4-coordinate: tetrahedral (p-block element, 2 lone pairs)

mer,cis–[Mn(H)(CO)₂{P(OPh)₃}₃]

Formula Unicode styled: 
mer,cis–[Mn(H)(CO)₂{P(OPh)₃}₃]
Compound name(s): 
Dicarbonyl-hydrido-tris(tri-isopropylphosphite-P)-manganese
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

cis,cis–[Mn(Br)(CO)₂{P(OPh)₃}(Dppm-κ²P)]

Formula Unicode styled: 
cis,cis–[Mn(Br)(CO)₂{P(OPh)₃}(Dppm-κ²P)]
Compound name(s): 
(bis(Diphenylphosphino)methane-P,P')-bromo-dicarbonyl-triphenylphosphite-manganese
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

cis–[Mn{Au(PPh₃)}(CO)₄{P(OPh)₃}]

Formula Unicode styled: 
cis–[Mn{Au(PPh₃)}(CO)₄{P(OPh)₃}]
Compound name(s): 
Triphenylphosphine-gold-tetracarbonyl-triphenoxy-phosphine-manganese
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[Ag(μ₂-O₂NO){P(OPh)₃}₂]₂

Formula Unicode styled: 
[Ag(μ₂-O₂NO){P(OPh)₃}₂]₂
Compound name(s): 
bis(μ₂-Nitrato)-bis(bis(triphenylphosphite)-silver(i))
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[Re(=CH₂){P(OPh)₃}(NO)(Cp*)]⊕

Formula Unicode styled: 
[Re(=CH₂){P(OPh)₃}(NO)(Cp*)]⊕
Compound name(s): 
(η⁵-Pentamethyl-cyclopentadienyl)-methylidene-nitrosyl-triphenylphosphito-rhenium(1+)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

mer,trans–[Cr(CO)₃(CS){P(OPh)₃}₂]

Formula Unicode styled: 
mer,trans–[Cr(CO)₃(CS){P(OPh)₃}₂]
Compound name(s): 
bis(Triphenylphosphite)-tricarbonyl-thiocarbonyl-chromium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

trans–[Mo(CO)₄{P(OPh)₃}₂]

Formula Unicode styled: 
trans–[Mo(CO)₄{P(OPh)₃}₂]
Compound name(s): 
bis(Triphenylphosphito)-tetracarbonyl-molybdenum(0)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[Mo(CO)₅{P(OPh)₃}]

Formula Unicode styled: 
[Mo(CO)₅{P(OPh)₃}]
Compound name(s): 
Triphenylphosphite-pentacarbonyl-molybdenum
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

fac–[Mo(CO)₃{P(OPh)₃}₃]

Formula Unicode styled: 
fac–[Mo(CO)₃{P(OPh)₃}₃]
Compound name(s): 
Tricarbonyl-tris(triphenylphosphite)-molybdenum
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

cis–[Mo(CO)₄{P(OPh)₃}₂]

Formula Unicode styled: 
cis–[Mo(CO)₄{P(OPh)₃}₂]
Compound name(s): 
bis(Triphenylphosphito)-tetracarbonyl-molybdenum(0)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

trans–[Cr(Br)(CO)₂{P(OPh)₃}₂(≡CPh)]

Formula Unicode styled: 
trans–[Cr(Br)(CO)₂{P(OPh)₃}₂(≡CPh)]
Compound name(s): 
Bromo-dicarbonyl-(phenylcarbyne)-bis(triphenylphosphite) chromium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

trans–[Cr(CO)₄{P(OPh)₃}₂]

Formula Unicode styled: 
trans–[Cr(CO)₄{P(OPh)₃}₂]
Compound name(s): 
bis(Triphenylphosphite) tetracarbonyl chromium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

trans–[Cr(CO)₄(PPh₃){P(OPh)₃}]

Formula Unicode styled: 
trans–[Cr(CO)₄(PPh₃){P(OPh)₃}]
Compound name(s): 
Tetracarbonyl-triphenylphosphine-triphenylphosphite-chromium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[Cr(CO)₅{P(OPh)₃}]

Formula Unicode styled: 
[Cr(CO)₅{P(OPh)₃}]
Compound name(s): 
Pentacarbonyl(triphenylphosphite)-chromium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[Au(Cl){P(OPh)₃}]

Formula Unicode styled: 
[Au(Cl){P(OPh)₃}]
Compound name(s): 
Chloro-triphenylphosphite-gold
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[Zr(CO){P(OMe)₃}(Cp)₂]

Formula Unicode styled: 
[Zr(CO){P(OMe)₃}(Cp)₂]
Compound name(s): 
Carbonyl-bis(η⁵-cyclopentadienyl)-trimethylphosphite-zirconium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[W(C≡CMe)(CO)₂{P(OMe)₃}(Cp)]

Formula Unicode styled: 
[W(C≡CMe)(CO)₂{P(OMe)₃}(Cp)]
Compound name(s): 
Dicarbonyl-(η-cyclopentadienyl)-(2-propynyl)-trimethylphosphite-tungsten
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

trans,trans,trans–[W(H)(CO)₂(NO){P(OMe)₃}₂]

Formula Unicode styled: 
trans,trans,trans–[W(H)(CO)₂(NO){P(OMe)₃}₂]
Compound name(s): 
Dicarbonyl-hydrido-nitrosyl-bis(trimethylphosphite)-tungsten
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

trans–[W(CO)(=C=CMePh){P(OMe)₃}₂(Cp)]⊕

Formula Unicode styled: 
trans–[W(CO)(=C=CMePh){P(OMe)₃}₂(Cp)]⊕
Compound name(s): 
Carbonyl-(η⁵-cyclopentadienyl)-(methyl(phenyl)vinylidene)-bis(trimethylphosphito)-tungsten(1+)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

trans–[Mo(I)(CO)₂{P(OMe)₃}(η⁵-C₅H₄Me)]

Formula Unicode styled: 
trans–[Mo(I)(CO)₂{P(OMe)₃}(η⁵-C₅H₄Me)]
Compound name(s): 
pi-(Methylcyclopentadienyl)-trans-iododicarbonyl(trimethyl phosphite) molybdenum
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2