Iridium

Cp* (η⁵-pentamethylcyclopentadienyl)

Attached groups:

H (hydrido)

Ta group (X type)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

CN: 7

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V⁵C⁷O^OE¹⁸B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Ir(η⁴-Cod)₂]⊕

Formula Unicode styled:

[Ir(η⁴-Cod)₂]⊕

Compound name(s):

bis(cycloocta-1,5-diene)-iridium(1+)

Central atom:

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X⁰L⁴»^⊕

[MLXZ]𝘲 class:

[ML₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Ir(H)(PPh₃)₂(η⁴-Cod)]

Formula Unicode styled:

[Ir(H)(PPh₃)₂(η⁴-Cod)]

Compound name(s):

hydrido-bis(triphenylphosphine)-(cycloocta-1,5-diene)-iridium

Central atom:

PPh₃ (triphenylphosphane)

Attached groups:

H (hydrido)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

trans–[Ir₂(Cl)₂(CO)₂(μ₂-Dmpm)₂(MeO₂C)C≡C(CO₂Me)]

Formula Unicode styled:

trans–[Ir₂(Cl)₂(CO)₂(μ₂-Dmpm)₂(MeO₂C)C≡C(CO₂Me)]

Compound name(s):

(μ₂-dimethyl-acetylenedicarboxylate)-bis(bis(diphenylphosphino)-methane-P,P')-dicarbonyl-dichloro-di-iridium(Ir—Ir)

Central atom:

Attached groups:

Dmpm (μ₂-1,2-bis-(dimethylphosphino)methane)

(MeO₂C)C≡C(CO₂Me) (dimethylacetylenedicarboxylate X₂)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C^5.5O^IIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir₂(CO)₄(PPh₃)₂(μ₂-η²,η²-PhC≡CPh)]

Formula Unicode styled:

[Ir₂(CO)₄(PPh₃)₂(μ₂-η²,η²-PhC≡CPh)]

Compound name(s):

(μ₂-η²,η²-diphenylacetylene)-bis(dicarbonyl-triphenylphosphine-iridium)

Central atom:

Attached groups:

PPh₃ (triphenylphosphane)

PhC≡CPh (μ₂-η²,η²-diphenylethyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^OE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ir(μ₂-OSiMe₃)(η⁴-Cod)]₂

Formula Unicode styled:

[Ir(μ₂-OSiMe₃)(η⁴-Cod)]₂

Compound name(s):

bis-[(μ₂-Trimethylsiloxo)-(η²,η²-1,5-cyclo-octadiene)-iridium

Central atom:

OSiMe₃ (μ₂-trimethylsiloxy)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Ir(μ₂-OEt)(η⁴-Cod)]₂

Formula Unicode styled:

[Ir(μ₂-OEt)(η⁴-Cod)]₂

Compound name(s):

bis-[(μ₂-Ethoxo)-(η²,η²-1,5-cyclo-octadiene)-iridium

Central atom:

Attached groups:

OEt (μ₂-ethoxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Ir(μ₂-H)(Cp*)]₂

Formula Unicode styled:

[Ir(μ₂-H)(Cp*)]₂

Compound name(s):

bis-[(μ₂-Hydrido)-(η⁵-pentamethylcyclopentadienyl)-iridium(Ir—Ir)]

Central atom:

Cp* (η⁵-pentamethylcyclopentadienyl)

Attached groups:

H (μ₂-hydrido)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Cl)₂(μ₂-Cl)(OHMe)₂]₂

Formula Unicode styled:

[Ir(Cl)₂(μ₂-Cl)(OHMe)₂]₂

Compound name(s):

bis-[(μ₂-Chloro)-dichloro-di(methanol)-iridium]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Cl)(CO){P(OPh)₃}(μ₂-O₂CMe)]₂

Formula Unicode styled:

[Ir(Cl)(CO){P(OPh)₃}(μ₂-O₂CMe)]₂

Compound name(s):

bis-[(μ₂-Acetato-O,O')-carbonyl-chloro-(triphenylphosphite)-iridium(Ir—Ir)]

Central atom:

Attached groups:

P(OPh)₃ (triphenylphosphite)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Cl)(CO)(SbPh₃)(μ₂-O₂CMe)]₂

Formula Unicode styled:

[Ir(Cl)(CO)(SbPh₃)(μ₂-O₂CMe)]₂

Compound name(s):

bis-[(μ₂-Acetato-O,O')-carbonyl-chloro-(triphenylstibane)-iridium(Ir—Ir)]

Central atom:

Attached groups:

SbPh₃ (triphenylstibane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Cl)(CO)(Py)(μ₂-O₂CMe)]₂

Formula Unicode styled:

[Ir(Cl)(CO)(Py)(μ₂-O₂CMe)]₂

Compound name(s):

bis-[(μ₂-Acetato-O,O')-carbonyl-chloro-(pyridine)-iridium(Ir—Ir)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Cl)(CO)(NCMe)(μ₂-O₂CMe)]₂

Formula Unicode styled:

[Ir(Cl)(CO)(NCMe)(μ₂-O₂CMe)]₂

Compound name(s):

bis-[(μ₂-Acetato-O,O')-carbonyl-chloro-(acetonitrile)-iridium(Ir—Ir)]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Cl)(CO)(Dmso-κS)(μ₂-O₂CMe)]₂

Formula Unicode styled:

[Ir(Cl)(CO)(Dmso-κS)(μ₂-O₂CMe)]₂

Compound name(s):

bis-[(μ₂-Acetato-O,O')-carbonyl-chloro-(dimethylsulfoxide-S)-iridium(Ir—Ir)]

Central atom:

Attached groups:

Dmso (dimethylsulfoxide-κS)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Cl)(AsPh₃)(CO)(μ₂-O₂CMe)]₂

Formula Unicode styled:

[Ir(Cl)(AsPh₃)(CO)(μ₂-O₂CMe)]₂

Compound name(s):

bis-[(μ₂-Acetato-O,O')-carbonyl-chloro-(triphenylarsine)-iridium(Ir—Ir)]

Central atom:

Attached groups:

AsPh₃ (triphenylarsane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

catena–3D-[Ir(μ₂-F)₃]

Formula Unicode styled:

catena–3D-[Ir(μ₂-F)₃]

Compound name(s):

catena-[trifluoro-iridium]

iridium trifluoride

Central atom:

Attached groups:

F (μ₂-fluoro)

Charge on central atom:

0

Compound type:

Catena-3D

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

catena–3D-[Ir(μ₂-Cl)₃]

Formula Unicode styled:

catena–3D-[Ir(μ₂-Cl)₃]

Compound name(s):

catena-[trichloro-iridium]|iridium trichloride

Central atom:

Attached groups:

Cl (μ₂-chloro)

Charge on central atom:

0

Compound type:

Catena-3D

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

catena–3D-[Ir(μ₂-Br)₃]

Formula Unicode styled:

catena–3D-[Ir(μ₂-Br)₃]

Compound name(s):

catena-[tribromo-iridium]|iridium tribromide

Central atom:

Attached groups:

Br (μ₂-bromo)

Charge on central atom:

0

Compound type:

Catena-3D

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

PPrⁱ₃ (triisopropylphosphane)

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

trans–[Ir(Cl)(H)₂(η²-H₂)(PPrⁱ₃)₂]

Formula Unicode styled:

trans–[Ir(Cl)(H)₂(η²-H₂)(PPrⁱ₃)₂]

Compound name(s):

Chloro-dihydrogen-bis(tri-isopropylphosphine)-dihydrido-iridium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

PMe₃ (trimethylphosphane)

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

mer–[Ir(Cl)(H)(O₂CPh-κO)(PMe₃)]

Formula Unicode styled:

mer–[Ir(Cl)(H)(O₂CPh-κO)(PMe₃)]

Compound name(s):

(Benzoato)-chloro-hydrido-tris(trimethylphosphine)-iridium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):