Iridium

Attached groups:

NO (nitrosyl, linear)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (-I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁴O^-IE¹⁸B⁶X¹L⁴Z¹»

[MLXZ]𝘲 class:

[MX₁L₄Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(CO)(PPh₃)(η⁶-C₇H₈)]⊕

Formula Unicode styled:

[Ir(CO)(PPh₃)(η⁶-C₇H₈)]⊕

Compound name(s):

(η⁶-Toluene)-carbonyl-(triphenylphosphine)-iridium(1+)

Central atom:

Attached groups:

C₇H₈ (toluene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X⁰L⁵»^⊕

[MLXZ]𝘲 class:

[ML₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ir(CO)(PPh₃)(η⁶-C₆H₆)]⊕

Formula Unicode styled:

[Ir(CO)(PPh₃)(η⁶-C₆H₆)]⊕

Compound name(s):

(η⁶-Benzene)-carbonyl-(triphenylphosphine)-iridium(1+)

Central atom:

Attached groups:

C₆H₆ (benzene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X⁰L⁵»^⊕

[MLXZ]𝘲 class:

[ML₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ir(CO)(PPh₃)(Dedtc)]

Formula Unicode styled:

[Ir(CO)(PPh₃)(Dedtc)]

Compound name(s):

Carbonyl-(N,N'-diethyldithiocarbamato)-(triphenylphosphine)-iridium

Central atom:

Attached groups:

Dedtc (diethyldithiocarbamato-κ²S)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Ir(CO)(NHXy)(PPh₃)₂]

Formula Unicode styled:

[Ir(CO)(NHXy)(PPh₃)₂]

Compound name(s):

Carbonyl-(3,5-dimethylphenylamino)-bis(triphenyl-phosphino)-iridium

Central atom:

Attached groups:

NHXy (xylylamino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Ir(CO)(Dedtc)(Cp*)]⊕

Formula Unicode styled:

[Ir(CO)(Dedtc)(Cp*)]⊕

Compound name(s):

Carbonyl-(diethyldithiocarbamato)-(η⁵-pentamethylcyclopentadienyl)-iridium(1+)

Central atom:

Attached groups:

Dedtc (diethyldithiocarbamato-κ²S)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(CNMe)(Dppe-κ²P)₂]⊕

Formula Unicode styled:

[Ir(CNMe)(Dppe-κ²P)₂]⊕

Compound name(s):

Methyl isocyanide-bis(1,2-bis(diphenylphosphino)ethane-P,P')-iridium(1+)

Central atom:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Attached groups:

CNMe (methyl isocyanide)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X⁰L⁵»^⊕

[MLXZ]𝘲 class:

[ML₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ir(CNMe)(CO)(PPh₃)₂]⊕

Formula Unicode styled:

[Ir(CNMe)(CO)(PPh₃)₂]⊕

Compound name(s):

Acetonitrile-carbonyl-bis(triphenylphosphine)-iridium(1+)

Central atom:

Attached groups:

CNMe (methyl isocyanide)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X⁰L⁴»^⊕

[MLXZ]𝘲 class:

[ML₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Ir(CN)₆]³⊖

Formula Unicode styled:

[Ir(CN)₆]³⊖

Compound name(s):

hexacyanoiridium(3-)

Central atom:

Attached groups:

CN (cyano-κC)

Charge on central atom:

-3

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰L⁰X⁶»^3⊖

[MLXZ]𝘲 class:

[MX₆]^3-

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(CN)₃(Cp*)]⊖

Formula Unicode styled:

[Ir(CN)₃(Cp*)]⊖

Compound name(s):

(η⁵-pentamethylcyclopentadienyl)-tri-cyano-iridium(1-)

Central atom:

Attached groups:

CN (cyano-κC)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X⁴L²»^⊖

[MLXZ]𝘲 class:

[MX₄L₂]^-

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(CH₂SiMe₃)(CO){P(OMe)₃}₃]

Formula Unicode styled:

[Ir(CH₂SiMe₃)(CO){P(OMe)₃}₃]

Compound name(s):

Carbonyl-tris(trimethylphosphite)-trimethylsilylmethyl-iridium

Central atom:

CH₂SiMe₃ (trimethylsilylmethyl)

Attached groups:

P(OMe)₃ (trimethylphosphite)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ir(CH₂OMe)(TolC≡CTol)(PMe₃)₃]

Formula Unicode styled:

[Ir(CH₂OMe)(TolC≡CTol)(PMe₃)₃]

Compound name(s):

(Methoxymethyl)-(η²-di-p-tolylacetylene)-tris(trimethylphosphine)-iridium

Central atom:

TolC≡CTol (ditolylethyne)

Attached groups:

CH₂OMe (methoxymethyl)

PMe₃ (trimethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ir(CH₂Cl)(CO)₂(Cp*)]⊕

Formula Unicode styled:

[Ir(CH₂Cl)(CO)₂(Cp*)]⊕

Compound name(s):

Dicarbonyl-(η⁵-pentamethyl-cyclopentadienyl)-chloromethyl-iridium

Central atom:

Attached groups:

CH₂Cl (chloromethyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(CH₂=C=CH₂)₂(PMe₂Ph)₃]⊕

Formula Unicode styled:

[Ir(CH₂=C=CH₂)₂(PMe₂Ph)₃]⊕

Compound name(s):

bis(η²-Allene)-tris(dimethylphenylphosphine)-iridium(1+)

Central atom:

PMe₂Ph (dimethylphenylphosphane)

Attached groups:

CH₂=C=CH₂ (allene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X⁰L⁵»^⊕

[MLXZ]𝘲 class:

[ML₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ir(CF₃)(I)(PMe₃)(Cp*)]

Formula Unicode styled:

[Ir(CF₃)(I)(PMe₃)(Cp*)]

Compound name(s):

(Trifluoromethyl)-iodo-(trimethylphosphine)-(η⁵-pentamethylcyclopentadienyl)-iridium

Central atom:

PMe₃ (trimethylphosphane)

Attached groups:

CF₃ (trifluoromethyl)

I (iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(CF₃)(C₂F₄)(CO)(PPh₃)₂]

Formula Unicode styled:

[Ir(CF₃)(C₂F₄)(CO)(PPh₃)₂]

Compound name(s):

Carbonyl-(η²-tetrafluoroethene)-trifluoromethyl-cis-bis(triphenylphosphine)-iridium

Central atom:

Attached groups:

CF₃ (trifluoromethyl)

C₂F₄ (tetrafluoroethene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ir(CF₃)(=CF₂)(CO)(PPh₃)]

Formula Unicode styled:

[Ir(CF₃)(=CF₂)(CO)(PPh₃)]

Compound name(s):

Carbonyl-difluoromethylidene-trifluoromethyl-bis(triphenylphosphine)-iridium

Central atom:

=CF₂ (difluoromethylidene)

Attached groups:

CF₃ (trifluoromethyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁴O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Ir(C₈H₁₄)₂(η⁶-C₆H₆)]⊕

Formula Unicode styled:

[Ir(C₈H₁₄)₂(η⁶-C₆H₆)]⊕

Compound name(s):

(η⁶-Benzene)-bis(η²-cyclo-octene)-iridium(1+)

Central atom:

Attached groups:

C₈H₁₄ (cyclooctene)

C₆H₆ (benzene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X⁰L⁵»^⊕

[MLXZ]𝘲 class:

[ML₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ir(C₆H₄)(PMe₃)(Cp*)]

Formula Unicode styled:

[Ir(C₆H₄)(PMe₃)(Cp*)]

Compound name(s):

(η²-Benzyne)-(η⁵-pentamethylcyclopentadienyl)-(trimethylphosphine)-iridium

Central atom:

PMe₃ (trimethylphosphane)

Attached groups:

C₆H₄ (benzyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ir(C₆H₄-C₆H₄)(η²-Cod)(Cp)]

Formula Unicode styled:

[Ir(C₆H₄-C₆H₄)(η²-Cod)(Cp)]

Compound name(s):

(η⁵-cyclopentadienyl)-(η²-cycloocta-1,5-diene)-(biphenyl-2,2'-diyl)-iridium

Central atom:

Attached groups:

C₆H₄-C₆H₄ (biphenyl-κC²)

Cod (η²-cyclooctadiene)

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: