Formula Unicode styled:
[Ge(Cl)(15-crown-5-κ³O)]⊕
Compound name(s):
(15-crown-5)-chloro-germanium(1+)
Central atom:
Charge on formula unit (QN):
1+
Attached groups:
Compound type:
Notes:
From the publication: "The adoption of a folded conformation by the [15]crown-5 ligand implies that the GeCl fragment is too large to fit into the cavity of the crown ether and that the germanium center possesses a stereochemically active lone pair of electrons".
DOI link to literature report:
Crystal data CSD link:
Crystal data ICSD link:
Valence Number (VN) = 𝘹 + 2𝘻 :
Coordination Number (CN, sum of attached group denticities):
Oxidation Number (ON) (Roman numerals):
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:
Bond number (BN) = 𝘹 + 𝘭 + 𝘻:
4
[MLXZ]𝘲 class:
[MX1L3]+
MLXZ class (ENC, equivalent neutral class):
MX2L2
Summary of calculated classifications:
Ge«V2C4OIIE10B4Z0X1L3»⊕
𝘥-electron configuration = 𝘮 – VN:
𝘥-electron configuration = 𝘮 – ON:
𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:
Attached atoms:
Cl1O3
Phase: