Osmium

Dppm (bis-(diphenylphosphino)methane-κ²P)

Attached groups:

=CH₂ (methylidene)

Cp* (η⁵-pentamethylcyclopentadienyl)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 4

Oxidation Number (ON) (Roman numerals):

ON: (IV)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁴C⁶O^IVE¹⁸B⁷Z⁰X³L⁴»^⊕

[MLXZ]𝘲 class:

[MX₃L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₄L₃

mer,trans–[Os(Cl)₃(SnCl₃)₂(NO)]²⊖

Formula Unicode styled:

mer,trans–[Os(Cl)₃(SnCl₃)₂(NO)]²⊖

Compound name(s):

bis(trichloro-tin)-trichloro-nitrosyl-osmium(2-)

Central atom:

Attached groups:

SnCl₃ (trichlorostannyl)

Charge on central atom:

-2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^IIE¹⁸B⁸X⁶L¹Z¹»^2⊖

[MLXZ]𝘲 class:

[MX₆L₁Z₁]^2-

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

mer,trans–[Os(Cl)₃(NS)(PPh₃)₂]

Formula Unicode styled:

mer,trans–[Os(Cl)₃(NS)(PPh₃)₂]

Compound name(s):

Trichloro-(thionitrosyl)-bis(triphenylphosphine)-osmium

Central atom:

Attached groups:

NS (thionitrosyl, linear)

PPh₃ (triphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^IIE¹⁸B⁸X⁴L³Z¹»

[MLXZ]𝘲 class:

[MX₄L₃Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

mer,trans–[Os(Cl)₂(PPrⁱ₃)(Py)₃]

Formula Unicode styled:

mer,trans–[Os(Cl)₂(PPrⁱ₃)(Py)₃]

Compound name(s):

Dichloro-tris(pyridine)-(tri-isopropylphosphine)-osmium

Central atom:

Attached groups:

PPrⁱ₃ (triisopropylphosphane)

Py (pyridine)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

mer,trans–[Os(Cl)₂(NO)(Terpy-κ³N)]⊕

Formula Unicode styled:

mer,trans–[Os(Cl)₂(NO)(Terpy-κ³N)]⊕

Compound name(s):

Dichloro-nitroso-(2,2':6,2''-terpyridine-N,N',N'')-osmium(1+)

Central atom:

Attached groups:

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^IIE¹⁸B⁸X³L⁴Z¹»^⊕

[MLXZ]𝘲 class:

[MX₃L₄Z₁]⁺

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

mer,trans–[Os(GaCl₃)(CO)₃(PMe₃)₂]

Formula Unicode styled:

mer,trans–[Os(GaCl₃)(CO)₃(PMe₃)₂]

Compound name(s):

tricarbonyl-trichloro-bis(trimethylphosphine)-gallium-osmium

Central atom:

PMe₃ (trimethylphosphane)

Attached groups:

GaCl₃ (trichlorogallane)

CO (carbonyl)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^OE¹⁸B⁶X⁰L⁵Z¹»

[MLXZ]𝘲 class:

[ML₅Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

mer,cis–[Os(H)(C₂H₄)₂(PMe₂Ph)₃]⊕

Formula Unicode styled:

mer,cis–[Os(H)(C₂H₄)₂(PMe₂Ph)₃]⊕

Compound name(s):

bis(η²-Ethylene)-tris(dimethylphenylphosphine)-hydrido-osmium(1+)

Central atom:

PMe₂Ph (dimethylphenylphosphane)

Attached groups:

H (hydrido)

C₂H₄ (ethene)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

mer,cis–[Os(Cl)₂(N)(Terpy-κ³N)]⊕

Formula Unicode styled:

mer,cis–[Os(Cl)₂(N)(Terpy-κ³N)]⊕

Compound name(s):

Dichloro-(nitrido)-(2,2':6',2''-terpyridine)-osmium(1+)

Central atom:

Attached groups:

N (nitrido; ≡N)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^VIE¹⁸B⁸Z⁰X⁵L³»^⊕

[MLXZ]𝘲 class:

[MX₅L₃]⁺

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

mer,cis–[Os(Cl)₂(NH₃)(Tpm-κ³N)]⊕

Formula Unicode styled:

mer,cis–[Os(Cl)₂(NH₃)(Tpm-κ³N)]⊕

Compound name(s):

Ammonia-dichloro-(tris(1-pyrazolyl)methane)-osmium(1+)

Central atom:

Attached groups:

Tpm (tris(pyrazolyl)methane-κ³N)

NH₃ (ammine)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V³C⁶O^IIIE¹⁷B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

mer,cis–[Os(Cl)₂(NCMe)(Terpy-κ³N)]⊕

Formula Unicode styled:

mer,cis–[Os(Cl)₂(NCMe)(Terpy-κ³N)]⊕

Compound name(s):

Acetonitrile-dichloro-(2,2':6',2''-terpyridyl)-osmium(1+)

Central atom:

Attached groups:

NCMe (acetonitrile)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V³C⁶O^IIIE¹⁷B⁶Z⁰X²L⁴»^⊕

[MLXZ]𝘲 class:

[MX₂L₄]⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

mer,cis–[Os(η²-H₂)(O₂CMe)(PPh₃)₃]⊕

Formula Unicode styled:

mer,cis–[Os(η²-H₂)(O₂CMe)(PPh₃)₃]⊕

Compound name(s):

(Acetato-O,O')-dihydrogen-tris(triphenylphosphine)-osmium(1+)

Central atom:

PPh₃ (triphenylphosphane)

Attached groups:

H₂ (η²-dihydrogen)

O₂CMe (acetato-κ²O)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X¹L⁵»^⊕

[MLXZ]𝘲 class:

[MX₁L₅]⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

mer,cis–[Os(SnCl₃)(CO)(PPh₃)₂(Dmdtc)]

Formula Unicode styled:

mer,cis–[Os(SnCl₃)(CO)(PPh₃)₂(Dmdtc)]

Compound name(s):

Carbonyl-trichlorotin-(N,N-dimethyldithiocarbamato-S,S')-bis(triphenylphosphine)-osmium

Central atom:

PPh₃ (triphenylphosphane)

Attached groups:

SnCl₃ (trichlorostannyl)

CO (carbonyl)

Dmdtc (dimethyldithiocarbamato-κ²S)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

mer,cis–[Os(OH₂)(Bpy)(Terpy-κ³N)]²⊕

Formula Unicode styled:

mer,cis–[Os(OH₂)(Bpy)(Terpy-κ³N)]²⊕

Compound name(s):

Aqua-(2,2'-bipyridyl)-(2,2''-terpyridyl)-osmium(2+)

Central atom:

Attached groups:

OH₂ (aqua)

Bpy (bipyridine)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X⁰L⁶»^2⊕

[MLXZ]𝘲 class:

[ML₆]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

mer–[Os(Cl)₃(Tp-κ³N)]⊖

Formula Unicode styled:

mer–[Os(Cl)₃(Tp-κ³N)]⊖

Compound name(s):

(hydrogen tris(1-pyrazolyl)borato-N,N',N'')-trichloro-osmium(1-)

Central atom:

Attached groups:

Tp (hydrotris(pyrazolyl)borato-κ³N)

Charge on central atom:

-1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V³C⁶O^IIIE¹⁷B⁶Z⁰X⁴L²»^⊖

[MLXZ]𝘲 class:

[MX₄L₂]^-

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

mer–[Os(Cl)₂(NO)(Tp-κ³N)]

Formula Unicode styled:

mer–[Os(Cl)₂(NO)(Tp-κ³N)]

Compound name(s):

Dichloro-(hydrogen tris(pyrazolylborato))-nitrosyl-osmium

Central atom:

Attached groups:

Tp (hydrotris(pyrazolyl)borato-κ³N)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^IIE¹⁸B⁸X⁴L³Z¹»

[MLXZ]𝘲 class:

[MX₄L₃Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

mer–[Os(Cl)(SC₆F₅)(N₂)(PMe₂Ph)₃]

Formula Unicode styled:

mer–[Os(Cl)(SC₆F₅)(N₂)(PMe₂Ph)₃]

Compound name(s):

Chloro-dinitrogen-pentafluorophenylthio-tris(dimethylphenylphosphine)-osmium

Central atom:

Attached groups:

SC₆F₅ (pentafluorothiophenyl)

N₂ (dinitrogen)

PMe₂Ph (dimethylphenylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

mer–[Os(Cl)(SO₃CF₃-κO)(N)(Terpy-κ³N)]⊕

Formula Unicode styled:

mer–[Os(Cl)(SO₃CF₃-κO)(N)(Terpy-κ³N)]⊕

Compound name(s):

Chloro-nitrido-(trifluoromethylsulfonyl-O) (2,2':6',2''-terpyridine-N,N',N'')-osmium(1+)

Central atom:

Attached groups:

OSO₂CF₃ (trifluoromethanesulfonato-κO)

N (nitrido; ≡N)

Charge on central atom:

1

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (VI)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^VIE¹⁸B⁸Z⁰X⁵L³»^⊕

[MLXZ]𝘲 class:

[MX₅L₃]⁺

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

mer–[Os(Br)₃(Dmso-κO)(SEt₂)(NO)]

Formula Unicode styled:

mer–[Os(Br)₃(Dmso-κO)(SEt₂)(NO)]

Compound name(s):

Tribromo-nitrosyl-diethylsulfido-(diethylsulfoxide-O)-osmium

Central atom:

Dmso (dimethylsulfoxide-κO)

Attached groups:

Br (bromo)

SEt₂ (diethylthioether)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V⁶C⁶O^IIE¹⁸B⁸X⁴L³Z¹»

[MLXZ]𝘲 class:

[MX₄L₃Z₁]

MLXZ class (ENC, equivalent neutral class):

MX₆L₂

mer–[Os(Br){Re(CO)₅}(CO)₃(PMe₃)]

Formula Unicode styled:

mer–[Os(Br){Re(CO)₅}(CO)₃(PMe₃)]

Compound name(s):

Pentacarbonyl-(bromo-tricarbonyl-trimethylphosphine-osmium)-rhenium

Central atom:

Re(CO)₅ (pentacarbonylrhenium)

Attached groups:

Br (bromo)

CO (carbonyl)

PMe₃ (trimethylphosphane)

Charge on central atom:

0

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

ON: (O)

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

Summary of calculated classifications:

Os«V²C⁶O^OE¹⁸B⁶Z⁰X²L⁴»

[MLXZ]𝘲 class:

[MX₂L₄]

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

fac–[Os(H)(η²-H₂)(PPrⁱ₃)([9]aneN₃-κ³N)]²⊕

Formula Unicode styled:

fac–[Os(H)(η²-H₂)(PPrⁱ₃)([9]aneN₃-κ³N)]²⊕

Compound name(s):

Dihydrido-(dihydrogen-H,H')-(1,4,7-triazacyclononane-N,N',N'')-(triisopropylphosphine)-osmium(2+)

Central atom:

PPrⁱ₃ (triisopropylphosphane)

Attached groups:

H (hydrido)

H₂ (η²-dihydrogen)

[9]aneN₃ (1,4,7-triazacyclononane-κ³N)

Charge on central atom:

2

Compound type:

Valence Number (VN) = 𝘹 + 2𝘻 :

Oxidation Number (ON) (Roman numerals):

Coordination Number (CN, sum of attached group denticities):

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: