Osmium

Attached groups:

H (hydrido)

PPh₃ (triphenylphosphane)

[9]aneS₃ (1,4,7-trithiocyclononane-κ²S)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

CN: 5

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Os«V²C⁵O^IIE¹⁶B⁵Z⁰X¹L⁴»^⊕

[MLXZ]𝘲 class:

[MX₁L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

fac–[Os(Cl)₃(NCS-κN)₃]²⊖

Formula Unicode styled:

fac–[Os(Cl)₃(NCS-κN)₃]²⊖

Compound name(s):

trichloro-tris(isothiocyanato)-osmium(2-)

Central atom:

Attached groups:

NCS (isothiocyanato-κN)

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Summary of calculated classifications:

Os«V⁴C⁶O^IVE¹⁶B⁶Z⁰L⁰X⁶»^2⊖

[MLXZ]𝘲 class:

[MX₆]^2-

MLXZ class (ENC, equivalent neutral class):

MX₄L₂

fac–[Os(Cl)₂(N)(Tpm-κ³N)]⊕

Formula Unicode styled:

fac–[Os(Cl)₂(N)(Tpm-κ³N)]⊕

Compound name(s):

Dichloro-nitrido-(tris(1-pyrazolyl)methane)-osmium(1+)

Central atom:

Attached groups:

Tpm (tris(pyrazolyl)methane-κ³N)

N (nitrido; ≡N)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^VIE¹⁸B⁸Z⁰X⁵L³»^⊕

[MLXZ]𝘲 class:

[MX₅L₃]⁺

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

fac–[Os(Cl)₂(NSe)(Tp-κ³N)]

Formula Unicode styled:

fac–[Os(Cl)₂(NSe)(Tp-κ³N)]

Compound name(s):

Dichloro-(hydrogen tripyrazolylborato)-selenonitrosyl-osmium

Central atom:

Attached groups:

NSe (selenonitrosyl, linear)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^IIE¹⁸B⁸X⁴L³Z¹»

[MLXZ]𝘲 class:

[MX₄L₃Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

fac–[Os(Cl)₂(NS)(Tpm-κ³N)]⊕

Formula Unicode styled:

fac–[Os(Cl)₂(NS)(Tpm-κ³N)]⊕

Compound name(s):

Dichloro-(tris(1-pyrazolyl)methane)-thionitrosyl-osmium(1+)

Central atom:

Attached groups:

NS (thionitrosyl, linear)

Tpm (tris(pyrazolyl)methane-κ³N)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^IIE¹⁸B⁸X³L⁴Z¹»^⊕

[MLXZ]𝘲 class:

[MX₃L₄Z₁]⁺

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

fac–[Os(Cl)₂(NS)(Tp-κ³N)]⊕

Formula Unicode styled:

fac–[Os(Cl)₂(NS)(Tp-κ³N)]⊕

Compound name(s):

Dichloro-(hydrogen tris(1-pyrazolyl)borate)-thionitrosyl-osmium(1+)

Central atom:

Attached groups:

NS (thionitrosyl, linear)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 7

Oxidation Number (ON) (Roman numerals):

ON: (III)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 17

Summary of calculated classifications:

Os«V⁷C⁶O^IIIE¹⁷B⁸X⁴L³Z¹»^⊕

[MLXZ]𝘲 class:

[MX₄L₃Z₁]⁺

MLXZ class (ENC, equivalent neutral class):

MX₇L₁

fac–[Os(Cl)₂(Dmso-κS)₃(PzH)]

Formula Unicode styled:

fac–[Os(Cl)₂(Dmso-κS)₃(PzH)]

Compound name(s):

Dichloro-tris(dimethylsulfoxide-S)-(pyrazole-N²)-osmium

Central atom:

Attached groups:

Dmso (dimethylsulfoxide-κS)

PzH (pyrazole)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

fac–[Os(Cl)₂(Dmso-κS)₃(N₂C₃H₄)]

Formula Unicode styled:

fac–[Os(Cl)₂(Dmso-κS)₃(N₂C₃H₄)]

Compound name(s):

Dichloro-tris(dimethylsulfoxide-S)-(imidazole-N³)-osmium

Central atom:

Attached groups:

Dmso (dimethylsulfoxide-κS)

N₂C₃H₄ (Imidazole)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

fac–[Os(Cl)(CO)(PPh₃)([9]aneN₃-1,4,7-Me₃-κ³N)]⊕

Formula Unicode styled:

fac–[Os(Cl)(CO)(PPh₃)([9]aneN₃-1,4,7-Me₃-κ³N)]⊕

Compound name(s):

bis(Carbonyl-chloro-(1,4,7-triazacyclononane)-triphenylphosphine-osmium(1+)

Central atom:

Attached groups:

PPh₃ (triphenylphosphane)

[9]aneN₃-1,4,7-Me₃ (1,4,7-trimethyl-1,4,7-triazacyclononane-κ³N)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

fac–[Os(η²-H₂)₂(PPrⁱ₃)(Tp-κ³N)]⊕

Formula Unicode styled:

fac–[Os(η²-H₂)₂(PPrⁱ₃)(Tp-κ³N)]⊕

Compound name(s):

(Hydrogen tris(pyrazolyl)borate-N,N',N'')-bis(dihydrogen-H,H')-(tri-isopropylphosphine)-osmium(1+)

Central atom:

PPrⁱ₃ (triisopropylphosphane)

Attached groups:

H₂ (η²-dihydrogen)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

fac–[Os(η²-H₂)(O=CMe₂)(PPrⁱ₃)(Tp-κ³N)]⊕

Formula Unicode styled:

fac–[Os(η²-H₂)(O=CMe₂)(PPrⁱ₃)(Tp-κ³N)]⊕

Compound name(s):

(Hydrogen tris(pyrazolyl)borate-N,N',N'')-(dihydrogen-H,H')-(tri-isopropylphosphine)-(acetone-O)-osmium(1+)

Central atom:

PPrⁱ₃ (triisopropylphosphane)

Attached groups:

H₂ (η²-dihydrogen)

O=CMe₂ (acetone)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

fac–[Os(O₂CMe-κO)₂(NS)(Tp-κ³N)]

Formula Unicode styled:

fac–[Os(O₂CMe-κO)₂(NS)(Tp-κ³N)]

Compound name(s):

bis(acetato-O)-(hydrogen tris(1-pyrazolyl)borato-N,N',N'')-(thionitrosyl)-osmium

Central atom:

NS (thionitrosyl, linear)

Attached groups:

O₂CMe (acetato-κO)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^IIE¹⁸B⁸X⁴L³Z¹»

[MLXZ]𝘲 class:

[MX₄L₃Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

fac–[Os(O₂CCF₃-κO)₂(N)(Tp-κ³N)]

Formula Unicode styled:

fac–[Os(O₂CCF₃-κO)₂(N)(Tp-κ³N)]

Compound name(s):

bis(Trifluoroacetato-O)-(hydrogen tris(pyrazol-1-yl)borate)-nitrido-osmium

Central atom:

O₂CCF₃ (trifluoroacetato-κO)

Attached groups:

N (nitrido; ≡N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^VIE¹⁸B⁸Z⁰X⁶L²»

[MLXZ]𝘲 class:

[MX₆L₂]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

fac–[Os(SO₃CF₃-κO)₂(NHPh)(Tp-κ³N)]

Formula Unicode styled:

fac–[Os(SO₃CF₃-κO)₂(NHPh)(Tp-κ³N)]

Compound name(s):

(Hydrogen tris(pyrazolyl)borate)-phenylamido-bis(trifluoromethanesulfonato-O)-osmium

Central atom:

OSO₂CF₃ (trifluoromethanesulfonato-κO)

Attached groups:

NHPh (phenylamino: planar)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁴C⁶O^IVE¹⁸B⁷Z⁰X⁴L³»

[MLXZ]𝘲 class:

[MX₄L₃]

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

fac–[Os(OMe)(η⁴-Cod)(Tp-κ³N)]

Formula Unicode styled:

fac–[Os(OMe)(η⁴-Cod)(Tp-κ³N)]

Compound name(s):

(eta⁴-1,5-Cyclo-octadienyl)-(hydrogen tris(pyrazolyl)borate)-methoxy-osmium

Central atom:

Cod (η²,η²-cycloocta-1,5-diene)

Attached groups:

OMe (methoxy)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

fac–[Os(O=CMe₂)₂(PPrⁱ₃)(Tp-κ³N)]⊕

Formula Unicode styled:

fac–[Os(O=CMe₂)₂(PPrⁱ₃)(Tp-κ³N)]⊕

Compound name(s):

(Hydrogen tris(pyrazolyl)borate-N,N',N'')-bis(acetone-O)-(tri-isopropylphosphine)-osmium(1+)

Central atom:

PPrⁱ₃ (triisopropylphosphane)

Attached groups:

O=CMe₂ (acetone)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

fac–[Os(NCMe)₃(PMe₂Ph)₃]²⊕

Formula Unicode styled:

fac–[Os(NCMe)₃(PMe₂Ph)₃]²⊕

Compound name(s):

tris(Acetonitrile)-tris(dimethylphenylphosphine)-osmium(2+)

Central atom:

PMe₂Ph (dimethylphenylphosphane)

Attached groups:

NCMe (acetonitrile)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X⁰L⁶»^2⊕

[MLXZ]𝘲 class:

[ML₆]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

fac–[Os(NCMe)(PPh₃)₂(Cp)]⊕

Formula Unicode styled:

fac–[Os(NCMe)(PPh₃)₂(Cp)]⊕

Compound name(s):

(Acetonitrile)-(η⁵-cyclopentadienyl)-bis(triphenylphosphine)-osmium(1+)

Central atom:

PPh₃ (triphenylphosphane)

Attached groups:

NCMe (acetonitrile)

Cp (η⁵-cyclopentadienyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

fac–[Os(CO)₃(μ₂-O₂CPh)]₂

Formula Unicode styled:

fac–[Os(CO)₃(μ₂-O₂CPh)]₂

Compound name(s):

bis(μ₂-benzoato)-hexacarbonyl-di-osmium

Central atom:

Attached groups:

O₂CPh (μ₂-benzoato)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

fac–[Os(CO)₃(μ₂-O₂CH)]₂

Formula Unicode styled:

fac–[Os(CO)₃(μ₂-O₂CH)]₂

Compound name(s):

bis(μ₂-formato)-hexacarbonyl-di-osmium

Central atom:

Attached groups:

O₂CH (μ₂-formato)

Charge on central atom:

0

Compound type:

Oligomer

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (I)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: