Iridium

Attached groups:

PMe₃ (trimethylphosphane)

CH=CH₂ (vinyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Cl)(C₆H₄-C₆H₄)(PPh₃)₂]

Formula Unicode styled:

[Ir(Cl)(C₆H₄-C₆H₄)(PPh₃)₂]

Compound name(s):

Chloro-(biphenyl-2,2'-diyl)-bis(triphenylphosphine)-iridium

Central atom:

Attached groups:

PPh₃ (triphenylphosphane)

C₆H₄-C₆H₄ (biphenyl-κC²)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Ir(Cl)(C₆H₄-C₆H₄)(AsPh₃)₂]

Formula Unicode styled:

[Ir(Cl)(C₆H₄-C₆H₄)(AsPh₃)₂]

Compound name(s):

Chloro-(biphenyl-2,2'-diyl)-bis(triphenylarsine)-iridium

Central atom:

Attached groups:

C₆H₄-C₆H₄ (biphenyl-κC²)

AsPh₃ (triphenylarsane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Ir(Cl)(C₂H₄)₂(PEt₃)]⊕

Formula Unicode styled:

[Ir(Cl)(C₂H₄)₂(PEt₃)]⊕

Compound name(s):

Chloro-bis(η²-ethylene)-bis(triethylphosphine)-iridium

Central atom:

Attached groups:

C₂H₄ (ethene)

PEt₃ (triethylphosphane)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

CN: 4

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Ir«V²C⁴O^IIE¹⁵B⁴Z⁰X¹L³»^⊕

[MLXZ]𝘲 class:

[MX₁L₃]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₂

[Ir(Cl)(C₂H₄)(SbPrⁱ₃)₂]

Formula Unicode styled:

[Ir(Cl)(C₂H₄)(SbPrⁱ₃)₂]

Compound name(s):

bis(Tri-isopropylstibane)-chloro-bis(η²-ethene)-iridium

Central atom:

Attached groups:

SbPrⁱ₃ (triisopropylstibane)

C₂H₄ (ethene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 4

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X¹L³»

[MLXZ]𝘲 class:

[MX₁L₃]

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Ir(Cl)(Bpy)(Cp*)]⊕

Formula Unicode styled:

[Ir(Cl)(Bpy)(Cp*)]⊕

Compound name(s):

Chloro-(η⁵-pentamethyl-cyclopentadienyl)-(2,2'-bipyridyl-N,N')-iridium(1+)

Central atom:

Attached groups:

Bpy (bipyridine)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Bz)(Cl)(CO)(Cp*)]

Formula Unicode styled:

[Ir(Bz)(Cl)(CO)(Cp*)]

Compound name(s):

Benzyl-carbonyl-chloro-(η⁵-pentamethyl-cyclopentadienyl)-iridium

Central atom:

Attached groups:

Bz (phenylmethanido-κC)

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Br)(H)₂(CO)(Dppe-κ²P)]

Formula Unicode styled:

[Ir(Br)(H)₂(CO)(Dppe-κ²P)]

Compound name(s):

Bromo-carbonyl-dihydrido-(1,2-bis(diphenylphosphino)ethane)-iridium

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Br)₆]³⊖

Formula Unicode styled:

[Ir(Br)₆]³⊖

Compound name(s):

hexabromoiridium(3-)

Central atom:

Attached groups:

Charge on central atom:

-3

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰L⁰X⁶»^3⊖

[MLXZ]𝘲 class:

[MX₆]^3-

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Br)₆]²⊖

Formula Unicode styled:

[Ir(Br)₆]²⊖

Compound name(s):

hexabromoiridium(2-)

Central atom:

Attached groups:

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Ir«V⁴C⁶O^IVE¹⁷B⁶Z⁰L⁰X⁶»^2⊖

[MLXZ]𝘲 class:

[MX₆]^2-

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

[Ir(Br)₅(NO)]⊖

Formula Unicode styled:

[Ir(Br)₅(NO)]⊖

Compound name(s):

pentabromo-nitroso-iridium(1-)

Central atom:

Attached groups:

NO (nitrosyl, linear)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 7

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V⁷C⁶O^IIIE¹⁸B⁸X⁶L¹Z¹»^⊖

[MLXZ]𝘲 class:

[MX₆L₁Z₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₇L₁

[Ir(Br)(μ₂-Br)(Cp*)]₂

Formula Unicode styled:

[Ir(Br)(μ₂-Br)(Cp*)]₂

Compound name(s):

Di-mu-bromo-bis(bromo-η⁵-pentamethyl-cyclopentadienyl-iridium)

Central atom:

Attached groups:

Br (μ₂-bromo)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Br)₂(η³-C₃H₅)(η⁴-Cod)]

Formula Unicode styled:

[Ir(Br)₂(η³-C₃H₅)(η⁴-Cod)]

Compound name(s):

(η³-allyl)-dibromo-(η⁴-cycloocta-1,5-diene)-iridium

Central atom:

Attached groups:

C₃H₅ (η³-allyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Br)₂(PPrⁱ₃)(η⁵-C₅HMe₄)]

Formula Unicode styled:

[Ir(Br)₂(PPrⁱ₃)(η⁵-C₅HMe₄)]

Compound name(s):

Dibromo-(η⁵-tetramethylcyclopentadienyl)-(triisopropylphosphine)-iridium

Central atom:

Attached groups:

PPrⁱ₃ (triisopropylphosphane)

C₅HMe₄ (η⁵-tetramethylcyclopentadienyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Br)(η⁴-Cod)(Cp)]⊕

Formula Unicode styled:

[Ir(Br)(η⁴-Cod)(Cp)]⊕

Compound name(s):

Bromo-(η⁵-cyclopentadienyl)-(η⁴-cycloocta-1,5-diene)-iridium(1+)

Central atom:

Attached groups:

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(Br)(NH₃)₅]²⊕

Formula Unicode styled:

[Ir(Br)(NH₃)₅]²⊕

Compound name(s):

bromo-pentaammine-iridium(2+)

Central atom:

Attached groups:

NH₃ (ammine)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X¹L⁵»^2⊕

[MLXZ]𝘲 class:

[MX₁L₅]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir{P(OMe)₃}(η³-C₃H₅)(η⁴-Cod)]

Formula Unicode styled:

[Ir{P(OMe)₃}(η³-C₃H₅)(η⁴-Cod)]

Compound name(s):

(η³-Allyl)-(η⁴-cyclo-octa-1,5-diene)-trimethylphosphite-iridium

Central atom:

P(OMe)₃ (trimethylphosphite)

Attached groups:

C₃H₅ (η³-allyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ir{Au(PPh₃)}(Dppe-κ²P)₂]⊕

Formula Unicode styled:

[Ir{Au(PPh₃)}(Dppe-κ²P)₂]⊕

Compound name(s):

bis(bis(Diphenylphosphino)-ethane-P,P')-(triphenylphosphine-gold)-iridium(1+)

Central atom:

Au(PPh₃) (triphenylphosphinogold)

Attached groups:

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (II)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Ir«V²C⁵O^IIE¹⁷B⁵Z⁰X¹L⁴»^⊕

[MLXZ]𝘲 class:

[MX₁L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

[Ir(η⁴-Cod)([9]aneS₃-κ²S)]⊕

Formula Unicode styled:

[Ir(η⁴-Cod)([9]aneS₃-κ²S)]⊕

Compound name(s):

(η⁴-Cyclo-octa-1,5-diene)-(1,4,7-trithiacyclononane-S,S',S'')-iridium(1+)

Central atom:

Attached groups:

[9]aneS₃ (1,4,7-trithiocyclononane-κ²S)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 4

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X⁰L⁴»^⊕

[MLXZ]𝘲 class:

[ML₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Ir(η⁴-C₄H₆)([9]aneS₃-κ³S)]⊕

Formula Unicode styled:

[Ir(η⁴-C₄H₆)([9]aneS₃-κ³S)]⊕

Compound name(s):

(η⁴-Butadiene)-(1,4,7-trithiacyclononane-S,S'S'')-iridium(1+)

Central atom:

[9]aneS₃ (1,4,7-trithiocyclononane-κ³S)

Attached groups:

C₄H₆ (η⁴-butadiene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: