SPh (μ₂-phenylthio)

cis–[Ir(μ₂-SPh)(CO)₂]₂

Formula Unicode styled: 
cis–[Ir(μ₂-SPh)(CO)₂]₂
Compound name(s): 
Di-mu-benzenethiolato-bis(dicarbonyl-iridium)
Central atom: 
Iridium
Attached groups: 
SPh (μ₂-phenylthio)
CO (carbonyl)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 4
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Ir«V1C4OIE16B4Z0X1L3»
[MLXZ]𝘲 class: 
[MX1L3]
MLXZ class (ENC, equivalent neutral class): 
MX1L3

cis–[Mn(CO)₄(μ₂-SPh)]₂

Formula Unicode styled: 
cis–[Mn(CO)₄(μ₂-SPh)]₂
Compound name(s): 
bis((μ₂-Phenylsulfido)-tetracarbonyl-manganese)
Central atom: 
Manganese
Attached groups: 
CO (carbonyl)
SPh (μ₂-phenylthio)
Charge on central atom: 
0
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Mn«V1C6OIE18B6Z0X1L5»
[MLXZ]𝘲 class: 
[MX1L5]
MLXZ class (ENC, equivalent neutral class): 
MX1L5

[Cd(SPh)₂(μ₂-SPh)]₂²⊖

Formula Unicode styled: 
[Cd(SPh)₂(μ₂-SPh)]₂²⊖
Compound name(s): 
bis(bis(μ₂-benzenethiolato-S)-bis(benzenethiolato-S)-cadmium(1-))
Central atom: 
Cadmium
Attached groups: 
SPh (phenylthio)
SPh (μ₂-phenylthio)
Charge on central atom: 
-1
Compound type: 
Oligomer
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 4
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 8
Summary of calculated classifications: 
Cd«V2C4OIIE8B4Z0X3L1»⊖
[MLXZ]𝘲 class: 
[MX3L1]-
MLXZ class (ENC, equivalent neutral class): 
MX2L2