[Re(Br)₂(μ₂-I)(PPh₃)]₃

Formula Unicode styled: 
[Re(Br)₂(μ₂-I)(PPh₃)]₃
Compound name(s): 
tris(μ-iodo)-tris(triphenylphosphine)-hexabromo-tri-rhenium
Central atom: 
Rhenium
Charge on formula unit (QN): 
0
Attached groups: 
Br (bromo)
I (μ₂-iodo)
PPh₃ (triphenylphosphane)
Compound type: 
Oligomer
DOI link to literature report: 
10.1016/j.poly.2023.116326
Crystal data CSD link: 
fifpet
Crystal data ICSD link: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Bond number (BN) = 𝘹 + 𝘭 + 𝘻: 
7
[MLXZ]𝘲 class: 
[MX5L2]
MLXZ class (ENC, equivalent neutral class): 
MX5L2
Summary of calculated classifications: 
Re«V5C6OIIIE16B7Z0X5L2»
Geometry: 
7-coordinate: pentagonal bipyramid (PBPY-7)
𝘥-electron configuration = 𝘮 – VN: 
d2
𝘥-electron configuration = 𝘮 – ON: 
d4
𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲: 
d2
Attached atoms: 
Br2I2P1Re1
Phase: 
Solid
InChIKey (see www.inchi-trust.org): 
MFNKDNXTRCCERP-UHFFFAOYSA-H