7-coordinate: ③₂-●-1 bent metallocene

Attached groups:

PhC≡CPh (diphenylethyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V²C⁷O^IIE¹⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Mo(PBuⁿ₃)(Cp)₂]

Formula Unicode styled:

[Mo(PBuⁿ₃)(Cp)₂]

Compound name(s):

(Tri-n-butylphosphine)-molybdocene

Central atom:

PBuⁿ₃ (tri-n-butylphosphane)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V²C⁷O^IIE¹⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Mo(OCH₂)(Cp)₂]

Formula Unicode styled:

[Mo(OCH₂)(Cp)₂]

Compound name(s):

bis(η-Cyclopentadienyl)-formaldehydo-molybdenum

Central atom:

Attached groups:

OCH₂ (formaldehyde-κC,O)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V²C⁷O^IIE¹⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Mo(O)(Cp*)₂]

Formula Unicode styled:

[Mo(O)(Cp*)₂]

Compound name(s):

Oxo-bis(η-pentamethylcyclopentadienyl)-molybdenum

Central atom:

Attached groups:

O (oxo X₂)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁴C⁷O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Mo(O)(η⁵-C₅H₄Me)₂]

Formula Unicode styled:

[Mo(O)(η⁵-C₅H₄Me)₂]

Compound name(s):

bis(Methyl-cyclopentadienyl)-oxo-molybdenum

Central atom:

C₅H₄Me (η⁵-methylcyclopentadienyl)

Attached groups:

O (oxo X₂)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁴C⁷O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Mo(HP—PH)(Cp)₂]

Formula Unicode styled:

[Mo(HP—PH)(Cp)₂]

Compound name(s):

bis(Cyclopentadienyl)biphosphino-molybdenum

Central atom:

Attached groups:

HP—PH (diphosphene X₂)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 8

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V⁴C⁸O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

[Mo(CO₂-κC,κO)(Cp)₂]

Formula Unicode styled:

[Mo(CO₂-κC,κO)(Cp)₂]

Compound name(s):

(η-Carbon dioxide)-bis(η-cyclopentadienyl)-molybdenum

Central atom:

CO₂ (carbon dioxide-κC,κO)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V²C⁷O^IIE¹⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Mo(CO)(Cp*)₂]

Formula Unicode styled:

[Mo(CO)(Cp*)₂]

Compound name(s):

Carbonyl-bis(η-pentamethylcyclopentadienyl)-molybdenum

Central atom:

Attached groups:

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V²C⁷O^IIE¹⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Mo(CNBuᵗ)(Cp)₂]

Formula Unicode styled:

[Mo(CNBuᵗ)(Cp)₂]

Compound name(s):

bis(η-Cyclopentadienyl)-(N-t-butylcyano)-molybdenum

Central atom:

CNBuᵗ (t-butyl isocyanide)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Mo«V²C⁷O^IIE¹⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Mo(CF₃C≡CCF₃)(η⁵-C₅H₄Me)₂]

Formula Unicode styled:

[Mo(CF₃C≡CCF₃)(η⁵-C₅H₄Me)₂]

Compound name(s):

(η-Hexafluorobut-2-yne)-bis(η-methylcyclopentadienyl)-molybdenum

Central atom:

CF₃C≡CCF₃ (bis(trifluoromethyl)ethyne)

Attached groups:

C₅H₄Me (η⁵-methylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

PMe₃ (trimethylphosphane)

Summary of calculated classifications:

Mo«V²C⁷O^IIE¹⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Nb(PMe₃)(η⁶-C₇H₈)₂]⊕

Formula Unicode styled:

[Nb(PMe₃)(η⁶-C₇H₈)₂]⊕

Compound name(s):

bis(η⁶-Toluene)-trimethylphosphine-niobium(1+)

Central atom:

Niobium

Attached groups:

C₇H₈ (toluene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V¹C⁷O^IE¹⁸B⁷Z⁰X⁰L⁷»^⊕

[MLXZ]𝘲 class:

[ML₇]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₆

[Nb(PhC≡CPh)(η⁶-C₆H₃Me₃)₂]⊕

Formula Unicode styled:

[Nb(PhC≡CPh)(η⁶-C₆H₃Me₃)₂]⊕

Compound name(s):

(eta²-Diphenylacetylene)-bis(η⁶-mesityl)-niobium(1+)

Central atom:

Niobium

Attached groups:

PhC≡CPh (diphenylethyne)

C₆H₃Me₃ (mesitylene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V¹C⁷O^IE¹⁸B⁷Z⁰X⁰L⁷»^⊕

[MLXZ]𝘲 class:

[ML₇]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₆

[Nb(CO)(η⁶-C₆H₃Me₃)₂]⊕

Formula Unicode styled:

[Nb(CO)(η⁶-C₆H₃Me₃)₂]⊕

Compound name(s):

bis(η⁶-Mesityl)-carbonyl-niobium(1+)

Central atom:

Niobium

Attached groups:

CO (carbonyl)

C₆H₃Me₃ (mesitylene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Nb«V¹C⁷O^IE¹⁸B⁷Z⁰X⁰L⁷»^⊕

[MLXZ]𝘲 class:

[ML₇]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₆

[Yb(Thf)(Cp*)₂]

Formula Unicode styled:

[Yb(Thf)(Cp*)₂]

Compound name(s):

bis(Pentamethyl-cyclopentadienyl)-tetrahydrofuran-ytterbium

Central atom:

Attached groups:

Thf (tetrahydrofuran)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Yb«V²C⁷O^IIE²⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Yb(Thf){η⁵-C₅H₄(SiMe₃)}₂]

Formula Unicode styled:

[Yb(Thf){η⁵-C₅H₄(SiMe₃)}₂]

Compound name(s):

bis(eta⁵-1,3-bis(Trimethylsilyl)-cyclopentadienyl)-tetrahydrofuran-ytterbium

Central atom:

C₅H₄(SiMe₃) (η⁵-(trimethylsilyl)cyclopentadienyl)

Attached groups:

Thf (tetrahydrofuran)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Yb«V²C⁷O^IIE²⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Yb(NPh₂)(Cp*)₂]

Formula Unicode styled:

[Yb(NPh₂)(Cp*)₂]

Compound name(s):

(Diphenylamido)-bis(eta⁵-pentamethylcyclopentadienyl)-ytterbium

Central atom:

NPh₂ (diphenylamino: planar)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 29

Summary of calculated classifications:

Yb«V³C⁷O^IIIE²⁹B⁸Z⁰X³L⁵»

[MLXZ]𝘲 class:

[MX₃L₅]

MLXZ class (ENC, equivalent neutral class):

MX₃L₅

[Yb(MeC≡CMe)(Cp*)₂]

Formula Unicode styled:

[Yb(MeC≡CMe)(Cp*)₂]

Compound name(s):

(eta²-(2-Butyne))-bis(eta⁵-pentamethyl-cyclopentadienyl)-ytterbium

Central atom:

Attached groups:

MeC≡CMe (butyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Yb«V²C⁷O^IIE²⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Yb(AlCp)(Cp)₂]

Formula Unicode styled:

[Yb(AlCp*)(Cp*)₂]

Compound name(s):

tris(eta⁵-Pentamethylcyclopentadienyl)-aluminium-ytterbium

Central atom:

AlCp* (pentamethylcyclopentadienylaluminium)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

C₅H₃(Buᵗ)₂ (η⁵-bis(t-butyl)cyclopentadienyl)

Summary of calculated classifications:

Yb«V²C⁷O^IIE²⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

[Hf(I){η⁵-C₅H₃(Buᵗ)₂}₂]

Formula Unicode styled:

[Hf(I){η⁵-C₅H₃(Buᵗ)₂}₂]

Compound name(s):

Iodo-bis(η⁵-1,3-di-t-butyl-cyclopentadienyl)-hafnium

Central atom:

Hafnium

Attached groups:

I (iodo)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Hf«V³C⁷O^IIIE¹⁵B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

[Zr(Me)(Cp*)₂]⊕

Formula Unicode styled:

[Zr(Me)(Cp*)₂]⊕

Compound name(s):

bis(η⁵-Pentamethyl-cyclopentadienyl)-methyl-zirconium(1+)

Central atom:

Zirconium

Attached groups:

Me (methyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):