attached groups:

PCy₃ (tricyclohexylphosphane)

S₂CH (dithioformato-κ²S)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis,trans–[Ir(H)₂(PBuᵗ₂Ph)₂]⊕

Formula Unicode styled:

cis,cis,trans–[Ir(H)₂(PBuᵗ₂Ph)₂]⊕

Compound name(s):

Dihydro-bis(di-t-butylphenylphosphine)-iridium(1+)

Central atom:

Attached groups:

PBuᵗ₂Ph (phenyl-di-t-butylphosphane)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 4

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Ir«V³C⁴O^IIIE¹⁴B⁴Z⁰X²L²»^⊕

[MLXZ]𝘲 class:

[MX₂L₂]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₁

cis,cis,trans–[Ir(H)₂(OH₂)(PPh₃)₂(Thf)]⊕

Formula Unicode styled:

cis,cis,trans–[Ir(H)₂(OH₂)(PPh₃)₂(Thf)]⊕

Compound name(s):

Aqua-dihydrido-bis(triphenylphosphine)-tetrahydrofuran-iridium(1+)

Central atom:

Attached groups:

OH₂ (aqua)

Thf (tetrahydrofuran)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis,trans–[Ir(H)₂(O=CMe₂)₂(PPh₃)₂]⊕

Formula Unicode styled:

cis,cis,trans–[Ir(H)₂(O=CMe₂)₂(PPh₃)₂]⊕

Compound name(s):

Dihydrido-bis(acetone)-bis(triphenylphosphine)-iridium(1+)

Central atom:

Attached groups:

O=CMe₂ (acetone)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis,cis,trans–[Ir(H)₂(NCMe)₂(PPrⁱ₃)₂]⊕

Formula Unicode styled:

cis,cis,trans–[Ir(H)₂(NCMe)₂(PPrⁱ₃)₂]⊕

Compound name(s):

bis(Acetonitrile)-dihydrido-bis(tri-isopropylphosphine)-iridium(1+)

Central atom:

Attached groups:

PPrⁱ₃ (triisopropylphosphane)

NCMe (acetonitrile)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: