trans–[Re(H)₂(PMe₂Ph)₂(Cp*)]

Formula Unicode styled:

Compound name(s):

Dihydrido-(eta-pentamethyl-cyclopentadienyl)-bis(dimethylphenylphosphine)-rhenium

Central atom:

Rhenium

Charge on formula unit (QN):

Attached groups:

H (hydrido)

PMe₂Ph (dimethylphenylphosphane)

Cp* (η⁵-pentamethylcyclopentadienyl)

Compound type:

Molecular

DOI link to literature report:

10.1016/0022-328X(89)87051-2

Crystal data CSD link:

sawnuz

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Coordination Number (CN, sum of attached group denticities):

CN: 7

Oxidation Number (ON) (Roman numerals):

ON: (III)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[MX₃L₄]

MLXZ class (ENC, equivalent neutral class):

MX₃L₄

Summary of calculated classifications:

Re«V³C⁷O^IIIE¹⁸B⁷Z⁰X³L⁴»

Geometry:

7-coordinate: ③-●-4 piano stool

Isomer label:

trans

𝘥-electron configuration = 𝘮 – VN:

d⁴

𝘥-electron configuration = 𝘮 – ON:

d⁴

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d⁴

Attached atoms:

C₅H₂P₂

Phase:

Solid

InChIKey (see www.inchi-trust.org):

VAAJDOSLFQOCFJ-UHFFFAOYSA-N