Iridium

Attached groups:

Buᵗ (t-butyl)

CO (carbonyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(AsPh₃)(PPh₃)(η⁴-Cod)]⊕

Formula Unicode styled:

[Ir(AsPh₃)(PPh₃)(η⁴-Cod)]⊕

Compound name(s):

(η⁴-Cyclo-octa-1,5-diene)-(triphenylarsine)-(triphenylphosphine)-iridium(1+)

Central atom:

PPh₃ (triphenylphosphane)

Attached groups:

AsPh₃ (triphenylarsane)

Cod (η²,η²-cycloocta-1,5-diene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X⁰L⁴»^⊕

[MLXZ]𝘲 class:

[ML₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Ir(=NC₆H₃Prⁱⁱ₂)(Cp*)]

Formula Unicode styled:

[Ir(=NC₆H₃Prⁱ₂)(Cp*)]

Compound name(s):

(η⁵-Pentamethyl-cyclopentadienyl)-(2,6-di-isopropylphenylimido)-iridium

Central atom:

=NC₆H₃Prⁱ₂ (2,6-di-isopropylphenylimino)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁴O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Ir(=NXy)(Cp*)]

Formula Unicode styled:

[Ir(=NXy)(Cp*)]

Compound name(s):

(η⁵-Pentamethyl-cyclopentadienyl)-(m-xylylimido)-iridium

Central atom:

Attached groups:

=NXy (xylylimino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁴O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Ir(⭀NBuᵗ)(Cp*)]

Formula Unicode styled:

[Ir(⭀NBuᵗ)(Cp*)]

Compound name(s):

t-Butylimido-(η⁵-pentamethyl-cyclopentadienyl)-iridium

Central atom:

Attached groups:

⭀NBuᵗ (⭀N t-butylimino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁴O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(=CPh₂)(PPrⁱ₃)(Cp)]

Formula Unicode styled:

[Ir(=CPh₂)(PPrⁱ₃)(Cp)]

Compound name(s):

(η⁵-Cyclopentadienyl)-diphenylcarbene-(tri-isopropylphosphine)-iridium

Central atom:

=CPh₂ (diphenylmethylidene)

Attached groups:

PPrⁱ₃ (triisopropylphosphane)

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁵O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(=CH₂)(Cp*)]₂

Formula Unicode styled:

[Ir(=CH₂)(Cp*)]₂

Compound name(s):

bis(μ₂-methylene)-bis(η⁵-pentamethylcyclopentadienyl)-di-iridium

Central atom:

Attached groups:

=CH₂ (methylidene)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V⁵C⁶O^IIIE¹⁸B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Ir(=CF₂)(PMe₃)(Cp*)]

Formula Unicode styled:

[Ir(=CF₂)(PMe₃)(Cp*)]

Compound name(s):

(Difluorocarbene)-(trimethylphosphine)-(η⁵-pentamethylcyclopentadienyl)-iridium

Central atom:

=CF₂ (difluoromethylidene)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁵O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(=CF₂)(CO)(Cp*)]

Formula Unicode styled:

[Ir(=CF₂)(CO)(Cp*)]

Compound name(s):

Carbonyl-(η⁵-pentamethylcyclopentadienyl)-(difluorocarbene)-iridium

Central atom:

=CF₂ (difluoromethylidene)

Attached groups:

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁵O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir([9]aneS₃-κ²S)(Cp*)]²⊕

Formula Unicode styled:

[Ir([9]aneS₃-κ²S)(Cp*)]²⊕

Compound name(s):

(η⁵-Pentamethyl-cyclopentadienyl)-(1,4,7-trithiacyclononane)-iridium(2+)

Central atom:

[9]aneS₃ (1,4,7-trithiocyclononane-κ²S)

Attached groups:

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁵O^IIIE¹⁶B⁵Z⁰X¹L⁴»^2⊕

[MLXZ]𝘲 class:

[MX₁L₄]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Ir([9]aneN₃-κ³N)(Cp*)]²⊕

Formula Unicode styled:

[Ir([9]aneN₃-κ³N)(Cp*)]²⊕

Compound name(s):

(η⁵-Pentamethyl-cyclopentadienyl)-(1,4,7-triazacyclononane)-iridium(2+)

Central atom:

[9]aneN₃ (1,4,7-triazacyclononane-κ³N)

Attached groups:

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X¹L⁵»^2⊕

[MLXZ]𝘲 class:

[MX₁L₅]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

fac–[Ir(Ph)₂(NC₉H₇)(Tp*-κ³N)]

Formula Unicode styled:

fac–[Ir(Ph)₂(NC₉H₇)(Tp*-κ³N)]

Compound name(s):

(hydrogen tris(3,5-dimethylpyrazol-1-yl)borate)-(quinoline)-diphenyl-iridium

Central atom:

Attached groups:

Ph (phenyl)

NC₉H₇ (quinoline-κN)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

fac–[Ir(Ph)(CO)(PMe₃)(Tp*-κ³N)]⊕

Formula Unicode styled:

fac–[Ir(Ph)(CO)(PMe₃)(Tp*-κ³N)]⊕

Compound name(s):

(Hydrogen tris(3,5-dimethylpyrazolyl)borate-N,N',N'')-(dinitrogen)-phenyl-(trimethylphosphine)-iridium(1+)

Central atom:

Attached groups:

Ph (phenyl)

CO (carbonyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

fac–[Ir(Me)(I)₃(CO)₂]⊖

Formula Unicode styled:

fac–[Ir(Me)(I)₃(CO)₂]⊖

Compound name(s):

dicarbonyl-methyl-triiodo-iridium(1-)

Central atom:

Attached groups:

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X⁴L²»^⊖

[MLXZ]𝘲 class:

[MX₄L₂]^-

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

fac–[Ir(I)(μ₂-I)(Me)(CO)₂]₂

Formula Unicode styled:

fac–[Ir(I)(μ₂-I)(Me)(CO)₂]₂

Compound name(s):

bis((μ₂-iodo)-dicarbonyl-iodo-methyl-iridium)

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

fac–[Ir(Me)₃(PMe₃)₃]

Formula Unicode styled:

fac–[Ir(Me)₃(PMe₃)₃]

Compound name(s):

Trimethyl(tris(trimethylphosphine))iridium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

fac–[Ir(Me)₃(PMe₂Ph)₃]

Formula Unicode styled:

fac–[Ir(Me)₃(PMe₂Ph)₃]

Compound name(s):

Trimethyl-tris(dimethylphenylphosphine)-iridium

Central atom:

Attached groups:

PMe₂Ph (dimethylphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

fac–[Ir(Me)(SO₃CF₃-κO)(PMe₃)(Tp*-κ³N)]

Formula Unicode styled:

fac–[Ir(Me)(SO₃CF₃-κO)(PMe₃)(Tp*-κ³N)]

Compound name(s):

(Hydrogen tris(3,5-dimethylpyrazolyl)borate)-methyl-(trifluoromethanesulfonato-O)-(trimethylphosphine)-iridium

Central atom:

Attached groups:

OSO₂CF₃ (trifluoromethanesulfonato-κO)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

fac–[Ir(Me)(N₂)(PMe₃)(Tp*-κ³N)]⊕

Formula Unicode styled:

fac–[Ir(Me)(N₂)(PMe₃)(Tp*-κ³N)]⊕

Compound name(s):

(Hydrogen tris(3,5-dimethylpyrazolyl)borate)-(dinitrogen)-methyl-(trimethylphosphine)-iridium(1+)

Central atom:

Attached groups:

N₂ (dinitrogen)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

fac–[Ir(H)(Me)(SiEt₃)(PMe₃)₃]

Formula Unicode styled:

fac–[Ir(H)(Me)(SiEt₃)(PMe₃)₃]

Compound name(s):

Hydrido-triethylsilyl-tris(trimethylphosphino)-methyl-iridium

Central atom:

Attached groups:

H (hydrido)

SiEt₃ (triethylsilyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: