cis–[Os(Cl)₂(PCy₃)₂(C)]

Formula Unicode styled:

Compound name(s):

Dichloro-bis(tricyclohexylphosphine)-(carbido)-osmium

Central atom:

Osmium

Charge on formula unit (QN):

Attached groups:

Cl (chloro)

PCy₃ (tricyclohexylphosphane)

C (carbido)

Compound type:

Molecular

DOI link to literature report:

10.1021/om070208u

Crystal data CSD link:

sivrev

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Coordination Number (CN, sum of attached group denticities):

CN: 5

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[MX₄L₂Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

Summary of calculated classifications:

Os«V⁶C⁵O^IVE¹⁶B⁷X⁴L²Z¹»

Geometry:

5-coordinate: square-based pyramid (SPY-5)

Isomer label:

cis

𝘥-electron configuration = 𝘮 – VN:

d²

𝘥-electron configuration = 𝘮 – ON:

d⁴

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d²

Attached atoms:

C₁Cl₂P₂

Phase:

Solid

InChIKey (see www.inchi-trust.org):

KWJZPLHXZQWECQ-UHFFFAOYSA-L