trans–[Os(η²-H₂)(NCMe)(Dppe-κ²P)₂]²⊕

Formula Unicode styled:

Compound name(s):

Acetonitrile-dihydrogen-bis(1,2-bis(diphenylphosphino)ethane)-osmium(2+)

Central atom:

Osmium

Charge on formula unit (QN):

Attached groups:

H₂ (η²-dihydrogen)

NCMe (acetonitrile)

Dppe (1,2-bis-(diphenylphosphino)ethane-κ²P)

Compound type:

Molecular

DOI link to literature report:

10.1021/om960113k

Crystal data CSD link:

tepzet

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Coordination Number (CN, sum of attached group denticities):

CN: 6

Oxidation Number (ON) (Roman numerals):

ON: (II)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[ML₆]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₂L₄

Summary of calculated classifications:

Os«V²C⁶O^IIE¹⁸B⁶Z⁰X⁰L⁶»^2⊕

Geometry:

6-coordinate: octahedron (OC-6)

Isomer label:

trans

𝘥-electron configuration = 𝘮 – VN:

d⁶

𝘥-electron configuration = 𝘮 – ON:

d⁶

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d⁶

Attached atoms:

H₁N₁P₄

Phase:

Solid

InChIKey (see www.inchi-trust.org):

DWFMEZSAGZTXNX-UHFFFAOYSA-N