3-coordinate: trigonal planar (p-block element, 1 lone pair)

[C(NPrⁱ₂)₂]

Formula Unicode styled: 
[C(NPrⁱ₂)₂]
Compound name(s): 
bis(di-isopropylamino)-carbene
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
C«V2C2OIIE8B3Z0X2L1»
[MLXZ]𝘲 class: 
[MX2L1]
MLXZ class (ENC, equivalent neutral class): 
MX2L1

[C(NPrⁱ₂)(PPh₃)]⊕

Formula Unicode styled: 
[C(NPrⁱ₂)(PPh₃)]⊕
Compound name(s): 
Di-isopropylamino(triphenylphosphonio)carbene(1+)
Central atom: 
Charge on central atom: 
1
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
C«V2C2OIIE8B3Z0X1L2»
[MLXZ]𝘲 class: 
[MX1L2]+
MLXZ class (ENC, equivalent neutral class): 
MX2L1

[C(PCy₃)(NPrⁱ₂)]⊕

Formula Unicode styled: 
[C(PCy₃)(NPrⁱ₂)]⊕
Compound name(s): 
Di-isopropylamino(tricyclohexylphosphonio)carbene(1+)
Central atom: 
Charge on central atom: 
1
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
C«V2C2OIIE8B3Z0X1L2»
[MLXZ]𝘲 class: 
[MX1L2]+
MLXZ class (ENC, equivalent neutral class): 
MX2L1

[C(Buᵗ)(NPrⁱ₂)]

Formula Unicode styled: 
[C(Buᵗ)(NPrⁱ₂)]
Compound name(s): 
syn-(t-butyl)(N,N-diisopropylamino)carbene
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
C«V2C2OIE8B3Z0X2L1»
[MLXZ]𝘲 class: 
[MX2L1]
MLXZ class (ENC, equivalent neutral class): 
MX2L1

[C(NCy₂)₂]

Formula Unicode styled: 
[C(NCy₂)₂]
Compound name(s): 
N,N,N',N'-tetracyclohexyldiaminocarbene
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
C«V2C2OIIE8B3Z0X2L1»
[MLXZ]𝘲 class: 
[MX2L1]
MLXZ class (ENC, equivalent neutral class): 
MX2L1

trans–[Ru(NO₂-κ²O)(NO)(Ttp)]

Formula Unicode styled: 
trans–[Ru(NO₂-κ²O)(NO)(Ttp)]
Compound name(s): 
Nitrito-nitrosyl-(tetra-p-tolylporphyrinato)-ruthenium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

trans,trans,trans–[Cu(NO₂-κ²O)₂(OH₂)₂{N(CH)₄N}₂]

Formula Unicode styled: 
trans,trans,trans–[Cu(NO₂-κ²O)₂(OH₂)₂{N(CH)₄N}₂]
Compound name(s): 
Diaqua-dinitrato-bis(pyrimidine-N)-copper
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

cis–[Cu(NO₂-κ²O)₂(TMEDA-κ²N)]

Formula Unicode styled: 
cis–[Cu(NO₂-κ²O)₂(TMEDA-κ²N)]
Compound name(s): 
(N,N,N',N'-Tetramethylethylenediamine)-dinitrito-copper
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

cis–[Cu(NO₂-κ²O)₂(Phen)]

Formula Unicode styled: 
cis–[Cu(NO₂-κ²O)₂(Phen)]
Compound name(s): 
Dinitrito-(1,10-phenanthroline-N,N')-copper
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

trans–[Ru(NO₂-κ²O)(NO)(Tpp)]

Formula Unicode styled: 
trans–[Ru(NO₂-κ²O)(NO)(Tpp)]
Compound name(s): 
Tetraphenylporphyrinato-nitroso-(nitrito-O)-ruthenium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

trans–[Ru(NO₂-κ²O)(NO)(Tpp)]

Formula Unicode styled: 
trans–[Ru(NO₂-κ²O)(NO)(Tpp)]
Compound name(s): 
(Tetraphenylporphyrinato)-nitrosyl-nitrito-ruthenium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

trans–[Ru(NO₂-κ²O)(NO)(Oep)]

Formula Unicode styled: 
trans–[Ru(NO₂-κ²O)(NO)(Oep)]
Compound name(s): 
(Octaethylporphyrinato)-nitrosyl-nitrito-ruthenium
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

fac–[Fe(NO₂-κ²O)₃(Tp*-κ³N)]⊖

Formula Unicode styled: 
fac–[Fe(NO₂-κ²O)₃(Tp*-κ³N)]⊖
Compound name(s): 
(hydrogen tris(3,5-dimethylpyrazolyl)borato)-trinitrito-iron(1-)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

fac–[Fe(κN-NO₂)(NO₂-κ²O)(NO)([9]aneN₃-κ³N)]⊕

Formula Unicode styled: 
fac–[Fe(κN-NO₂)(NO₂-κ²O)(NO)([9]aneN₃-κ³N)]⊕
Compound name(s): 
bis(Nitrito)-(nitroso)-(1,4,7-triazacyclononane)-iron(1+)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[Co(NO₂-κ²O)(NH₃)₅]²⊕

Formula Unicode styled: 
[Co(NO₂-κ²O)(NH₃)₅]²⊕
Compound name(s): 
Pentaammine-nitrato-cobalt(2+)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

cis,cis,trans–[Co(NCS-κN)(NO₂-κ²O)(En)₂]⊕

Formula Unicode styled: 
cis,cis,trans–[Co(NCS-κN)(NO₂-κ²O)(En)₂]⊕
Compound name(s): 
bis(Ethylenediamine)-(isothiocyanato)-nitrito-cobalt(1+)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

[Ni(NO₂-κ²O)(NO)(Dppe-κ²P)]₂

Formula Unicode styled: 
[Ni(NO₂-κ²O)(NO)(Dppe-κ²P)]₂
Compound name(s): 
bis-[(μ₂-1,2-bis(Diphenylphosphino)-ethane-P,P')-nitrito-nitrosyl-nickel]
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

mer–[Ni(κN-NO₂)(NO₂-κ²O)(OH₂)(Terpy-κ³N)]

Formula Unicode styled: 
mer–[Ni(κN-NO₂)(NO₂-κ²O)(OH₂)(Terpy-κ³N)]
Compound name(s): 
Aqua-nitrito-nitro-(terpyridyl-N,N',N'')-nickel
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

cis,cis,trans–[Ni(NO₂-κ²O)₂(TMEDA-κ²N)₂]

Formula Unicode styled: 
cis,cis,trans–[Ni(NO₂-κ²O)₂(TMEDA-κ²N)₂]
Compound name(s): 
bis(N,N-Dimethyl-ethylenediamine)-bis(nitrito-O)-nickel
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2

trans–[Al(NO₂-κ²O)₂(Pc)]⊖

Formula Unicode styled: 
trans–[Al(NO₂-κ²O)₂(Pc)]⊖
Compound name(s): 
bis(nitrito-O)-(phthalocyaninato)-aluminium(1-)
Central atom: 
Charge on central atom: 
0
Compound type: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
Oxidation Number (ON) (Roman numerals): 
Coordination Number (CN, sum of attached group denticities): 
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
Summary of calculated classifications: 
O«V2C2O-IIE8B2Z0L0X2»
[MLXZ]𝘲 class: 
[MX2]
MLXZ class (ENC, equivalent neutral class): 
MX2