mer,cis–[Ir(H)₂(SnCl₃)(PPh₃)₃]

Formula Unicode styled:

Compound name(s):

Dihydro-(trichloro-tin)-tris(triphenylphosphine)-iridium

Central atom:

Iridium

Charge on formula unit (QN):

Attached groups:

H (hydrido)

SnCl₃ (trichlorostannyl)

PPh₃ (triphenylphosphane)

Compound type:

Molecular

DOI link to literature report:

10.1016/0022-328X(85)87122-9

Crystal data CSD link:

dejxul

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Coordination Number (CN, sum of attached group denticities):

CN: 6

Oxidation Number (ON) (Roman numerals):

ON: (III)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[MX₃L₃]

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

Summary of calculated classifications:

Ir«V³C⁶O^IIIE¹⁸B⁶Z⁰X³L³»

Geometry:

6-coordinate: octahedron (OC-6)

Isomer label:

mer,cis

𝘥-electron configuration = 𝘮 – VN:

d⁶

𝘥-electron configuration = 𝘮 – ON:

d⁶

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d⁶

Attached atoms:

H₂P₃Sn₁

Phase:

Solid

InChIKey (see www.inchi-trust.org):

HOYQOAXUWBVATQ-UHFFFAOYSA-K