4-coordinate: tetrahedral (p-block element, 2 lone pairs)

cis–[Pt(Cl)₂{P(OMe)₃}₂]

Formula Unicode styled: 
cis–[Pt(Cl)₂{P(OMe)₃}₂]
Compound name(s): 
Dichloro-bis(trimethylphosphito)-platinum
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

cis–[Pd(Cl)₂{P(OMe)₃}₂]

Formula Unicode styled: 
cis–[Pd(Cl)₂{P(OMe)₃}₂]
Compound name(s): 
Dichloro-bis(trimethoxyphosphite)-palladium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

cis–[Mo(CO)₄{P(OMe)₃}₂]

Formula Unicode styled: 
cis–[Mo(CO)₄{P(OMe)₃}₂]
Compound name(s): 
Tetracarbonyl-bis(trimethyl phosphite)-molybdenum
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

cis–[Mo(CO)₄(Pip){P(OMe)₃}]

Formula Unicode styled: 
cis–[Mo(CO)₄(Pip){P(OMe)₃}]
Compound name(s): 
Tetracarbonyl-trimethylphosphite-piperidine-molybdenum
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

cis–[Ir(μ₂-SBuᵗ)(CO){P(OMe)₃}]₂

Formula Unicode styled: 
cis–[Ir(μ₂-SBuᵗ)(CO){P(OMe)₃}]₂
Compound name(s): 
bis(mu-t-Butylthiolato)-bis(carbonyl-trimethylphosphite-iridium)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

cis–[Fe(NCMe)₂{P(OMe)₃}₄]²⊕

Formula Unicode styled: 
cis–[Fe(NCMe)₂{P(OMe)₃}₄]²⊕
Compound name(s): 
bis(Acetonitrile)-tetrakis(trimethylphosphite)-iron(2+)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

cis–[Cr(CO)₂{P(OMe)₃}₂(Cp)]⊕

Formula Unicode styled: 
cis–[Cr(CO)₂{P(OMe)₃}₂(Cp)]⊕
Compound name(s): 
Dicarbonyl-(η-pentamethyl-cyclopentadienyl)-bis(trimethylphosphito)-chromium(1+)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[B(BF₂)(Mes)₂{P(OMe)₃}]

Formula Unicode styled: 
[B(BF₂)(Mes)₂{P(OMe)₃}]
Compound name(s): 
1,1-difluoro-2,2-dimesityl-2-(trimethylphosphite)diborane
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

axial–[Ru(CO)₄{P(OMe)₃}]

Formula Unicode styled: 
axial–[Ru(CO)₄{P(OMe)₃}]
Compound name(s): 
Tetracarbonyl-trimethylphosphite-ruthenium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[Au(Cl){P(OMe)₃}]

Formula Unicode styled: 
[Au(Cl){P(OMe)₃}]
Compound name(s): 
Chloro-(trimethylphosphite-P)-gold
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[Ag(μ₂-O₂NO){P(OMe)₃}₂]₂

Formula Unicode styled: 
[Ag(μ₂-O₂NO){P(OMe)₃}₂]₂
Compound name(s): 
Di-μ-nitrato-tetra-(trimethyl phosphite)-di-silver
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[Ce(O₂)]

Formula Unicode styled: 
[Ce(O₂)]
Compound name(s): 
dioxo-cerium
cerium dioxide
ceric oxide
Central atom: 
Attached groups: 
Charge on central atom: 
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V4C4O-II»
[MLXZ]𝘲 class: 
MLXZ class (ENC, equivalent neutral class): 

cis–[Pt(O₂)(PPh₃)₂]

Formula Unicode styled: 
cis–[Pt(O₂)(PPh₃)₂]
Compound name(s): 
bis(Triphenylphosphine)-dioxo-platinum
Central atom: 
Attached groups: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

trans–[Ir(Cl)(O₂)(CO)(PPh₃)₂]

Formula Unicode styled: 
trans–[Ir(Cl)(O₂)(CO)(PPh₃)₂]
Compound name(s): 
Carbonyl-chloro-peroxo-bis(triphenylphosphine)-iridium
Central atom: 
Attached groups: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

trans–[Ir(SC₆F₅)(O₂)(CO)(PPh₃)₂]

Formula Unicode styled: 
trans–[Ir(SC₆F₅)(O₂)(CO)(PPh₃)₂]
Compound name(s): 
Carbonyl-(pentafluorophenylthiolato)-(peroxo-O,O')-bis(triphenylphosphine)-iridium
Central atom: 
Attached groups: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[Ir(I)(CS)(O₂)(PPh₃)₂]

Formula Unicode styled: 
[Ir(I)(CS)(O₂)(PPh₃)₂]
Compound name(s): 
Iodo-(peroxo-O,O')-thiocarbonyl-bis(triphenylphosphine)-iridium
Central atom: 
Attached groups: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[Ir(SMe)(O₂)(CO)(PPh₃)]

Formula Unicode styled: 
[Ir(SMe)(O₂)(CO)(PPh₃)]
Compound name(s): 
Carbonyl-(methylthiolato)-(peroxo-O,O')-bis(triphenylphosphine)-iridium
Central atom: 
Attached groups: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[Ir(O₂)(Dppm-κ²P)₂]⊕

Formula Unicode styled: 
[Ir(O₂)(Dppm-κ²P)₂]⊕
Compound name(s): 
bis(bis(Diphenylphosphino)methane-P,P')-(η²-peroxo)-iridium(1+)
Central atom: 
Attached groups: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[Re(Me)(OH₂)(O₂)₂]

Formula Unicode styled: 
[Re(Me)(OH₂)(O₂)₂]
Compound name(s): 
Aqua-methyl-bis(peroxo)-oxo-rhenium
Central atom: 
Attached groups: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[W(O)(O₂)₂(OPy)₂]

Formula Unicode styled: 
[W(O)(O₂)₂(OPy)₂]
Compound name(s): 
bis(Peroxo)-bis(pyridine-N-oxide)-oxo-tungsten
Central atom: 
Attached groups: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2