6-coordinate: trigonal prism (TPR-6)

[W(S₂C₆H₄-κ²S)₃]²⊖

Formula Unicode styled: 
[W(S₂C₆H₄-κ²S)₃]²⊖
Compound name(s): 
tris(benzene-1,2-dithiolato)-tungsten(2-)
Central atom: 
Tungsten
Attached groups: 
S₂C₆H₄ (benzene-1,2-dithiolato-κ²S)
Charge on central atom: 
-2
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 14
Summary of calculated classifications: 
W«V4C6OIVE14B6Z0L0X6»2⊖
[MLXZ]𝘲 class: 
[MX6]2-
MLXZ class (ENC, equivalent neutral class): 
MX4L2

[Re(Me)₆]

Formula Unicode styled: 
[Re(Me)₆]
Compound name(s): 
Hexamethyl-rhenium
Central atom: 
Rhenium
Attached groups: 
Me (methyl)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (VI)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 13
Summary of calculated classifications: 
Re«V6C6OVIE13B6Z0L0X6»
[MLXZ]𝘲 class: 
[MX6]
MLXZ class (ENC, equivalent neutral class): 
MX6

[Re(SCPhCCPhS)₃]

Formula Unicode styled: 
[Re(SCPhCCPhS)₃]
Compound name(s): 
tris(cis-1,2-Diphenylethylene-1,2-dithiolato-S,S')-rhenium
Central atom: 
Rhenium
Attached groups: 
SCPhCCPhS (diphenylethenedithiolato-κ²S)
Charge on central atom: 
0
Compound type: 
Molecular
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Summary of calculated classifications: 
Re«V3C6OIIIE16B6Z0X3L3»
[MLXZ]𝘲 class: 
[MX3L3]
MLXZ class (ENC, equivalent neutral class): 
MX3L3