Tungsten

Cp* (η⁵-pentamethylcyclopentadienyl)

Attached groups:

CH₂ (μ₂-methylidene)

O (oxo ⭀O X₂L)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

CN: 7

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁷O^VE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

catena–1D-trans–[W(Cl)₄(μ₂–O)]

Formula Unicode styled:

catena–1D-trans–[W(Cl)₄(μ₂–O)]

Compound name(s):

catena-[tetrachloro-oxo-tungsten|

Central atom:

Attached groups:

Cl (chloro)

O (μ₂–oxo X₂L)

Charge on central atom:

0

Compound type:

Catena-1D

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

W«V⁶C⁶O^VIE¹⁴B⁷Z⁰X⁶L¹»

[MLXZ]𝘲 class:

[MX₆L₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

trans–[W(μ₂-O₂CPh)₂(Thf)]₂

Formula Unicode styled:

trans–[W(μ₂-O₂CPh)₂(Thf)]₂

Compound name(s):

bis-[bis(μ₂-Benzoato)-(tetrahydrofuran)-tungsten(W≣W)]

Central atom:

Attached groups:

O₂CPh (μ₂-benzoato)

Thf (tetrahydrofuran)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^IIE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

trans–[W(μ₂-O₂CCF₃)₂(PPh₃)]₂

Formula Unicode styled:

trans–[W(μ₂-O₂CCF₃)₂(PPh₃)]₂

Compound name(s):

bis-[bis-(μ₂-Trifluoroacetato)-(triphenylphosphine)-tungsten(W≣W)]

Central atom:

O₂CCF₃ (μ₂-trifluoroacetato)

Attached groups:

PPh₃ (triphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^IIE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

trans–[W(Cl)₄(PhC≡CPh)(OPCl₃)]

Formula Unicode styled:

trans–[W(Cl)₄(PhC≡CPh)(OPCl₃)]

Compound name(s):

(η²-Diphenylacetylene)-tetrachloro-(trichlorophosphine oxide-O)-tungsten

Central atom:

OPCl₃ (trichlorophosphane oxide)

Attached groups:

Cl (chloro)

PhC≡CPh (diphenylethyne)

Charge on central atom:

0

Compound type:

Molecular

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

W«V⁴C⁶O^IVE¹⁴B⁶Z⁰X⁴L²»

[MLXZ]𝘲 class:

[MX₄L₂]

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

mer,cis–[W(μ₂-SPh)(CO)₃(≡CNEt₂)]₂

Formula Unicode styled:

mer,cis–[W(μ₂-SPh)(CO)₃(≡CNEt₂)]₂

Compound name(s):

bis-[(μ₂-Phenylthio)-tricarbonyl-(diethylamino)carbyne)-tungsten]

Central atom:

Attached groups:

SPh (μ₂-phenylthio)

≡CNEt₂ (diethylaminomethylidyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁴C⁶O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

fac–[W(NMe₂)(CO)₂(Tp*-κ³N)]

Formula Unicode styled:

fac–[W(NMe₂)(CO)₂(Tp*-κ³N)]

Compound name(s):

Dicarbonyl-(hydrogen tris(3,5-dimethylpyrazolyl)borate)-dimethylammonio-tungsten

Central atom:

NMe₂ (dimethylamino: planar)

Attached groups:

Tp* (hydrotris(3,5-dimethylpyrazolyl)borato-κ³N)

Charge on central atom:

0

Compound type:

Molecular

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V²C⁶O^IIE¹⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

fac–[W(Br)(μ₂-Br)(CO)₂(⭀NPh)]₂

Formula Unicode styled:

fac–[W(Br)(μ₂-Br)(CO)₂(⭀NPh)]₂

Compound name(s):

bis-[(μ₂-Bromo)-bromo-dicarbonyl-(phenylimido)-tungsten]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁴C⁶O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

cis,cis,trans–[W(I)(μ₂-OMe)(CO)₂(⭀NPh)]₂

Formula Unicode styled:

cis,cis,trans–[W(I)(μ₂-OMe)(CO)₂(⭀NPh)]₂

Compound name(s):

bis-[(μ₂-Methoxo)-dicarbonyl-iodo-phenylnitrido-tungsten]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁴C⁶O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

cis–[W(F)₄(μ₂–O)]₄

Formula Unicode styled:

cis–[W(F)₄(μ₂–O)]₄

Compound name(s):

tetrakis-[tetrafluoro-oxo-tungsten]

Central atom:

Attached groups:

F (fluoro)

O (μ₂–oxo X₂L)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

W«V⁶C⁶O^VIE¹⁴B⁷Z⁰X⁶L¹»

[MLXZ]𝘲 class:

[MX₆L₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₁

cis,cis–[W(μ₂-N₃)(CO)₂(≡CNEt₂)]₂

Formula Unicode styled:

cis,cis–[W(μ₂-N₃)(CO)₂(≡CNEt₂)]₂

Compound name(s):

bis-[(μ₂-Azido)-bis(tricarbonyl-((diethylamino)-carbyne)-tungsten)

Central atom:

Attached groups:

N₃ (μ₂-azido)

≡CNEt₂ (diethylaminomethylidyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁴C⁶O^IVE¹⁶B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

cis–[W(μ₂-SPh)(CO)₄]₂²⊖

Formula Unicode styled:

cis–[W(μ₂-SPh)(CO)₄]₂²⊖

Compound name(s):

bis-[(μ₂-phenylthiolato)-tetracarbonyl-tungsten(1-)]

Central atom:

Attached groups:

SPh (μ₂-phenylthio)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁰C⁶O^OE¹⁸B⁶Z⁰X¹L⁵»^⊖

[MLXZ]𝘲 class:

[MX₁L₅]^-

MLXZ class (ENC, equivalent neutral class):

ML₆

cis–[W(μ₂-SPh)(CO)₄]₂

Formula Unicode styled:

cis–[W(μ₂-SPh)(CO)₄]₂

Compound name(s):

bis-[(μ₂-phenylthiolato)-tetracarbonyl-tungsten(W—W)]

Central atom:

Attached groups:

SPh (μ₂-phenylthio)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V²C⁶O^IE¹⁸B⁷Z⁰X²L⁵»

[MLXZ]𝘲 class:

[MX₂L₅]

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

cis–[W(OMe)₃(μ₂-OMe)(O)]₂

Formula Unicode styled:

cis–[W(OMe)₃(μ₂-OMe)(O)]₂

Compound name(s):

bis-[(μ₂-Methoxo)-tris(methoxy)-(oxo)-tungsten]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^VIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

cis–[W(OMe)₃(μ₂-OMe)(⭀NPh)]₂

Formula Unicode styled:

cis–[W(OMe)₃(μ₂-OMe)(⭀NPh)]₂

Compound name(s):

bis-[(μ₂-Methoxo)-tris(methoxy)-(phenylimido)-tungsten]

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^VIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

cis–[W(μ₂-OMe)(CO)₄]₂²⊖

Formula Unicode styled:

cis–[W(μ₂-OMe)(CO)₄]₂²⊖

Compound name(s):

bis-[(μ₂-methoxo)-tetracarbonyl-tungsten(1-)]

Central atom:

Attached groups:

OMe (μ₂-methoxy)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁰C⁶O^OE¹⁸B⁶Z⁰X¹L⁵»^⊖

[MLXZ]𝘲 class:

[MX₁L₅]^-

MLXZ class (ENC, equivalent neutral class):

ML₆

cis–[W(F)₂(μ₂-F)(O)₂]₂²⊖

Formula Unicode styled:

cis–[W(F)₂(μ₂-F)(O)₂]₂²⊖

Compound name(s):

bis-[trifluoro-dioxo-tungsten(1-)]

Central atom:

Attached groups:

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^VIE¹⁶B⁸Z⁰X⁷L¹»^⊖

[MLXZ]𝘲 class:

[MX₇L₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

cis–[W(CO)₂(Dmpe)(Cp)]⊕

Formula Unicode styled:

cis–[W(CO)₂(Dmpe)(Cp)]⊕

Compound name(s):

Dicarbonyl-(η⁵-pentadienyl)-(bis(dimethylphosphino)ethane-P,P')-tungsten(1+)

Central atom:

Attached groups:

Dmpe (1,2-bis-(dimethylphosphino)ethane)

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

1

Compound type:

Molecular

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 7

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V²C⁷O^IIE¹⁸B⁷Z⁰X¹L⁶»^⊕

[MLXZ]𝘲 class:

[MX₁L₆]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₅

cis–[W(Cl)₂(μ₂-Cl)(NO)₂]₂²⊖

Formula Unicode styled:

cis–[W(Cl)₂(μ₂-Cl)(NO)₂]₂²⊖

Compound name(s):

bis-[(μ₂-chloro)-dichloro-dinitrosyl-tungsten(1-)]

Central atom:

(NO)₂ (dinitrosyl, (N≡O)₂ cis-octahedral Ⓢ)

Attached groups:

Cl (chloro)

Cl (μ₂-chloro)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^OE¹⁸B⁹X⁵L³Z¹»^⊖

[MLXZ]𝘲 class:

[MX₅L₃Z₁]^-

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

catena–1D-[W(I)₂(μ₂-I)(μ₂–O)]

Formula Unicode styled:

catena–1D-[W(I)₂(μ₂-I)(μ₂–O)]

Compound name(s):

catena-[triiodo-oxo-tungsten(W—W)|

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Catena-1D

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

CN: 7

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: