Iridium

Attached groups:

S₆ (hexasulfanediyl-κ²S)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(S₄)(PMe₃)(Cp*)]

Formula Unicode styled:

[Ir(S₄)(PMe₃)(Cp*)]

Compound name(s):

(η⁵-Pentamethyl-cyclopentadienyl)-trimethylphosphine-(tetrasulfido-S,S')-iridium

Central atom:

S₄ (tetrasulfanediyl-κ²S)

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(S₄)(CO)(Cp*)]

Formula Unicode styled:

[Ir(S₄)(CO)(Cp*)]

Compound name(s):

Carbonyl-(η⁵-pentamethyl-cyclopentadienyl)-cyclotetrasulfido-iridium

Central atom:

S₄ (tetrasulfanediyl-κ²S)

Attached groups:

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(S₂C₆H₄-κ²S)(Cp*)]⊕

Formula Unicode styled:

[Ir(S₂C₆H₄-κ²S)(Cp*)]⊕

Compound name(s):

(Benzene-1,2-dithiolato)-(η⁵-pentamethyl-cyclopentadienyl)-iridium

Central atom:

S₂C₆H₄ (benzene-1,2-dithiolato-κ²S)

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Summary of calculated classifications:

Ir«V⁴C⁵O^IVE¹⁵B⁵Z⁰X³L²»^⊕

[MLXZ]𝘲 class:

[MX₃L₂]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₁

[Ir(PPrⁱ₃)(η⁴-C₄H₆)₂]⊕

Formula Unicode styled:

[Ir(PPrⁱ₃)(η⁴-C₄H₆)₂]⊕

Compound name(s):

bis(s-cis-η⁴-Butadiene)-(tri-isopropylphosphane)-iridium(1+)

Central atom:

PPrⁱ₃ (triisopropylphosphane)

Attached groups:

C₄H₆ (η⁴-butadiene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X⁰L⁵»^⊕

[MLXZ]𝘲 class:

[ML₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ir(PPh₃)₃(NO)]

Formula Unicode styled:

[Ir(PPh₃)₃(NO)]

Compound name(s):

tris(Triphenylphosphine)nitrosyl-iridium

Central atom:

Attached groups:

NO (nitrosyl, linear)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (-I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁴O^-IE¹⁸B⁶X¹L⁴Z¹»

[MLXZ]𝘲 class:

[MX₁L₄Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(PPh₃)₂(η⁴-Cod)]⊕

Formula Unicode styled:

[Ir(PPh₃)₂(η⁴-Cod)]⊕

Compound name(s):

(η²,η²-1,5-Cyclo-octadienyl)-bis(triphenylphosphine)-iridium(1+)

Central atom:

Attached groups:

Cod (η²,η²-cycloocta-1,5-diene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X⁰L⁴»^⊕

[MLXZ]𝘲 class:

[ML₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Ir(PPh₃)₂(NO)₂]⊕

Formula Unicode styled:

[Ir(PPh₃)₂(NO)₂]⊕

Compound name(s):

Dinitrosyl-bis(triphenylphosphine) iridium(1+)

Central atom:

Attached groups:

(NO)₂ (dinitrosyl, (N≡O)₂ tetrahedral Ⓢ)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (-I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁴O^-IE¹⁸B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(PPh₃)₂(NO)(Phen)]²⊕

Formula Unicode styled:

[Ir(PPh₃)₂(NO)(Phen)]²⊕

Compound name(s):

Nitrosyl-(1,10-phenanthroline)-bis(triphenylphosphine)-iridium(1+)

Central atom:

Attached groups:

NO (nitrosyl, linear)

Phen (phenanthroline)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V⁵C⁵O^IE¹⁸B⁷X¹L⁵Z¹»^2⊕

[MLXZ]𝘲 class:

[MX₁L₅Z₁]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Ir(PMePh₂)₄]⊕

Formula Unicode styled:

[Ir(PMePh₂)₄]⊕

Compound name(s):

tetrakis(Methyldiphenylphosphine) iridium(1+)

Central atom:

PMePh₂ (methyldiphenylphosphane)

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X⁰L⁴»^⊕

[MLXZ]𝘲 class:

[ML₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Ir(PMe₃)₅]⊕

Formula Unicode styled:

[Ir(PMe₃)₅]⊕

Compound name(s):

pentakis(Trimethylphosphine)-iridium(1+)

Central atom:

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X⁰L⁵»^⊕

[MLXZ]𝘲 class:

[ML₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ir(PMe₃)₃(η⁴-Cod)]³⊕

Formula Unicode styled:

[Ir(PMe₃)₃(η⁴-Cod)]³⊕

Compound name(s):

(η⁴-Cyclo-octa-1,5-diene)-(tris(trimethylphosphine))-iridium(3+)

Central atom:

Attached groups:

Cod (η²,η²-cycloocta-1,5-diene)

Charge on central atom:

3

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁵O^IIIE¹⁶B⁵Z⁰X⁰L⁵»^3⊕

[MLXZ]𝘲 class:

[ML₅]³⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Ir(PMe₃)₃(η⁴-Cod)]⊕

Formula Unicode styled:

[Ir(PMe₃)₃(η⁴-Cod)]⊕

Compound name(s):

(η²,η²-Cyclo-octa-1,5-diene)-tris(trimethylphosphino)-iridium(1+)

Central atom:

Attached groups:

Cod (η²,η²-cycloocta-1,5-diene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X⁰L⁵»^⊕

[MLXZ]𝘲 class:

[ML₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ir(PMe₃)(≡CPh)(η⁵-C₅EtMe₄)]⊕

Formula Unicode styled:

[Ir(PMe₃)(≡CPh)(η⁵-C₅EtMe₄)]⊕

Compound name(s):

Benzylidyne-(η⁵-ethyltetramethylcyclopentadienyl)-trimethylphosphine-iridium(1+)

Central atom:

Attached groups:

≡CPh (phenylmethylidyne, benzylidyne)

C₅EtMe₄ (η⁵-ethyltetramethylcyclopentadienyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V⁵C⁵O^VE¹⁸B⁷Z⁰X⁴L³»^⊕

[MLXZ]𝘲 class:

[MX₄L₃]⁺

MLXZ class (ENC, equivalent neutral class):

MX₅L₂

[Ir(PMe₂Ph)₄]⊕

Formula Unicode styled:

[Ir(PMe₂Ph)₄]⊕

Compound name(s):

tetrakis(Dimethyl(phenyl)phosphine)-iridium(1+)

Central atom:

PMe₂Ph (dimethylphenylphosphane)

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁴O^IE¹⁶B⁴Z⁰X⁰L⁴»^⊕

[MLXZ]𝘲 class:

[ML₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₁L₃

[Ir(OSiEt₃)(Tpp)]

Formula Unicode styled:

[Ir(OSiEt₃)(Tpp)]

Compound name(s):

(5,10,15,20-Tetra-p-tolylporphyrinato)-(triethoxysilyl)-iridium

Central atom:

Tpp (tetraphenylporphyrin)

Attached groups:

OSiEt₃ (triethylsiloxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁵O^IIIE¹⁶B⁵Z⁰X³L²»

[MLXZ]𝘲 class:

[MX₃L₂]

MLXZ class (ENC, equivalent neutral class):

MX₃L₂

[Ir(ONO₂-κO)(O₂NO-κ²O)(Cp*)]

Formula Unicode styled:

[Ir(ONO₂-κO)(O₂NO-κ²O)(Cp*)]

Compound name(s):

(η⁵-Pentamethyl-cyclopentadienyl)-(nitrato-O,O')-(nitrato-O)-iridium

Central atom:

Attached groups:

NO₃ (nitrato-κO)

NO₃ (nitrato-κ²O)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(OMe)(CO)(Tcne)(PPh₃)₂]

Formula Unicode styled:

[Ir(OMe)(CO)(Tcne)(PPh₃)₂]

Compound name(s):

Carbonyl-(η²-tetracyanoethylene)-methoxy-bis(triphenylphosphine)-iridium

Central atom:

Attached groups:

OMe (methoxy)

CO (carbonyl)

Tcne (tetracyanoethene)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V¹C⁵O^IE¹⁸B⁵Z⁰X¹L⁴»

[MLXZ]𝘲 class:

[MX₁L₄]

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

[Ir(OH₂)₆]³⊕

Formula Unicode styled:

[Ir(OH₂)₆]³⊕

Compound name(s):

hexaaquairidium(3+)

Central atom:

Attached groups:

OH₂ (aqua)

Charge on central atom:

3

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X⁰L⁶»^3⊕

[MLXZ]𝘲 class:

[ML₆]³⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

[Ir(OH₂)₃(Cp*)]²⊕

Formula Unicode styled:

[Ir(OH₂)₃(Cp*)]²⊕

Compound name(s):

Triaqua-(η⁵-cyclopentadienyl)-iridium(2+)

Central atom:

Attached groups:

OH₂ (aqua)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: