7-coordinate: pentagonal bipyramid (PBPY-7)

[U{(O)₂}(Cl)(μ₂-Cl)(Thf)₂]₂

Formula Unicode styled: 
[U{(O)₂}(Cl)(μ₂-Cl)(Thf)₂]₂
Compound name(s): 
bis-[(μ₂-Chloro)-chloro-dioxo-bis(tetrahydrofuran)-uranium]
Central atom: 
Uranium
Attached groups: 
(O)₂ (di{oxo ⭀O X₂L} trans Ⓢ)
Cl (chloro)
Cl (μ₂-chloro)
Thf (tetrahydrofuran)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 22
Summary of calculated classifications: 
U«V6C7OVIE22B11Z0X6L5»
[MLXZ]𝘲 class: 
[MX6L5]
MLXZ class (ENC, equivalent neutral class): 
MX6L5

[U(⭀NPh)₂(SO₃CF₃-κO)(μ₂-SO₃CF₃)(Thf)₂]₂

Formula Unicode styled: 
[U(⭀NPh)₂(SO₃CF₃-κO)(μ₂-SO₃CF₃)(Thf)₂]₂
Compound name(s): 
bis-[(μ₂-Trifluoromethanesulfonato-O,O')-bis(phenylimido)-bis-(tetrahydrofuran)-(trifluoromethanesulfonato-O)-uranium]
Central atom: 
Uranium
Attached groups: 
(⭀NPh)₂ (di(⭀NPh phenylimino) Ⓢ)
OSO₂CF₃ (trifluoromethanesulfonato-κO)
OSO₂CF₃ (μ₂-trifluoromethanesulfonato-κ²O)
Thf (tetrahydrofuran)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 22
Summary of calculated classifications: 
U«V6C7OVIE22B11Z0X6L5»
[MLXZ]𝘲 class: 
[MX6L5]
MLXZ class (ENC, equivalent neutral class): 
MX6L5

[Pu{(O)₂}(μ₂-O₂CPh)(Bpy)]₂

Formula Unicode styled: 
[Pu{(O)₂}(μ₂-O₂CPh)(Bpy)]₂
Compound name(s): 
bis-[(μ₂-Benzoato)-(μ₂-oxo)-oxo-(2,2'-dipyridyl)-plutonium]
Central atom: 
Plutonium
Attached groups: 
(O)₂ (di{oxo ⭀O X₂L} trans Ⓢ)
O₂CPh (μ₂-benzoato)
Bpy (bipyridine)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 23
Summary of calculated classifications: 
Pu«V5C7OVE23B10Z0X5L5»
[MLXZ]𝘲 class: 
[MX5L5]
MLXZ class (ENC, equivalent neutral class): 
MX5L5

[Np(Br)(SC₆F₅)(Se₂)(Py)₃]₂

Formula Unicode styled: 
[Np(Br)(SC₆F₅)(Se₂)(Py)₃]₂
Compound name(s): 
bis-[bromo-[μ-diselenido]-(2,3,4,5,6-pentafluorobenzene-1-thiolato)-tris(pyridine)-thorium]
Central atom: 
Neptunium
Attached groups: 
Br (bromo)
SC₆F₅ (pentafluorothiophenyl)
Se₂ (perseleno-κ²Se)
Py (pyridine)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 17
Summary of calculated classifications: 
Np«V4C7OIVE17B7Z0X4L3»
[MLXZ]𝘲 class: 
[MX4L3]
MLXZ class (ENC, equivalent neutral class): 
MX4L3

[Np(O)(μ₂–O)(μ₂-O₂CPh)(Phen)]

Formula Unicode styled: 
[Np(O)(μ₂–O)(μ₂-O₂CPh)(Phen)]
Compound name(s): 
bis-[(μ₂-Benzoato)-(μ₂-oxo)-oxo-(1,10-phenanthroline)-neptunium]
Central atom: 
Neptunium
Attached groups: 
O (oxo X₂)
O (μ₂–oxo X₂L)
O₂CPh (μ₂-benzoato)
Phen (phenanthroline)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 20
Summary of calculated classifications: 
Np«V5C7OVE20B9Z0X5L4»
[MLXZ]𝘲 class: 
[MX5L4]
MLXZ class (ENC, equivalent neutral class): 
MX5L4

[Np(O)(μ₂–O)(μ₂-O₂CPh)(Bpy)]

Formula Unicode styled: 
[Np(O)(μ₂–O)(μ₂-O₂CPh)(Bpy)]
Compound name(s): 
bis-[(μ₂-Benzoato)-(μ₂-oxo)-oxo-(2,2'-dipyridyl)-neptunium]
Central atom: 
Neptunium
Attached groups: 
O (oxo ⭀O X₂L)
O (μ₂–oxo X₂L)
O₂CPh (μ₂-benzoato)
Bpy (bipyridine)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 22
Summary of calculated classifications: 
Np«V5C7OVE22B10Z0X5L5»
[MLXZ]𝘲 class: 
[MX5L5]
MLXZ class (ENC, equivalent neutral class): 
MX5L5

catena–2D-[U{(O)₂}{μ₂-O₂P(OEt)₂}₂(Dmso-κO)]

Formula Unicode styled: 
catena–2D-[U{(O)₂}{μ₂-O₂P(OEt)₂}₂(Dmso-κO)]
Compound name(s): 
catena-[bis(μ₂-Diethylphosphato)-(dimethylsulfoxide)-dioxo-uranium]
Central atom: 
Uranium
Attached groups: 
(O)₂ (di{oxo ⭀O X₂L} trans Ⓢ)
O₂P(OEt)₂ (μ₂-diethylphosphate)
Dmso (dimethylsulfoxide-κO)
Charge on central atom: 
0
Compound type: 
Catena-2D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 22
Summary of calculated classifications: 
U«V6C7OVIE22B11Z0X6L5»
[MLXZ]𝘲 class: 
[MX6L5]
MLXZ class (ENC, equivalent neutral class): 
MX6L5

catena–1D-[U{(O)₂}(μ₂-SO₄)₂(OH₂)]²⊖

Formula Unicode styled: 
catena–1D-[U{(O)₂}(μ₂-SO₄)₂(OH₂)]²⊖
Compound name(s): 
catena-[bis(μ₂-sulfato-O,O')-aqua-dioxo-uranium(4-)]
Central atom: 
Uranium
Attached groups: 
(O)₂ (di{oxo ⭀O X₂L} trans Ⓢ)
SO₄ (μ₂-sulphato)
OH₂ (aqua)
Charge on central atom: 
-2
Compound type: 
Catena-1D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 22
Summary of calculated classifications: 
U«V6C7OVIE22B11Z0X8L3»2⊖
[MLXZ]𝘲 class: 
[MX8L3]2-
MLXZ class (ENC, equivalent neutral class): 
MX6L5

catena–2D-[Np{(O)₂}(OSO₂Me-κO²)₂(OH₂)]

Formula Unicode styled: 
catena–2D-[Np{(O)₂}(OSO₂Me-κO²)₂(OH₂)]
Compound name(s): 
catena-[bis(μ-methanesulfonato)-aqua-dioxo-neptunium]
Central atom: 
Neptunium
Attached groups: 
(O)₂ (di{oxo ⭀O X₂L} trans Ⓢ)
OSO₂Me (methanesulfonato-κO²)
OH₂ (aqua)
Charge on central atom: 
0
Compound type: 
Catena-2D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 23
Summary of calculated classifications: 
Np«V6C7OVIE23B11Z0X6L5»
[MLXZ]𝘲 class: 
[MX6L5]
MLXZ class (ENC, equivalent neutral class): 
MX6L5

[Bi(I)₄(Terpy-κ³N)]⊖

Formula Unicode styled: 
[Bi(I)₄(Terpy-κ³N)]⊖
Compound name(s): 
tetrakis(iodo)-(2,2':6',2''-terpyridine)-bismuth(1-)
Central atom: 
Bismuth
Attached groups: 
I (iodo)
Terpy (terpyridine-κ³N)
Charge on central atom: 
-1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Bi«V3C7OIIIE16B7Z0X4L3»⊖
[MLXZ]𝘲 class: 
[MX4L3]-
MLXZ class (ENC, equivalent neutral class): 
MX3L4

[Bi(I)₂(Py)₃{(OPPh₂)₂CH₂}]⊕

Formula Unicode styled: 
[Bi(I)₂(Py)₃{(OPPh₂)₂CH₂}]⊕
Compound name(s): 
Di-iodo-(bis(diphenylphosphinyl)methane)-tripyridine-bismuth(1+)
Central atom: 
Bismuth
Attached groups: 
I (iodo)
Py (pyridine)
(OPPh₂)₂CH₂ (bis(diphenylphosphinoyl)methane)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Bi«V3C7OIIIE16B7Z0X2L5»⊕
[MLXZ]𝘲 class: 
[MX2L5]+
MLXZ class (ENC, equivalent neutral class): 
MX3L4

[Bi(I)₂(Dedtc)(Terpy-κ³N)]

Formula Unicode styled: 
[Bi(I)₂(Dedtc)(Terpy-κ³N)]
Compound name(s): 
(N,N-Diethyldithiocarbamato)-di-iodo-(2,2':6',2''-terpyridyl)-bismuth
Central atom: 
Bismuth
Attached groups: 
I (iodo)
Dedtc (diethyldithiocarbamato-κ²S)
Terpy (terpyridine-κ³N)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Bi«V3C7OIIIE16B7Z0X3L4»
[MLXZ]𝘲 class: 
[MX3L4]
MLXZ class (ENC, equivalent neutral class): 
MX3L4

catena–2D-[Tc(Cl)(μ₂-Cl)₂]

Formula Unicode styled: 
catena–2D-[Tc(Cl)(μ₂-Cl)₂]
Compound name(s): 
catena-trichloro-technetium]
technetium trichloride
Central atom: 
Technetium
Attached groups: 
Cl (chloro)
Cl (μ₂-chloro)
Charge on central atom: 
0
Compound type: 
Catena-2D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 7
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Tc«V7C7OIIIE18B9Z0X7L2»
[MLXZ]𝘲 class: 
[MX7L2]
MLXZ class (ENC, equivalent neutral class): 
MX7L2

catena–2D-[Re(Cl)(μ₂-Cl)₂]

Formula Unicode styled: 
catena–2D-[Re(Cl)(μ₂-Cl)₂]
Compound name(s): 
catena-[trichloro-rhenium(Re=Re)]
trirhenium nonachloride
rhenium trichloride
Central atom: 
Rhenium
Attached groups: 
Cl (chloro)
Cl (μ₂-chloro)
Charge on central atom: 
0
Compound type: 
Catena-2D
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 7
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Re«V7C7OIIIE18B9Z0X7L2»
[MLXZ]𝘲 class: 
[MX7L2]
MLXZ class (ENC, equivalent neutral class): 
MX7L2

[Zr(F)₅(μ₂-F)]₂⁴⊖

Formula Unicode styled: 
[Zr(F)₅(μ₂-F)]₂⁴⊖
Compound name(s): 
bis-[(μ₂-fluoro)-pentafluoro-zirconium(2-)]
Central atom: 
Zirconium
Attached groups: 
F (fluoro)
F (μ₂-fluoro)
Charge on central atom: 
-2
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
Zr«V4C7OIVE14B7Z0X6L1»2⊖
[MLXZ]𝘲 class: 
[MX6L1]2-
MLXZ class (ENC, equivalent neutral class): 
MX4L3

[Zr(F)₃(μ₂-F){O=CH(NMe₂)-κO}₂]₂

Formula Unicode styled: 
[Zr(F)₃(μ₂-F){O=CH(NMe₂)-κO}₂]₂
Compound name(s): 
bis-[(μ₂-Fluoro)-bis(N,N-dimethylformamide)-trifluoro-zirconium]
Central atom: 
Zirconium
Attached groups: 
F (fluoro)
F (μ₂-fluoro)
O=CH(NMe₂) (dimethylformamido-κO)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
Zr«V4C7OIVE14B7Z0X4L3»
[MLXZ]𝘲 class: 
[MX4L3]
MLXZ class (ENC, equivalent neutral class): 
MX4L3

[Zr(F)₃(μ₂-F)(Dmso-κO)₂]₂

Formula Unicode styled: 
[Zr(F)₃(μ₂-F)(Dmso-κO)₂]₂
Compound name(s): 
bis-[(μ₂-Fluoro)-bis(bis(dimethylsulfoxide)-trifluoro-zirconium]
Central atom: 
Zirconium
Attached groups: 
F (fluoro)
F (μ₂-fluoro)
Dmso (dimethylsulfoxide-κO)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
Zr«V4C7OIVE14B7Z0X4L3»
[MLXZ]𝘲 class: 
[MX4L3]
MLXZ class (ENC, equivalent neutral class): 
MX4L3

[Ti(Cl)(μ₂–O)(12-crown-4-κ⁴O)]₂²⊕

Formula Unicode styled: 
[Ti(Cl)(μ₂–O)(12-crown-4-κ⁴O)]₂²⊕
Compound name(s): 
bis-[chloro-(μ₂-oxo)-(12-crown-4)-titanium(1+)]
Central atom: 
Titanium
Attached groups: 
Cl (chloro)
O (μ₂–oxo X₂L)
12-crown-4 (12-crown-4-κ⁴O)
Charge on central atom: 
1
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Ti«V4C7OIVE16B8Z0X3L5»⊕
[MLXZ]𝘲 class: 
[MX3L5]+
MLXZ class (ENC, equivalent neutral class): 
MX4L4

[Hf(F)₄(μ₂-F)(OH₂)]₂²⊖

Formula Unicode styled: 
[Hf(F)₄(μ₂-F)(OH₂)]₂²⊖
Compound name(s): 
bis-[(μ₂-fluoro)-aqua-tetrafluoro-hafnium(1-)]
Central atom: 
Hafnium
Attached groups: 
F (fluoro)
F (μ₂-fluoro)
OH₂ (aqua)
Charge on central atom: 
-1
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
Hf«V4C7OIVE14B7Z0X5L2»⊖
[MLXZ]𝘲 class: 
[MX5L2]-
MLXZ class (ENC, equivalent neutral class): 
MX4L3

[Hf(F)₃(μ₂-F)(Dmso-κO)₂]₂

Formula Unicode styled: 
[Hf(F)₃(μ₂-F)(Dmso-κO)₂]₂
Compound name(s): 
bis-[(μ₂-Fluoro)-trifluoro-bis(dimethylsulfoxide)-hafnium]
Central atom: 
Hafnium
Attached groups: 
F (fluoro)
F (μ₂-fluoro)
Dmso (dimethylsulfoxide-κO)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
Hf«V4C7OIVE14B7Z0X4L3»
[MLXZ]𝘲 class: 
[MX4L3]
MLXZ class (ENC, equivalent neutral class): 
MX4L3