cis,trans–[Os(SiCl₃)(PPh₃)₂(Dmdtc)]

Formula Unicode styled:

Compound name(s):

Carbonyl-(dimethyldithiocarbamato-S,S')-(trichlorosilyl)-bis(triphenylphosphine)-osmium

Central atom:

Osmium

Charge on formula unit (QN):

Attached groups:

SiCl₃ (trichlorosilyl)

PPh₃ (triphenylphosphane)

Dmdtc (dimethyldithiocarbamato-κ²S)

Compound type:

Molecular

DOI link to literature report:

10.1016/j.jorganchem.2005.12.072

Crystal data CSD link:

nekgoa

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 2

Coordination Number (CN, sum of attached group denticities):

CN: 5

Oxidation Number (ON) (Roman numerals):

ON: (II)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 16

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[MX₂L₃]

MLXZ class (ENC, equivalent neutral class):

MX₂L₃

Summary of calculated classifications:

Os«V²C⁵O^IIE¹⁶B⁵Z⁰X²L³»

Geometry:

6-coordinate: octahedron (OC-6)

Isomer label:

cis,trans

𝘥-electron configuration = 𝘮 – VN:

d⁶

𝘥-electron configuration = 𝘮 – ON:

d⁶

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d⁶

Attached atoms:

P₂S₂Si₁

Phase:

Solid

InChIKey (see www.inchi-trust.org):

UOADFBBPVGMRFD-UHFFFAOYSA-N