5-coordinate (geometry not specified)

[Bi(PO₄-κ⁴O)]

Formula Unicode styled:

[Bi(PO₄-κ⁴O)]

Compound name(s):

catena-phosphato-bismuth]|bismuth phosphate

Central atom:

Bismuth

Attached groups:

PO₄ (phosphato-κ⁴O)

Charge on central atom:

Compound type:

Lattice

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 0

Summary of calculated classifications:

Bi«V³C⁵O^III»

[MLXZ]𝘲 class:

MLXZ class (ENC, equivalent neutral class):

[Re(Mes)(⭀NBuᵗ)(μ₃–O)]₂

Formula Unicode styled:

[Re(Mes)(⭀NBuᵗ)(μ₃–O)]₂

Compound name(s):

bis-[(t-Butylimido-N)-(μ₂-oxo)-mesityl-rhenium]

Central atom:

Rhenium

Attached groups:

Mes (mesityl)

⭀NBuᵗ (⭀N t-butylimino)

O (μ₃–oxo X₂L)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Re«V⁵C⁵O^VE¹⁶B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Re(CH₂SiMe₃)₂(≡CSiMe₃)]₂

Formula Unicode styled:

[Re(CH₂SiMe₃)₂(≡CSiMe₃)]₂

Compound name(s):

bis-[(Trimethylsilylmethylidyne)-bis(trimethylsilylmethyl)-rhenium(Re=Re)]

Central atom:

Rhenium

Attached groups:

CH₂SiMe₃ (trimethylsilylmethyl)

≡CSiMe₃ (trimethylsilylmethylidyne)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 7

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Re«V⁷C⁵O^VE¹⁴B⁷Z⁰L⁰X⁷»

[MLXZ]𝘲 class:

[MX₇]

MLXZ class (ENC, equivalent neutral class):

MX₇

[Pd(SO₂-κ²O)(PBz₃)]₃

Formula Unicode styled:

[Pd(SO₂-κ²O)(PBz₃)]₃

Compound name(s):

tris-[(μ₂-Sulfur dioxide)-(tribenzylphosphine)-palladium]

Central atom:

Palladium

Attached groups:

SO₂ (dioxosulfur-κ²O)

PBz₃ (tribenzylphosphane)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Pd«V²C⁵O^OE¹⁸B⁵Z⁰X²L³»

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Os(CO)₃(η³-C₇H₇)]⊖

Formula Unicode styled:

[Os(CO)₃(η³-C₇H₇)]⊖

Compound name(s):

tricarbonyl-(η3-cycloheptatrienyl)-osmium(1-)

Central atom:

Osmium

Attached groups:

CO (carbonyl)

C₇H₇ (η³-cycloheptatrienyl)

Charge on central atom:

-1

Compound type:

Molecular

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Os«V⁰C⁵O^OE¹⁸B⁵Z⁰X¹L⁴»^⊖

[MLXZ]𝘲 class:

[MX₁L₄]^-

MLXZ class (ENC, equivalent neutral class):

ML₅

[Os(⭀NBuᵗ)₂(μ₂-NBuᵗ)]₂²⊕

Formula Unicode styled:

[Os(⭀NBuᵗ)₂(μ₂-NBuᵗ)]₂²⊕

Compound name(s):

bis-[(μ₂-t-Butylimido)-bis(t-butylimido)-osmium(Os—Os)(1+)]

Central atom:

Osmium

Attached groups:

(⭀NBuᵗ)₂ (di(⭀NBuᵗ t-butylimino)-cis X₄L Ⓢ)

NBuᵗ (μ₂-t-butylimino X₂L)

Charge on central atom:

1

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 8

Oxidation Number (ON) (Roman numerals):

ON: (VII)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Os«V⁸C⁵O^VIIE¹⁸B⁹Z⁰X⁷L²»^⊕

[MLXZ]𝘲 class:

[MX₇L₂]⁺

MLXZ class (ENC, equivalent neutral class):

MX₈L₁

[W(Se)₂(μ₂-Se)]₂²⊖

Formula Unicode styled:

[W(Se)₂(μ₂-Se)]₂²⊖

Compound name(s):

bis-[(μ₂-selenido)-bis(selenido)-tungsten(W—W)(1-)]

Central atom:

Tungsten

Attached groups:

Se (seleno; ⭀Se)

Se (μ₂-seleno X–X)

Charge on central atom:

-1

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

W«V⁶C⁵O^VE¹⁸B⁹Z⁰X⁷L²»^⊖

[MLXZ]𝘲 class:

[MX₇L₂]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[W(S)₂(μ₂-S)]₂²⊖

Formula Unicode styled:

[W(S)₂(μ₂-S)]₂²⊖

Compound name(s):

bis-[μ₂-sulfido)-disulfido-tungsten(W—W)(1-)]

Central atom:

Tungsten

Attached groups:

S (thio)

S (μ₂-thio)

Charge on central atom:

-1

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

W«V⁶C⁵O^VE¹⁶B⁸Z⁰X⁷L¹»^⊖

[MLXZ]𝘲 class:

[MX₇L₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

[W(OPrⁱ)₂(≡CSiMe₃)]₂

Formula Unicode styled:

[W(OPrⁱ)₂(≡CSiMe₃)]₂

Compound name(s):

bis-[(μ₂-Trimethylsilylmethylidyne)-bis(isopropoxy)-tungsten(W—W)]

Central atom:

Tungsten

Attached groups:

OPrⁱ (isopropoxy)

≡CSiMe₃ (trimethylsilylmethylidyne)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 12

Summary of calculated classifications:

W«V⁶C⁵O^VE¹²B⁶Z⁰L⁰X⁶»

[MLXZ]𝘲 class:

[MX₆]

MLXZ class (ENC, equivalent neutral class):

MX₆

[W(OBuᵗ)₂(PhC≡CPh)]₂

Formula Unicode styled:

[W(OBuᵗ)₂(PhC≡CPh)]₂

Compound name(s):

bis-[μ₂-η⁴-Diphenylacetylene)-bis(t-butoxy)-tungsten(W≡W)]

Central atom:

Tungsten

Attached groups:

OBuᵗ (t-butyloxy)

PhC≡CPh (diphenylethyne L₂)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

W«V⁴C⁵O^IIE¹⁴B⁶Z⁰X⁴L²»

[MLXZ]𝘲 class:

[MX₄L₂]

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

[W(CH₂SiMe₃)₂(≡CSiMe₃)]₂

Formula Unicode styled:

[W(CH₂SiMe₃)₂(≡CSiMe₃)]₂

Compound name(s):

bis-[(μ₂-Trimethylsilylmethylidyne)-bis(trimethylsilylmethyl)-tungsten(W—W)]

Central atom:

Tungsten

Attached groups:

CH₂SiMe₃ (trimethylsilylmethyl)

≡CSiMe₃ (trimethylsilylmethylidyne)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 12

Summary of calculated classifications:

W«V⁶C⁵O^VE¹²B⁶Z⁰L⁰X⁶»

[MLXZ]𝘲 class:

[MX₆]

MLXZ class (ENC, equivalent neutral class):

MX₆

[V{N(SiMe₃)₂}₂(μ₂–O)]₂

Formula Unicode styled:

[V{N(SiMe₃)₂}₂(μ₂–O)]₂

Compound name(s):

bis-[(μ₂-Oxo)-bis(bis(trimethysilyl)amido)-vanadium(V—V)]

Central atom:

Vanadium

Attached groups:

N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar)

O (μ₂–oxo X₂L)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

V«V⁵C⁵O^IVE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[V(NMe₂)₂(μ₂-NBuᵗ)]₂

Formula Unicode styled:

[V(NMe₂)₂(μ₂-NBuᵗ)]₂

Compound name(s):

bis-[μ₂-Phenylimido)-bis(dimethylamido)-vanadium(V—V)]

Central atom:

Vanadium

Attached groups:

NMe₂ (dimethylamino: planar)

NBuᵗ (μ₂-t-butylimino X₂L)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

V«V⁵C⁵O^IVE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[V(NMe₂)₂(μ₂-NXy)]₂

Formula Unicode styled:

[V(NMe₂)₂(μ₂-NXy)]₂

Compound name(s):

bis-[μ₂-xylylimido)-bis(dimethylamido)-vanadium(V—V)]

Central atom:

Vanadium

Attached groups:

NMe₂ (dimethylamino: planar)

NXy (μ₂-xylylimino X₂L)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

V«V⁵C⁵O^IVE¹⁶B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

[V(Mes)₂(μ₂-NTol)]₂

Formula Unicode styled:

[V(Mes)₂(μ₂-NTol)]₂

Compound name(s):

bis-[(μ₂-p-Tolylimido)-bismesityl-vanadium(V—V)]

Central atom:

Vanadium

Attached groups:

Mes (mesityl)

NTol (μ₂-tolylimino X₂L)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 12

Summary of calculated classifications:

V«V⁵C⁵O^IVE¹²B⁶Z⁰X⁵L¹»

[MLXZ]𝘲 class:

[MX₅L₁]

MLXZ class (ENC, equivalent neutral class):

MX₅L₁

[V(CH₂SiMe₃)(OBuᵗ)(μ₂-NBuᵗ)]₂

Formula Unicode styled:

[V(CH₂SiMe₃)(OBuᵗ)(μ₂-NBuᵗ)]₂

Compound name(s):

bis-[trimethylsilylmethyl-(t-butoxy)-(μ₂-t-butylamido-N,N)-vanadium(V—V)]

Central atom:

Vanadium

Attached groups:

CH₂SiMe₃ (trimethylsilylmethyl)

OBuᵗ (t-butyloxy)

NBuᵗ (μ₂-t-butylimino X₂L)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 12

Summary of calculated classifications:

V«V⁵C⁵O^IVE¹²B⁶Z⁰X⁵L¹»

[MLXZ]𝘲 class:

[MX₅L₁]

MLXZ class (ENC, equivalent neutral class):

MX₅L₁

[V(CH₂Buᵗ)(OBuᵗ)(μ₂-NBuᵗ)]₂

Formula Unicode styled:

[V(CH₂Buᵗ)(OBuᵗ)(μ₂-NBuᵗ)]₂

Compound name(s):

bis-[Neopentyl-(t-butoxy)-(μ₂-t-butylamido-N,N)-vanadium(V—V)]

Central atom:

Vanadium

Attached groups:

CH₂Buᵗ (t-butylmethyl)

OBuᵗ (t-butyloxy)

NBuᵗ (μ₂-t-butylimino X₂L)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 12

Summary of calculated classifications:

V«V⁵C⁵O^IVE¹²B⁶Z⁰X⁵L¹»

[MLXZ]𝘲 class:

[MX₅L₁]

MLXZ class (ENC, equivalent neutral class):

MX₅L₁

[Ta(H)₂{OSi(OBuᵗ₃)}₂]₂

Formula Unicode styled:

[Ta(H)₂{OSi(OBuᵗ₃)}₂]₂

Compound name(s):

bis-[di(μ₂-Hydrido)-bis(tri-t-butylsilyloxy)-tantalum(Ta—Ta)]

Central atom:

Tantalum

Attached groups:

H (hydrido)

OSi(OBuᵗ)₃ (tri-t-butoxy-siloxy)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 10

Summary of calculated classifications:

Ta«V⁵C⁵O^IVE¹⁰B⁵Z⁰L⁰X⁵»

[MLXZ]𝘲 class:

[MX₅]

MLXZ class (ENC, equivalent neutral class):

MX₅

[Ta(Cl){N(SiMe₃)₂}(μ₂-NSiMe₃)]₂

Formula Unicode styled:

[Ta(Cl){N(SiMe₃)₂}(μ₂-NSiMe₃)]₂

Compound name(s):

bis-[(μ₂-Trimethylsilylamido)-chloro-(bis(trimethylsilyl)amido)-tantalum(Ta—Ta)]

Central atom:

Tantalum

Attached groups:

Cl (chloro)

N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar)

NSiMe₃ (μ₂-trimethylsilylimino X₂L)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

Ta«V⁵C⁵O^IVE¹⁴B⁷Z⁰X⁵L²»

[MLXZ]𝘲 class:

[MX₅L₂]

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Mo(OPrⁱ)₂(Py)₂]₂

Formula Unicode styled:

[Mo(OPrⁱ)₂(Py)₂]₂

Compound name(s):

bis-[bis(Isopropoxy)-bis(pyridyl)-molybdenum(Mo≣Mo)]

Central atom:

Molybdenum

Attached groups:

OPrⁱ (isopropoxy)

Py (pyridine)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Mo«V⁶C⁵O^IIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂