Tungsten

Attached groups:

⭀NPh (phenylimino)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁴C⁶O^IVE¹⁸B⁸Z⁰X³L⁵»^⊕

[MLXZ]𝘲 class:

[MX₃L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

fac–[W(CO)₂(=CMePh)(Tp*-κ³N)]⊕

Formula Unicode styled:

fac–[W(CO)₂(=CMePh)(Tp*-κ³N)]⊕

Compound name(s):

(Methylphenylmethylidene)-dicarbonyl-(hydrogentris(3,5-dimethylpyrazolyl)borate-N,N',N'')-tungsten(1+)

Central atom:

Attached groups:

=CMePh (methylbenzylidene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁴C⁶O^IVE¹⁶B⁷Z⁰X³L⁴»^⊕

[MLXZ]𝘲 class:

[MX₃L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

fac–[W(CO)(NCMe)(PhC≡CPh)(Tp*-κ³N)]⊕

Formula Unicode styled:

fac–[W(CO)(NCMe)(PhC≡CPh)(Tp*-κ³N)]⊕

Compound name(s):

(η²-1,2-Diphenylacetylene)-acetonitrile-carbonyl-(hydrogen tris(3,5-dimethylpyrazolyl)borato)-tungsten(1+)

Central atom:

Attached groups:

NCMe (acetonitrile)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V²C⁶O^IIE¹⁶B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

fac–[W(CO)(NCMe)(PhC≡CH)(Tp*-κ³N)]⊕

Formula Unicode styled:

fac–[W(CO)(NCMe)(PhC≡CH)(Tp*-κ³N)]⊕

Compound name(s):

bis(η²-Phenylacetylene)-carbonyl-(hydrogen tris(3,5-dimethylpyrazolyl)borate-N,N',N'')-tungsten

Central atom:

Attached groups:

NCMe (acetonitrile)

PhC≡CH (phenylethyne)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V²C⁶O^IIE¹⁶B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

cis,trans–[W(Cl)₂(CO)(PMePh₂)₂(≡CPPh₃)]

Formula Unicode styled:

cis,trans–[W(Cl)₂(CO)(PMePh₂)₂(≡CPPh₃)]

Compound name(s):

Carbonyl-dichloro-bis(diphenylmethylphosphine)-(triphenylphosphino)carbyne-tungsten

Central atom:

Attached groups:

PMePh₂ (methyldiphenylphosphane)

≡CPPh₃ (triphenylphosphinomethylidyne)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 5

Oxidation Number (ON) (Roman numerals):

ON: (V)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

W«V⁵C⁶O^VE¹⁷B⁸Z⁰X⁵L³»

[MLXZ]𝘲 class:

[MX₅L₃]

MLXZ class (ENC, equivalent neutral class):

MX₅L₃

cis,trans–[W(Cl)₂(CO)(PMePh₂)₂(PhC≡CPh)]

Formula Unicode styled:

cis,trans–[W(Cl)₂(CO)(PMePh₂)₂(PhC≡CPh)]

Compound name(s):

(η²-Diphenylacetylene)-carbonyl-dichloro-bis(diphenylmethylphosphine)-tungsten

Central atom:

Attached groups:

PMePh₂ (methyldiphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V²C⁶O^IIE¹⁶B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

cis,trans–[W(Cl)₂(CH₂Buᵗ)(PHPh)(PEt₃)₂]

Formula Unicode styled:

cis,trans–[W(Cl)₂(CH₂Buᵗ)(PHPh)(PEt₃)₂]

Compound name(s):

Dichloro-bis(triethylphosphine)-neopentylidyne-phenylphosphido-tungsten

Central atom:

Attached groups:

CH₂Buᵗ (t-butylmethyl)

PHPh (phenylphosphanyl)

PEt₃ (triethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

PMe₂Ph (dimethylphenylphosphane)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 14

Summary of calculated classifications:

W«V⁴C⁶O^IVE¹⁴B⁶Z⁰X⁴L²»

[MLXZ]𝘲 class:

[MX₄L₂]

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

cis,trans–[W(Cl)₂(=NTol)(CO)(PMe₂Ph)₂]

Formula Unicode styled:

cis,trans–[W(Cl)₂(=NTol)(CO)(PMe₂Ph)₂]

Compound name(s):

Carbonyl-dichloro-(p-tolylimido)-bis(methyldiphenylphosphine)-tungsten

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁴C⁶O^IVE¹⁶B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

cis,trans–[W(Cl)₂(⭀NPh)(PMe₃)₂(PhC≡CPh)]

Formula Unicode styled:

cis,trans–[W(Cl)₂(⭀NPh)(PMe₃)₂(PhC≡CPh)]

Compound name(s):

Dichloro-(η²-diphenylacetylene)-trans-bis(trimethylphosphine)-phenylimido-tungsten

Central atom:

Attached groups:

PMe₃ (trimethylphosphane)

⭀NPh (phenylimino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁴C⁶O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

cis,trans–[W(Cl)₂(⭀NBuᵗ)(PMe₃)₂(PhC≡CPh)]

Formula Unicode styled:

cis,trans–[W(Cl)₂(⭀NBuᵗ)(PMe₃)₂(PhC≡CPh)]

Compound name(s):

(η²-Diphenylacetylene)-t-butylimido-dichloro-bis(trimethylphosphine)-tungsten

Central atom:

Attached groups:

PMe₃ (trimethylphosphane)

⭀NBuᵗ (⭀N t-butylimino)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁴C⁶O^IVE¹⁸B⁸Z⁰X⁴L⁴»

[MLXZ]𝘲 class:

[MX₄L₄]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

cis,trans–[W(CO)(NO)(O₂CMe)(PPh₃)₂]

Formula Unicode styled:

cis,trans–[W(CO)(NO)(O₂CMe)(PPh₃)₂]

Compound name(s):

trans-(Acetato-O,O')-carbonyl-nitrosyl-bis(triphenylphosphine)-tungsten

Central atom:

Attached groups:

PPh₃ (triphenylphosphane)

NO (nitrosyl, linear)

O₂CMe (acetato-κ²O)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁴C⁶O^OE¹⁸B⁸X²L⁵Z¹»

[MLXZ]𝘲 class:

[MX₂L₅Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₄L₄

cis,trans–[W(=CHPh)(CO)(PMe₃)₂(Dedtc)]

Formula Unicode styled:

cis,trans–[W(=CHPh)(CO)(PMe₃)₂(Dedtc)]

Compound name(s):

Benzylidyne-carbonyl-(diethyldithiocarbamato-S,S')-bis(trimethylphosphine)-tungsten

Central atom:

Attached groups:

=CHPh (benzylidene)

PMe₃ (trimethylphosphane)

Dedtc (diethyldithiocarbamato-κ²S)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

W«V³C⁶O^IIIE¹⁷B⁷Z⁰X³L⁴»

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

cis,cis,trans–[W(F)₂(O)₂(Bpy)]

Formula Unicode styled:

cis,cis,trans–[W(F)₂(O)₂(Bpy)]

Compound name(s):

2,2'-Bipyridyl-difluoro-dioxo-tungsten

Central atom:

Attached groups:

F (fluoro)

Bpy (bipyridine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^VIE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

cis,cis,trans–[W(Cl)₂(O)₂(OPPh₃)₂]

Formula Unicode styled:

cis,cis,trans–[W(Cl)₂(O)₂(OPPh₃)₂]

Compound name(s):

Dichlorodioxo-bis(triphenylphosphine oxide)-tungsten

Central atom:

Attached groups:

OPPh₃ (triphenylphosphane oxide)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^VIE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

cis,cis,trans–[W(Cl)₂(O)₂(Bpy)]

Formula Unicode styled:

cis,cis,trans–[W(Cl)₂(O)₂(Bpy)]

Compound name(s):

(2,2'-Bipyridyl)-dichloro-dioxo-tungsten

Central atom:

Attached groups:

Bpy (bipyridine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^VIE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

cis,cis,trans–[W(SPh)₂(O)(Phen)]

Formula Unicode styled:

cis,cis,trans–[W(SPh)₂(O)(Phen)]

Compound name(s):

Dioxo-(1,10-phenanthroline)-bis(phenylthiolato)-tungsten

Central atom:

Attached groups:

SPh (phenylthio)

O (oxo ⭀O X₂L)

Phen (phenanthroline)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁴C⁵O^IVE¹⁶B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

cis,cis,trans–[W(SO₃CF₃-κO)₂(=NBuᵗ)(⭀NBuᵗ)(NH₂Buᵗ)]

Formula Unicode styled:

cis,cis,trans–[W(SO₃CF₃-κO)₂(=NBuᵗ)(⭀NBuᵗ)(NH₂Buᵗ)]

Compound name(s):

bis(Trifluoromethanesulfonato-O)-bis(t-butylimido)-bis(t-butylamino)-tungsten

Central atom:

OSO₂CF₃ (trifluoromethanesulfonato-κO)

Attached groups:

=NBuᵗ (t-butylimino)

⭀NBuᵗ (⭀N t-butylimino)

NH₂Buᵗ (t-butylamine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁵O^VIE¹⁶B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

cis,cis,cis–[W(Cl)₂(O)₂(TMEDA-κ²N)]

Formula Unicode styled:

cis,cis,cis–[W(Cl)₂(O)₂(TMEDA-κ²N)]

Compound name(s):

Dichloro-dioxo-N,N,N',N'-tetramethylethylenediamine-tungsten

Central atom:

Attached groups:

TMEDA (tetramethylethylenediamine-κ²N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁶C⁶O^VIE¹⁸B⁹Z⁰X⁶L³»

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

[W(CO)₂(MeO₂C)C≡C(CO₂Me)₂(Dppe-κ²P)]

Formula Unicode styled:

[W(CO)₂(MeO₂C)C≡C(CO₂Me)₂(Dppe-κ²P)]

Compound name(s):

bis(Carbonyl-(η²-dimethyl acetylenedicarboxylate))-(bis(diphenylphosphino)ethane-P,P')-tungsten

Central atom:

Attached groups:

(MeO₂C)C≡C(CO₂Me) (dimethylacetylenedicarboxylate)

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 0

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

W«V⁰C⁶O^OE¹⁸B⁶Z⁰X⁰L⁶»

[MLXZ]𝘲 class:

[ML₆]

MLXZ class (ENC, equivalent neutral class):

ML₆

cis,cis–[W(I)₂(CO)(NCMe)(PhC≡CPh)₂]

Formula Unicode styled:

cis,cis–[W(I)₂(CO)(NCMe)(PhC≡CPh)₂]

Compound name(s):

Acetonitrile-carbonyl-di-iodo-bis(η²-diphenylacetylene)-tungsten

Central atom:

Attached groups:

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: