mer,cis–[Cr(OH₂)(Acac)(Terpy-κ³N)]²⊕

Formula Unicode styled:

Compound name(s):

(Acetylacetonato)-aqua-(2,2':6',2''-terpyridine)-chromium(2+)

Central atom:

Chromium

Charge on formula unit (QN):

Attached groups:

OH₂ (aqua)

Acac (acetylacetonato)

Terpy (terpyridine-κ³N)

Compound type:

Molecular

DOI link to literature report:

10.1107/S1600536807056176

Crystal data CSD link:

hiqmaw

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 3

Coordination Number (CN, sum of attached group denticities):

CN: 6

Oxidation Number (ON) (Roman numerals):

ON: (III)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 15

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[MX₁L₅]²⁺

MLXZ class (ENC, equivalent neutral class):

MX₃L₃

Summary of calculated classifications:

Cr«V³C⁶O^IIIE¹⁵B⁶Z⁰X¹L⁵»^2⊕

Geometry:

6-coordinate: octahedron (OC-6)

Isomer label:

mer,cis

𝘥-electron configuration = 𝘮 – VN:

d³

𝘥-electron configuration = 𝘮 – ON:

d³

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d³

Attached atoms:

N₃O₃

Phase:

Solid

InChIKey (see www.inchi-trust.org):

ZRSLCMNRJWUHEC-UHFFFAOYSA-N