4-coordinate: square plane (SP-4)

Attached groups:

PCy₃ (tricyclohexylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

trans–[Ir(Cl)(C₂H₄)(PPh₃)₂]

Formula Unicode styled:

trans–[Ir(Cl)(C₂H₄)(PPh₃)₂]

Compound name(s):

Chloro-ethylene-bis(triphenylphosphine) iridium

Central atom:

Attached groups:

C₂H₄ (ethene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

trans–[Ir(Cl)(=CPh₂)(PPrⁱ₃)₂]

Formula Unicode styled:

trans–[Ir(Cl)(=CPh₂)(PPrⁱ₃)₂]

Compound name(s):

Chloro-(diphenylmethylidene)-bis(triisopropylphosphine)-iridium

Central atom:

Attached groups:

=CPh₂ (diphenylmethylidene)

PPrⁱ₃ (triisopropylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁴O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

trans–[Ir(SC₆F₅)(CO)(PPh₃)₂]

Formula Unicode styled:

trans–[Ir(SC₆F₅)(CO)(PPh₃)₂]

Compound name(s):

Carbonyl-(pentafluorophenylthiolato)-bis(triphenylphosphine)-iridium

Central atom:

SC₆F₅ (pentafluorothiophenyl)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

trans–[Ir(OSiMe₃)(CO)(PPh₃)₂]

Formula Unicode styled:

trans–[Ir(OSiMe₃)(CO)(PPh₃)₂]

Compound name(s):

Carbonyl-bis(triphenylphosphine)-(trimethylsiloxy)-iridium

Central atom:

Attached groups:

OSiMe₃ (trimethylsiloxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

trans–[Ir(OPh)(CO)(PPh₃)₂]

Formula Unicode styled:

trans–[Ir(OPh)(CO)(PPh₃)₂]

Compound name(s):

Carbonyl-phenoxy-bis(triphenylphosphine)-iridium

Central atom:

Attached groups:

OPh (phenoxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

trans–[Ir(OH)(CO)(PCy₃)₂]

Formula Unicode styled:

trans–[Ir(OH)(CO)(PCy₃)₂]

Compound name(s):

Carbonyl-hydroxy-bis(tricyclohexylphosphine)-iridium

Central atom:

Attached groups:

OH (hydroxo)

PCy₃ (tricyclohexylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

trans–[Ir(OC₆F₅)(CO)(PPh₃)₂]

Formula Unicode styled:

trans–[Ir(OC₆F₅)(CO)(PPh₃)₂]

Compound name(s):

Carbonyl-(pentafluorophenoxy-O)-bis(triphenylphosphine)-iridium

Central atom:

OC₆F₅ (pentafluorophenoxy)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

trans–[Ir(NHTol)(CO)(PPh₃)₂]

Formula Unicode styled:

trans–[Ir(NHTol)(CO)(PPh₃)₂]

Compound name(s):

Carbonyl-p-tolylamido-bis(triphenylphosphine)-iridium

Central atom:

Attached groups:

NHTol (tolylamino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

trans–[Ir(Mes)₂(SEt₂)₂]

Formula Unicode styled:

trans–[Ir(Mes)₂(SEt₂)₂]

Compound name(s):

bis(Diethyl sulfido)-bis(2,4,6-trimethylphenyl)-iridium

Central atom:

Attached groups:

Mes (mesityl)

SEt₂ (diethylthioether)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Ir«V²C⁴O^IIE¹⁵B⁴Z⁰X²L²»

[MLXZ]𝘲 class:

[MX₂L₂]

MLXZ class (ENC, equivalent neutral class):

MX₂L₂

trans–[Ir(Mes)₂(PMe₃)₂]

Formula Unicode styled:

trans–[Ir(Mes)₂(PMe₃)₂]

Compound name(s):

bis(2,4,6-Trimethylphenyl)-bis(trimethylphosphine)-iridium

Central atom:

PMe₃ (trimethylphosphane)

Attached groups:

Mes (mesityl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Ir«V²C⁴O^IIE¹⁵B⁴Z⁰X²L²»

[MLXZ]𝘲 class:

[MX₂L₂]

MLXZ class (ENC, equivalent neutral class):

MX₂L₂

trans–[Ir(Mes)(CO)(PPh₃)₂]

Formula Unicode styled:

trans–[Ir(Mes)(CO)(PPh₃)₂]

Compound name(s):

Carbonyl-mesityl-bis(triphenylphosphine)-iridium

Central atom:

Attached groups:

Mes (mesityl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

trans–[Ir(CO)₂(PBuᵗ₂Ph)₂]⊕

Formula Unicode styled:

trans–[Ir(CO)₂(PBuᵗ₂Ph)₂]⊕

Compound name(s):

Dicarbonyl-bis(di-t-butylphenylphosphine)-iridium(1+)

Central atom:

Attached groups:

PBuᵗ₂Ph (phenyl-di-t-butylphosphane)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X⁰L⁴»^⊕

[MLXZ]𝘲 class:

[ML₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

trans–[Ir(CO){O=CMe(OH)}(PPh₃)₂]⊕

Formula Unicode styled:

trans–[Ir(CO){O=CMe(OH)}(PPh₃)₂]⊕

Compound name(s):

(Acetic acid-O)-carbonyl-bis(triphenylphosphine)-iridium(1+)

Central atom:

Attached groups:

O=CMe(OH) (ethanoic acid-κO)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X⁰L⁴»^⊕

[MLXZ]𝘲 class:

[ML₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

trans–[Ir(C₆F₅)(PEt₃)₂(PEt₂F)]

Formula Unicode styled:

trans–[Ir(C₆F₅)(PEt₃)₂(PEt₂F)]

Compound name(s):

(Fluorodiethylphosphine)-bis(triethylphosphine)-pentafluorophenyl-iridium

Central atom:

PEt₂F (diethylfluorophosphane)

Attached groups:

C₆F₅ (pentafluorophenyl)

PEt₃ (triethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

trans–[Ir(C₆F₅)(CO)(PPh₃)₂]

Formula Unicode styled:

trans–[Ir(C₆F₅)(CO)(PPh₃)₂]

Compound name(s):

(Pentafluorophenyl)-carbonyl-bis(triphenylphosphine)-iridium

Central atom:

Attached groups:

C₆F₅ (pentafluorophenyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

trans–[Ir(C≡CPh)(CO)(PPh₃)₂]

Formula Unicode styled:

trans–[Ir(C≡CPh)(CO)(PPh₃)₂]

Compound name(s):

Carbonyl-(2-phenylethynyl)-bis(triphenylphosphine)-iridium

Central atom:

Attached groups:

C≡CPh (phenylethynyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Ir(μ₂-Cl)(η⁴-Cod)]₂

Formula Unicode styled:

[Ir(μ₂-Cl)(η⁴-Cod)]₂

Compound name(s):

bis(μ₂-Chloro)-bis(η⁴-1,5-cyclo-octadiene)-di-iridium

Central atom:

Cod (η²,η²-cycloocta-1,5-diene)

Attached groups:

Cl (μ₂-chloro)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Ir(Cl)(PPh₃)₃]

Formula Unicode styled:

[Ir(Cl)(PPh₃)₃]

Compound name(s):

Chloro-tris(triphenylphosphine)-iridium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Ir(Cl)(PEt₂Ph)₃]

Formula Unicode styled:

[Ir(Cl)(PEt₂Ph)₃]

Compound name(s):

tris(diethylphenylphosphine)-chloro-iridium

Central atom:

Attached groups:

PEt₂Ph (diethylphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: