7-coordinate: pentagonal bipyramid (PBPY-7)

[Tc(Cl)₂(NS)(Dedtc)₂]

Formula Unicode styled: 
[Tc(Cl)₂(NS)(Dedtc)₂]
Compound name(s): 
Dichloro-bis(diethyldithiocarbamato-S,S')-thionitrosyl-technetium
Central atom: 
Technetium
Attached groups: 
Cl (chloro)
NS (thionitrosyl, linear)
Dedtc (diethyldithiocarbamato-κ²S)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 7
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Tc«V7C7OIIIE18B9X5L3Z1»
[MLXZ]𝘲 class: 
[MX5L3Z1]
MLXZ class (ENC, equivalent neutral class): 
MX7L2

[Tc(Br)₂(NS)(Dedtc)₂]

Formula Unicode styled: 
[Tc(Br)₂(NS)(Dedtc)₂]
Compound name(s): 
Dibromo-bis(N,N-diethyldithiocarbamato)-thionitrosyl-technetium
Central atom: 
Technetium
Attached groups: 
Br (bromo)
NS (thionitrosyl, linear)
Dedtc (diethyldithiocarbamato-κ²S)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 7
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Tc«V7C7OIIIE18B9X5L3Z1»
[MLXZ]𝘲 class: 
[MX5L3Z1]
MLXZ class (ENC, equivalent neutral class): 
MX7L2

[Tc(PMe₂Ph)(Dedtc)₃]

Formula Unicode styled: 
[Tc(PMe₂Ph)(Dedtc)₃]
Compound name(s): 
tris(Diethyldithiocarbamato)-dimethylphenylphosphine-technetium
Central atom: 
Technetium
Attached groups: 
PMe₂Ph (dimethylphenylphosphane)
Dedtc (diethyldithiocarbamato-κ²S)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Tc«V3C7OIIIE18B7Z0X3L4»
[MLXZ]𝘲 class: 
[MX3L4]
MLXZ class (ENC, equivalent neutral class): 
MX3L4

[Tc(CO)(Dedtc)₃]

Formula Unicode styled: 
[Tc(CO)(Dedtc)₃]
Compound name(s): 
Carbonyl-tris(diethyldithiocarbamato)-technetium
Central atom: 
Technetium
Attached groups: 
CO (carbonyl)
Dedtc (diethyldithiocarbamato-κ²S)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Tc«V3C7OIIIE18B7Z0X3L4»
[MLXZ]𝘲 class: 
[MX3L4]
MLXZ class (ENC, equivalent neutral class): 
MX3L4

[Re(H)₂(CO)(PMe₃)₄]⊕

Formula Unicode styled: 
[Re(H)₂(CO)(PMe₃)₄]⊕
Compound name(s): 
Carbonyl-dihydrido-tetrakis(trimethylphosphino)-rhenium(1+)
Central atom: 
Rhenium
Attached groups: 
H (hydrido)
CO (carbonyl)
PMe₃ (trimethylphosphane)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Re«V3C7OIIIE18B7Z0X2L5»⊕
[MLXZ]𝘲 class: 
[MX2L5]+
MLXZ class (ENC, equivalent neutral class): 
MX3L4

[Re(CO)₄{Au(PPh₃)}₃]

Formula Unicode styled: 
[Re(CO)₄{Au(PPh₃)}₃]
Compound name(s): 
Tetracarbonyl-tris(triphenylphosphine)-trigold-rhenium
Central atom: 
Rhenium
Attached groups: 
CO (carbonyl)
Au(PPh₃) (triphenylphosphinogold)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Re«V3C7OIIIE18B7Z0X3L4»
[MLXZ]𝘲 class: 
[MX3L4]
MLXZ class (ENC, equivalent neutral class): 
MX3L4

[Re(CO)(Dedtc)₃]

Formula Unicode styled: 
[Re(CO)(Dedtc)₃]
Compound name(s): 
Carbonyl-tris(N,N-diethyldithiocarbamato)-rhenium
Central atom: 
Rhenium
Attached groups: 
CO (carbonyl)
Dedtc (diethyldithiocarbamato-κ²S)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Re«V3C7OIIIE18B7Z0X3L4»
[MLXZ]𝘲 class: 
[MX3L4]
MLXZ class (ENC, equivalent neutral class): 
MX3L4

[W(S)(Dedtc)₃]⊕

Formula Unicode styled: 
[W(S)(Dedtc)₃]⊕
Compound name(s): 
tris(N,N-Diethyldithiocarbamato-S,S')-thio-tungsten(1+)
Central atom: 
Tungsten
Attached groups: 
S (thio; ⭀S)
Dedtc (diethyldithiocarbamato-κ²S)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
W«V6C7OVIE18B9Z0X5L4»⊕
[MLXZ]𝘲 class: 
[MX5L4]+
MLXZ class (ENC, equivalent neutral class): 
MX6L3

[W(H)₂(I)(SiMe₃)(PMe₃)₃]

Formula Unicode styled: 
[W(H)₂(I)(SiMe₃)(PMe₃)₃]
Compound name(s): 
Dihydrido-iodo-tris(trimethylphosphine)-trimethylsilyl-tungsten
Central atom: 
Tungsten
Attached groups: 
H (hydrido)
I (iodo)
SiMe₃ (trimethylsilyl)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
W«V4C7OIVE16B7Z0X4L3»
[MLXZ]𝘲 class: 
[MX4L3]
MLXZ class (ENC, equivalent neutral class): 
MX4L3

[W(F)₄(O)(Py)₂]

Formula Unicode styled: 
[W(F)₄(O)(Py)₂]
Compound name(s): 
Tetrafluoro-oxo-dipyridyl-tungsten
Central atom: 
Tungsten
Attached groups: 
F (fluoro)
O (oxo ⭀O X₂L)
Py (pyridine)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
W«V6C7OVIE18B9Z0X6L3»
[MLXZ]𝘲 class: 
[MX6L3]
MLXZ class (ENC, equivalent neutral class): 
MX6L3

[W(Cl)(H)(CO)₂(PMe₃)₃]

Formula Unicode styled: 
[W(Cl)(H)(CO)₂(PMe₃)₃]
Compound name(s): 
Chloro-dicarbonyl-hydrido-tris(trimethylphosphino)-tungsten
Central atom: 
Tungsten
Attached groups: 
Cl (chloro)
H (hydrido)
CO (carbonyl)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
W«V2C7OIIE18B7Z0X2L5»
[MLXZ]𝘲 class: 
[MX2L5]
MLXZ class (ENC, equivalent neutral class): 
MX2L5

[W(Cl)₂(S)(Dmdtc)₂]

Formula Unicode styled: 
[W(Cl)₂(S)(Dmdtc)₂]
Compound name(s): 
Dichloro-bis(dimethyldithiocarbamato)-thioxo-tungsten
Central atom: 
Tungsten
Attached groups: 
Cl (chloro)
S (thio; ⭀S)
Dmdtc (dimethyldithiocarbamato-κ²S)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
W«V6C7OVIE18B9Z0X6L3»
[MLXZ]𝘲 class: 
[MX6L3]
MLXZ class (ENC, equivalent neutral class): 
MX6L3

[W(CO)₅(Se₂)]⊕

Formula Unicode styled: 
[W(CO)₅(Se₂)]⊕
Compound name(s): 
Diseleno-pentacarbonyl-tungsten(1+)
Central atom: 
Tungsten
Attached groups: 
CO (carbonyl)
Se₂ (perseleno-κ²Se)
Charge on central atom: 
1
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 17
Summary of calculated classifications: 
W«V3C7OIIIE17B7Z0X2L5»⊕
[MLXZ]𝘲 class: 
[MX2L5]+
MLXZ class (ENC, equivalent neutral class): 
MX3L4

[W(O)(S₂)(Dedtc)₂]

Formula Unicode styled: 
[W(O)(S₂)(Dedtc)₂]
Compound name(s): 
Oxo-disulfido-bis(N,N-diethyl-dithiocarbamato-S,S')-tungsten
Central atom: 
Tungsten
Attached groups: 
O (oxo ⭀O X₂L)
S₂ (disulfanediyl-κ²S)
Dedtc (diethyldithiocarbamato-κ²S)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
W«V6C7OVIE18B9Z0X6L3»
[MLXZ]𝘲 class: 
[MX6L3]
MLXZ class (ENC, equivalent neutral class): 
MX6L3

[W(O)(S₂)₂(Phen)]

Formula Unicode styled: 
[W(O)(S₂)₂(Phen)]
Compound name(s): 
1,10-Phenanthroline-oxo-bis(disulfido)-tungsten
Central atom: 
Tungsten
Attached groups: 
O (oxo ⭀O X₂L)
S₂ (disulfanediyl-κ²S)
Phen (phenanthroline)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
W«V6C7OVIE18B9Z0X6L3»
[MLXZ]𝘲 class: 
[MX6L3]
MLXZ class (ENC, equivalent neutral class): 
MX6L3

[W(O)(S₂)₂(Bpy)]

Formula Unicode styled: 
[W(O)(S₂)₂(Bpy)]
Compound name(s): 
(2,2'-Bipyridyl)-bis(disulfide)-oxo-tungsten
Central atom: 
Tungsten
Attached groups: 
O (oxo ⭀O X₂L)
S₂ (disulfanediyl-κ²S)
Bpy (bipyridine)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
W«V6C7OVIE18B9Z0X6L3»
[MLXZ]𝘲 class: 
[MX6L3]
MLXZ class (ENC, equivalent neutral class): 
MX6L3

[W(CN)₆(O)]²⊖

Formula Unicode styled: 
[W(CN)₆(O)]²⊖
Compound name(s): 
hexacyano-oxo-tungsten(2-)
Central atom: 
Tungsten
Attached groups: 
CN (cyano-κC)
O (oxo ⭀O X₂L)
Charge on central atom: 
-2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
W«V6C7OVIE18B9Z0X8L1»2⊖
[MLXZ]𝘲 class: 
[MX8L1]2-
MLXZ class (ENC, equivalent neutral class): 
MX6L3

trans–[W(CN)₅(OMe)(O)]²⊖

Formula Unicode styled: 
trans–[W(CN)₅(OMe)(O)]²⊖
Compound name(s): 
pentacyano-oxo-methoxy-tungsten(2-)
Central atom: 
Tungsten
Attached groups: 
CN (cyano-κC)
OMe (methoxy)
O (oxo ⭀O X₂L)
Charge on central atom: 
-2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
W«V6C7OVIE18B9Z0X8L1»2⊖
[MLXZ]𝘲 class: 
[MX8L1]2-
MLXZ class (ENC, equivalent neutral class): 
MX6L3

[Mo(H)₂(PMe₃)₅]

Formula Unicode styled: 
[Mo(H)₂(PMe₃)₅]
Compound name(s): 
Pentakis(trimethylphosphine)molybdenum(II) hydride
Central atom: 
Molybdenum
Attached groups: 
H (hydrido)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Mo«V2C7OIIE18B7Z0X2L5»
[MLXZ]𝘲 class: 
[MX2L5]
MLXZ class (ENC, equivalent neutral class): 
MX2L5

[Mo(H)₂(PMe₃)₅]

Formula Unicode styled: 
[Mo(H)₂(PMe₃)₅]
Compound name(s): 
pentakis(Trimethylphosphine)-dihydrido-molybdenum
Central atom: 
Molybdenum
Attached groups: 
H (hydrido)
PMe₃ (trimethylphosphane)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN, sum of attached group denticities): 
CN: 7
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Summary of calculated classifications: 
Mo«V2C7OIIE18B7Z0X2L5»
[MLXZ]𝘲 class: 
[MX2L5]
MLXZ class (ENC, equivalent neutral class): 
MX2L5