9-coordinate: ③₂-●-3 bent metallocene

③₂-●-3 bent metallocene

[Zr(Cl)(Dedtc)(Cp)₂]

Formula Unicode styled: 
[Zr(Cl)(Dedtc)(Cp)₂]
Compound name(s): 
bis(η⁵-Cyclopentadienyl)-chloro-(N,N-diethyldithiocarbamato)-zirconium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Zr«V4C9OIVE18B9Z0X4L5»
[MLXZ]𝘲 class: 
[MX4L5]
MLXZ class (ENC, equivalent neutral class): 
MX4L5

[Zr{NC₅H₃(CO₂)₂-κN,κ²O}(Cp)₂]

Formula Unicode styled: 
[Zr{NC₅H₃(CO₂)₂-κN,κ²O}(Cp)₂]
Compound name(s): 
bis(η⁵-cyclopentadienyl)-(pyridine-2,6-dicarboxylato)-zirconium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Zr«V4C9OIVE18B9Z0X4L5»
[MLXZ]𝘲 class: 
[MX4L5]
MLXZ class (ENC, equivalent neutral class): 
MX4L5

[Zr{NC₅H₃(CO₂)₂-κN,κ²O}(η⁵-C₅H₄Me)₂]

Formula Unicode styled: 
[Zr{NC₅H₃(CO₂)₂-κN,κ²O}(η⁵-C₅H₄Me)₂]
Compound name(s): 
bis(η⁵-Methylcyclopentadienyl)-(2,6-pyridinedicarboxylato)-zirconium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Zr«V4C9OIVE18B9Z0X4L5»
[MLXZ]𝘲 class: 
[MX4L5]
MLXZ class (ENC, equivalent neutral class): 
MX4L5

[Zr(PzH)(Acac)(Cp)₂]⊕

Formula Unicode styled: 
[Zr(PzH)(Acac)(Cp)₂]⊕
Compound name(s): 
(Acetylacetonato-O,O')-(pyrazole-N)-zirconocene(1+)
Central atom: 
Charge on central atom: 
1
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Zr«V4C9OIVE18B9Z0X3L6»
[MLXZ]𝘲 class: 
[MX3L6]+
MLXZ class (ENC, equivalent neutral class): 
MX4L5

[Zr(SO₃CF₃-κO)₂(Thf)(Cp)₂]

Formula Unicode styled: 
[Zr(SO₃CF₃-κO)₂(Thf)(Cp)₂]
Compound name(s): 
bis(η⁵-Cyclopentadienyl)-tetrahydrofuran-bis(trifluoromethanesulfonato)-zirconium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Zr«V4C9OIVE18B9Z0X4L5»
[MLXZ]𝘲 class: 
[MX4L5]
MLXZ class (ENC, equivalent neutral class): 
MX4L5

[Zr(SO₃CF₃-κO)(OH₂)₂(Cp)₂]⊕

Formula Unicode styled: 
[Zr(SO₃CF₃-κO)(OH₂)₂(Cp)₂]⊕
Compound name(s): 
Diaqua-bis(η⁵-cyclopentadienyl)-(p-tolylsulfonato)-zirconium(1+)
Central atom: 
Charge on central atom: 
1
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Zr«V4C9OIVE18B9Z0X3L6»
[MLXZ]𝘲 class: 
[MX3L6]+
MLXZ class (ENC, equivalent neutral class): 
MX4L5

[Zr(SO₃CF₃-κO)(Bpy)(Cp)₂]⊕

Formula Unicode styled: 
[Zr(SO₃CF₃-κO)(Bpy)(Cp)₂]⊕
Compound name(s): 
bis(η⁵-Cyclopentadienyl)-(2,2'-bipyridyl-N,N')-(trifluoromethanesulfonato-O)zirconium(1+)
Central atom: 
Charge on central atom: 
1
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Zr«V4C9OIVE18B9Z0X3L6»
[MLXZ]𝘲 class: 
[MX3L6]+
MLXZ class (ENC, equivalent neutral class): 
MX4L5

[Zr(OH₂)₃(Cp)₂]²⊕

Formula Unicode styled: 
[Zr(OH₂)₃(Cp)₂]²⊕
Compound name(s): 
Triaqua-bis(η⁵-cyclopentadienyl)-zirconium(2+)
Central atom: 
Charge on central atom: 
2
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Zr«V4C9OIVE18B9Z0X2L7»2⊕
[MLXZ]𝘲 class: 
[MX2L7]2+
MLXZ class (ENC, equivalent neutral class): 
MX4L5

[Y(NCMe)₃{η⁵-C₅H₄(SiMe₃)}₂]⊕

Formula Unicode styled: 
[Y(NCMe)₃{η⁵-C₅H₄(SiMe₃)}₂]⊕
Compound name(s): 
tris(Acetonitrile)-bis(eta⁵-trimethylsilyl-cyclopentadienyl)-yttrium(1+)
Central atom: 
Charge on central atom: 
1
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Y«V3C9OIIIE18B9Z0X2L7»
[MLXZ]𝘲 class: 
[MX2L7]+
MLXZ class (ENC, equivalent neutral class): 
MX3L6

[Ti(GePh₃)(COMe-κC,κO)(Cp)₂]

Formula Unicode styled: 
[Ti(GePh₃)(COMe-κC,κO)(Cp)₂]
Compound name(s): 
(eta-Acetyl)-bis(eta-cyclopentadienyl)-triphenyl-germanium-titanium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Ti«V4C9OIVE18B9Z0X4L5»
[MLXZ]𝘲 class: 
[MX4L5]
MLXZ class (ENC, equivalent neutral class): 
MX4L5

[Ce(Terpy-κ³N)(Cp*)₂]⊕

Formula Unicode styled: 
[Ce(Terpy-κ³N)(Cp*)₂]⊕
Compound name(s): 
bis(η⁵-Pentamethyl-cyclopentadienyl)-(2,2':6',2''-terpyridyl)-cerium(1+)
Central atom: 
Charge on central atom: 
1
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
Ce«V3C9OIIIE19B9Z0X2L7»
[MLXZ]𝘲 class: 
[MX2L7]+
MLXZ class (ENC, equivalent neutral class): 
MX3L6