4-coordinate: square plane (SP-4)

PPh₃ (triphenylphosphane)

Attached groups:

SMes (mesitylthio)

NO (nitrosyl, linear)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V⁵C⁴O^IE¹⁶B⁶X³L²Z¹»

[MLXZ]𝘲 class:

[MX₃L₂Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₅L₁

cis–[Ir(μ₂-SBuᵗ)(CO){P(OMe)₃}]₂

Formula Unicode styled:

cis–[Ir(μ₂-SBuᵗ)(CO){P(OMe)₃}]₂

Compound name(s):

bis(mu-t-Butylthiolato)-bis(carbonyl-trimethylphosphite-iridium)

Central atom:

Attached groups:

SBuᵗ (t-butylthio-μ₂)

P(OMe)₃ (trimethylphosphite)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(μ₂-Pz)(η⁴-Cod)]₂

Formula Unicode styled:

cis–[Ir(μ₂-Pz)(η⁴-Cod)]₂

Compound name(s):

bis((η⁴-Cyclo-octadiene)-(μ₂-pyrazolyl)-iridium)

Central atom:

Attached groups:

Pz (μ₂-pyrazolyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(PCy₃)(Py)(η⁴-Cod)]⊕

Formula Unicode styled:

cis–[Ir(PCy₃)(Py)(η⁴-Cod)]⊕

Compound name(s):

(Tricyclohexylphosphine)-(η⁴-cycloocta-1,5-diene)-(pyridine)-iridium(1+)

Central atom:

Attached groups:

Py (pyridine)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X⁰L⁴»^⊕

[MLXZ]𝘲 class:

[ML₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(OSiMe₃)(PCy₃)(η⁴-Cod)]

Formula Unicode styled:

cis–[Ir(OSiMe₃)(PCy₃)(η⁴-Cod)]

Compound name(s):

(Tricyclohexylphosphine)-(trimethylsiloxy)-(η⁴-cycloocta-1,5-diene)-iridium

Central atom:

Attached groups:

OSiMe₃ (trimethylsiloxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(OSiMe₃)(CO)₂(PCy₃)]

Formula Unicode styled:

cis–[Ir(OSiMe₃)(CO)₂(PCy₃)]

Compound name(s):

Dicarbonyl-(tricyclohexylphosphine)-(trimethylsiloxy)-iridium

Central atom:

Attached groups:

OSiMe₃ (trimethylsiloxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(Mes)(CO)(PPh₃)₂]

Formula Unicode styled:

cis–[Ir(Mes)(CO)(PPh₃)₂]

Compound name(s):

Carbonyl-mesityl-bis(triphenylphosphine)-iridium

Central atom:

Attached groups:

Mes (mesityl)

PPh₃ (triphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(Mes)(CO)(Dppe-κ²P)]

Formula Unicode styled:

cis–[Ir(Mes)(CO)(Dppe-κ²P)]

Compound name(s):

Carbonyl-(2,4,6-trimethylphenyl)-(1,2-bis(diphenylphosphino) ethane)-iridium

Central atom:

Attached groups:

Mes (mesityl)

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(Hfa)(η⁴-Cod)]

Formula Unicode styled:

cis–[Ir(Hfa)(η⁴-Cod)]

Compound name(s):

(η⁴-1,5-Cyclooctadiene)-(hexafluoroacetylacetonato)-iridium

Central atom:

Hfa (hexafluoroacetylacetonato)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(Dmso-κS)₂(Py)₂]⊕

Formula Unicode styled:

cis–[Ir(Dmso-κS)₂(Py)₂]⊕

Compound name(s):

bis(Dimethylsulfoxide)-bis(pyridine)-iridium(1+)

Central atom:

Dmso (dimethylsulfoxide-κS)

Attached groups:

Py (pyridine)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X⁰L⁴»^⊕

[MLXZ]𝘲 class:

[ML₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(CO)₂(μ₂-AsBuᵗ₂)]₂

Formula Unicode styled:

cis–[Ir(CO)₂(μ₂-AsBuᵗ₂)]₂

Compound name(s):

bis(μ₂-Di-t-butylarsino)-tetracarbonyl-di-iridium

Central atom:

Attached groups:

AsBuᵗ₂ (μ₂-bis-t-butyl-arsanyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(CO)₂(μ₂-Pz)]₂

Formula Unicode styled:

cis–[Ir(CO)₂(μ₂-Pz)]₂

Compound name(s):

bis(μ₂-Pyrazolyl)-bis(dicarbonyl-di-iridium

Central atom:

Attached groups:

Pz (μ₂-pyrazolyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(CO)₂(μ₂-PBuᵗ₂)]₂

Formula Unicode styled:

cis–[Ir(CO)₂(μ₂-PBuᵗ₂)]₂

Compound name(s):

bis(μ₂-Di-t-butylphosphino)-tetracarbonyl-di-iridium Ir=Ir

Central atom:

Attached groups:

PBuᵗ₂ (μ₂-dibutylphosphanyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Summary of calculated classifications:

Ir«V³C⁴O^IE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

cis–[Ir(CO)₂(μ₂-NH₂)]₂

Formula Unicode styled:

cis–[Ir(CO)₂(μ₂-NH₂)]₂

Compound name(s):

bis(μ₂-Amido)-tetracarbonyl-di-iridium

Central atom:

Attached groups:

NH₂ (μ₂-amino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(CO)₂(Acac)]

Formula Unicode styled:

cis–[Ir(CO)₂(Acac)]

Compound name(s):

Dicarbonyl-(acetylacetonato-O,O')-iridium

Central atom:

Attached groups:

Acac (acetylacetonato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(CO)(μ₂-Pz)(PPh₃)]₂

Formula Unicode styled:

cis–[Ir(CO)(μ₂-Pz)(PPh₃)]₂

Compound name(s):

Dicarbonyl-bis(triphenylphosphine)-bis(μ₂-pyrazolyl)-di-iridium

Central atom:

Attached groups:

PPh₃ (triphenylphosphane)

Pz (μ₂-pyrazolyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(CH₂CN)₂(CO)₂]⊖

Formula Unicode styled:

cis–[Ir(CH₂CN)₂(CO)₂]⊖

Compound name(s):

dicarbonyl-bis(cyanomethyl)-iridium(1-)

Central atom:

Attached groups:

CH₂CN (cyanomethyl)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X²L²»^⊖

[MLXZ]𝘲 class:

[MX₂L₂]^-

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(C₈H₁₄)₂(Acac)]

Formula Unicode styled:

cis–[Ir(C₈H₁₄)₂(Acac)]

Compound name(s):

(Acetylacetonato-O,O')-bis(η²-cyclo-octene)-iridium

Central atom:

Attached groups:

C₈H₁₄ (cyclooctene)

Acac (acetylacetonato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(C₈H₁₄)(PCy₃)(Acac)]

Formula Unicode styled:

cis–[Ir(C₈H₁₄)(PCy₃)(Acac)]

Compound name(s):

(η²-cyclooctene)-tricyclohexylphosphine-acetylacetonato-iridium

Central atom:

Attached groups:

C₈H₁₄ (cyclooctene)

Acac (acetylacetonato)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

cis–[Ir(C₆Cl₅)₂(η⁴-Cod)]

Formula Unicode styled:

cis–[Ir(C₆Cl₅)₂(η⁴-Cod)]

Compound name(s):

(η⁴-1,5-Cyclo-octadiene)-bis(pentachlorophenyl)-iridium

Central atom:

C₆Cl₅ (pentachlorophenyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):