7-coordinate: ③₂-●-1 bent metallocene

[V(=NXy)(Cp*)₂]

Formula Unicode styled: 
[V(=NXy)(Cp*)₂]
Compound name(s): 
2,6-Dimethylphenylimido-bis(η-pentamethyl-cyclopentadienyl)-vanadium
Central atom: 
Vanadium
Attached groups: 
=NXy (xylylimino)
Cp* (η⁵-pentamethylcyclopentadienyl)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 17
Summary of calculated classifications: 
V«V4C7OIVE17B8Z0X4L4»
[MLXZ]𝘲 class: 
[MX4L4]
MLXZ class (ENC, equivalent neutral class): 
MX4L4

[Tm(I){η⁵-C₅H₂(SiMe₃)₃}₂]

Formula Unicode styled: 
[Tm(I){η⁵-C₅H₂(SiMe₃)₃}₂]
Compound name(s): 
bis(η⁵-1,2,4-tris(Trimethylsilyl)cyclopentadienyl)-iodo-thulium
Central atom: 
Thulium
Attached groups: 
I (iodo)
C₅H₂(SiMe₃)₃ (η⁵-tris(trimethylsilyl)cyclopentadienyl)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 26
Summary of calculated classifications: 
Tm«V3C7OIIIE26B7Z0X3L4»
[MLXZ]𝘲 class: 
[MX3L4]
MLXZ class (ENC, equivalent neutral class): 
MX3L4

[Tm(I){η⁵-C₅H₂(Buᵗ)₃}₂]

Formula Unicode styled: 
[Tm(I){η⁵-C₅H₂(Buᵗ)₃}₂]
Compound name(s): 
iodo-bis(η⁵-1,2,4-tris-(t-butyl)cyclopentadienyl)-thulium
Central atom: 
Thulium
Attached groups: 
I (iodo)
C₅H₂(Buᵗ)₃ (η⁵-tris(t-butyl)cyclopentadienyl)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 26
Summary of calculated classifications: 
Tm«V3C7OIIIE26B7Z0X3L4»
[MLXZ]𝘲 class: 
[MX3L4]
MLXZ class (ENC, equivalent neutral class): 
MX3L4

[Tm(Cl){η⁵-C₅H₂(Buᵗ)₃}₂]

Formula Unicode styled: 
[Tm(Cl){η⁵-C₅H₂(Buᵗ)₃}₂]
Compound name(s): 
bis(1,2,4-tri-t-butyl-cyclopentadienyl)-chloro-thulium
Central atom: 
Thulium
Attached groups: 
Cl (chloro)
C₅H₂(Buᵗ)₃ (η⁵-tris(t-butyl)cyclopentadienyl)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 26
Summary of calculated classifications: 
Tm«V3C7OIIIE26B7Z0X3L4»
[MLXZ]𝘲 class: 
[MX3L4]
MLXZ class (ENC, equivalent neutral class): 
MX3L4

[Tm(Thf){η⁵-C₅H₃(SiMe₃)₂}₂]

Formula Unicode styled: 
[Tm(Thf){η⁵-C₅H₃(SiMe₃)₂}₂]
Compound name(s): 
(tetrahydrofuran)-bis(η⁵-1,3-bis(trimethylsilyl)cyclopentadienyl)-thulium
Central atom: 
Thulium
Attached groups: 
Thf (tetrahydrofuran)
C₅H₃(SiMe₃)₂ (η⁵-bis(trimethylsilyl)cyclopentadienyl)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 27
Summary of calculated classifications: 
Tm«V2C7OIIE27B7Z0X2L5»
[MLXZ]𝘲 class: 
[MX2L5]
MLXZ class (ENC, equivalent neutral class): 
MX2L5

[Tm(Thf){η⁵-C₅H₃(Buᵗ)₂}₂]

Formula Unicode styled: 
[Tm(Thf){η⁵-C₅H₃(Buᵗ)₂}₂]
Compound name(s): 
bis(η⁵-1,3-Di-t-butyl-cyclopentadienyl)-(tetrahydrofuran)-thulium
Central atom: 
Thulium
Attached groups: 
Thf (tetrahydrofuran)
C₅H₃(Buᵗ)₂ (η⁵-bis(t-butyl)cyclopentadienyl)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 27
Summary of calculated classifications: 
Tm«V2C7OIIE27B7Z0X2L5»
[MLXZ]𝘲 class: 
[MX2L5]
MLXZ class (ENC, equivalent neutral class): 
MX2L5

[Tm(Thf){η⁵-C₅H₂(SiMe₃)₃}₂]

Formula Unicode styled: 
[Tm(Thf){η⁵-C₅H₂(SiMe₃)₃}₂]
Compound name(s): 
bis(η⁵-1,2,4-tris(Trimethylsilyl)cyclopentadienyl)-tetrahydrofuran-thulium
Central atom: 
Thulium
Attached groups: 
Thf (tetrahydrofuran)
C₅H₂(SiMe₃)₃ (η⁵-tris(trimethylsilyl)cyclopentadienyl)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 27
Summary of calculated classifications: 
Tm«V2C7OIIE27B7Z0X2L5»
[MLXZ]𝘲 class: 
[MX2L5]
MLXZ class (ENC, equivalent neutral class): 
MX2L5

[Tm(Thf){η⁵-C₅H₂(Buᵗ)₃}₂]

Formula Unicode styled: 
[Tm(Thf){η⁵-C₅H₂(Buᵗ)₃}₂]
Compound name(s): 
bis(η⁵-1,2,4-tris-(t-butyl)cyclopentadienyl)-(tetrahydrofuran-O)-thulium
Central atom: 
Thulium
Attached groups: 
Thf (tetrahydrofuran)
C₅H₂(Buᵗ)₃ (η⁵-tris(t-butyl)cyclopentadienyl)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 27
Summary of calculated classifications: 
Tm«V2C7OIIE27B7Z0X2L5»
[MLXZ]𝘲 class: 
[MX2L5]
MLXZ class (ENC, equivalent neutral class): 
MX2L5

[Tm(Thf)(C₄PMe₂Buᵗ₂)₂]

Formula Unicode styled: 
[Tm(Thf)(C₄PMe₂Buᵗ₂)₂]
Compound name(s): 
bis(η⁵-2,5-Di-t-butyl-3,4-dimethylphospholide)-(tetrahydrofuran)-thulium
Central atom: 
Thulium
Attached groups: 
Thf (tetrahydrofuran)
C₄PMe₂Buᵗ₂ (η⁵-2,5-di-t-butyl-3,4-dimethylphospholido)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 27
Summary of calculated classifications: 
Tm«V2C7OIIE27B7Z0X2L5»
[MLXZ]𝘲 class: 
[MX2L5]
MLXZ class (ENC, equivalent neutral class): 
MX2L5

[Tm(PhNNPh)(C₄PMe₂Buᵗ₂)₂]

Formula Unicode styled: 
[Tm(PhNNPh)(C₄PMe₂Buᵗ₂)₂]
Compound name(s): 
bis(η⁵-2,5-Di-t-butyl-3,4-dimethylphospholide)-(η²-azobenzene)-thulium
Central atom: 
Thulium
Attached groups: 
PhNNPh (diphenyldiazene)
C₄PMe₂Buᵗ₂ (η⁵-2,5-di-t-butyl-3,4-dimethylphospholido)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 8
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 29
Summary of calculated classifications: 
Tm«V2C8OIIE29B8Z0X2L6»
[MLXZ]𝘲 class: 
[MX2L6]
MLXZ class (ENC, equivalent neutral class): 
MX2L6

[Hf(PMe₃)(Cp)(η⁷-C₇H₇)]

Formula Unicode styled: 
[Hf(PMe₃)(Cp)(η⁷-C₇H₇)]
Compound name(s): 
(η-Cycloheptatrienyl)-(η-cyclopentadienyl)-(trimethylphosphine)-hafnium
Central atom: 
Hafnium
Attached groups: 
PMe₃ (trimethylphosphane)
Cp (η⁵-cyclopentadienyl)
C₇H₇ (η⁷-cycloheptatrienyl X₃L₂)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 8
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Hf«V4C8OIVE18B9Z0X4L5»
[MLXZ]𝘲 class: 
[MX4L5]
MLXZ class (ENC, equivalent neutral class): 
MX4L5