cis–[W(μ₂-SPh)(CO)₄]₂²⊖

Formula Unicode styled:

Compound name(s):

bis-[(μ₂-phenylthiolato)-tetracarbonyl-tungsten(1-)]

Central atom:

Tungsten

Charge on formula unit (QN):

1–

Attached groups:

SPh (μ₂-phenylthio)

CO (carbonyl)

Compound type:

Oligomer

DOI link to literature report:

10.1021/ic00293a040

Crystal data CSD link:

jabjif

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Coordination Number (CN, sum of attached group denticities):

CN: 6

Oxidation Number (ON) (Roman numerals):

ON: (O)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[MX₁L₅]^-

MLXZ class (ENC, equivalent neutral class):

ML₆

Summary of calculated classifications:

W«V⁰C⁶O^OE¹⁸B⁶Z⁰X¹L⁵»^⊖

Geometry:

6-coordinate: octahedron (OC-6)

Isomer label:

cis

𝘥-electron configuration = 𝘮 – VN:

d⁶

𝘥-electron configuration = 𝘮 – ON:

d⁶

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d⁶

Attached atoms:

C₄S₂

Phase:

Solid

InChIKey (see www.inchi-trust.org):

HOUVAAOGOIXZPQ-UHFFFAOYSA-N