cis–[V(CO)₂(Dmpe)(Cp)]

Formula Unicode styled:

Compound name(s):

Dicarbonyl-(η-cyclopentadienyl)-(1,2-bis(dimethylphosphino)ethane)-vanadium

Central atom:

Vanadium

Charge on formula unit (QN):

Attached groups:

CO (carbonyl)

Dmpe (1,2-bis-(dimethylphosphino)ethane)

Cp (η⁵-cyclopentadienyl)

Compound type:

Molecular

DOI link to literature report:

10.1021/om800712k

Crystal data CSD link:

bolcip

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Coordination Number (CN, sum of attached group denticities):

CN: 7

Oxidation Number (ON) (Roman numerals):

ON: (I)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[MX₁L₆]

MLXZ class (ENC, equivalent neutral class):

MX₁L₆

Summary of calculated classifications:

V«V¹C⁷O^IE¹⁸B⁷Z⁰X¹L⁶»

Geometry:

7-coordinate: ③-●-4 piano stool

Isomer label:

cis

𝘥-electron configuration = 𝘮 – VN:

d⁴

𝘥-electron configuration = 𝘮 – ON:

d⁴

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d⁴

Attached atoms:

C₇P₂

Phase:

Solid

InChIKey (see www.inchi-trust.org):

PAIGTYMFNDIHGM-UHFFFAOYSA-N