cis–[Mn{Mn(CO)₅}{C(OMe)Ph}(CO)₄]

Formula Unicode styled:

Compound name(s):

Nonacarbonyl-(phenyl(methoxy)carbene)-di-manganese

Central atom:

Manganese

Charge on formula unit (QN):

Attached groups:

Mn(CO)₅ (pentacarbonylmanganese)

C(OMe)Ph (methoxyphenylcarbene)

CO (carbonyl)

Compound type:

Molecular

DOI link to literature report:

10.1002/cber.19721050417

Crystal data CSD link:

npmcmn

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Coordination Number (CN, sum of attached group denticities):

CN: 6

Oxidation Number (ON) (Roman numerals):

ON: (O)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[MX₁L₅]

MLXZ class (ENC, equivalent neutral class):

MX₁L₅

Summary of calculated classifications:

Mn«V¹C⁶O^OE¹⁸B⁶Z⁰X¹L⁵»

Geometry:

6-coordinate: octahedron (OC-6)

Isomer label:

cis

𝘥-electron configuration = 𝘮 – VN:

d⁶

𝘥-electron configuration = 𝘮 – ON:

d⁷

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d⁶

Attached atoms:

C₅Mn₁

Phase:

Solid

InChIKey (see www.inchi-trust.org):

WVNSKHVHHQQYAM-UHFFFAOYSA-N