trans–[Ir(O₂CCF₃-κO)₂(PPh₃)₂(NO)]

Formula Unicode styled: 
trans–[Ir(O₂CCF₃-κO)₂(PPh₃)₂(NO)]
Compound name(s): 
Nitrosyl-bis(trifluoroacetato-O)-bis(triphenylphosphine)-iridium
Central atom: 
Iridium
Charge on formula unit (QN): 
0
Attached groups: 
O₂CCF₃ (trifluoroacetato-κO)
PPh₃ (triphenylphosphane)
NO (nitrosyl, linear)
Compound type: 
Molecular
DOI link to literature report: 
10.1039/dt9850000611
Crystal data CSD link: 
caswuo10
Crystal data ICSD link: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 5
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (I)
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 18
Bond number (BN) = 𝘹 + 𝘭 + 𝘻: 
7
[MLXZ]𝘲 class: 
[MX3L3Z1]
MLXZ class (ENC, equivalent neutral class): 
MX5L2
Summary of calculated classifications: 
Ir«V5C5OIE18B7X3L3Z1»
Geometry: 
5-coordinate: trigonal bipyramid (TBPY-5)
Isomer label: 
trans
𝘥-electron configuration = 𝘮 – VN: 
d4
𝘥-electron configuration = 𝘮 – ON: 
d8
𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲: 
d4
Attached atoms: 
N1O2P2
Phase: 
Solid
InChIKey (see www.inchi-trust.org): 
RSHOWDAZAATEOG-UHFFFAOYSA-L