[V{N(SiMe₃)₂}₂(μ₂–O)]₂

Formula Unicode styled: 
[V{N(SiMe₃)₂}₂(μ₂–O)]₂
Compound name(s): 
bis-[(μ₂-Oxo)-bis(bis(trimethysilyl)amido)-vanadium(V—V)]
Central atom: 
Vanadium
Charge on formula unit (QN): 
0
Attached groups: 
N(SiMe₃)₂ (bis(trimethylsilyl)amino: planar)
O (μ₂–oxo X₂L)
Compound type: 
Oligomer
DOI link to literature report: 
10.1021/ja960226v
Crystal data CSD link: 
taxhuv
Crystal data ICSD link: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Bond number (BN) = 𝘹 + 𝘭 + 𝘻: 
8
[MLXZ]𝘲 class: 
[MX5L3]
MLXZ class (ENC, equivalent neutral class): 
MX5L3
Summary of calculated classifications: 
V«V5C5OIVE16B8Z0X5L3»
Geometry: 
5-coordinate (geometry not specified)
𝘥-electron configuration = 𝘮 – VN: 
d0
𝘥-electron configuration = 𝘮 – ON: 
d1
𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲: 
d0
Attached atoms: 
N2O2V1
Phase: 
Solid
InChIKey (see www.inchi-trust.org): 
RXQBOISBXCRJEE-UHFFFAOYNA-N