cis,cis,trans–[W(Cl)₂(O)₂(OPPh₃)₂]

Formula Unicode styled:

Compound name(s):

Dichlorodioxo-bis(triphenylphosphine oxide)-tungsten

Central atom:

Tungsten

Charge on formula unit (QN):

Attached groups:

Cl (chloro)

(O)₂ (dioxo-cis X₄L Ⓢ)

OPPh₃ (triphenylphosphane oxide)

Compound type:

Molecular

DOI link to literature report:

10.1107/S0567740878004021

Crystal data CSD link:

cxphow

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 6

Coordination Number (CN, sum of attached group denticities):

CN: 6

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[MX₆L₃]

MLXZ class (ENC, equivalent neutral class):

MX₆L₃

Summary of calculated classifications:

W«V⁶C⁶O^VIE¹⁸B⁹Z⁰X⁶L³»

Geometry:

6-coordinate: octahedron (OC-6)

Isomer label:

cis,cis,trans

𝘥-electron configuration = 𝘮 – VN:

d⁰

𝘥-electron configuration = 𝘮 – ON:

d¹⁰

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d⁰

Attached atoms:

Cl₂O₄

Phase:

Solid

InChIKey (see www.inchi-trust.org):

JHINNAJDMUPNKE-UHFFFAOYSA-L