cis,cis,trans–[W(SPh)₂(O)(Phen)]

Formula Unicode styled: 
cis,cis,trans–[W(SPh)₂(O)(Phen)]
Compound name(s): 
Dioxo-(1,10-phenanthroline)-bis(phenylthiolato)-tungsten
Central atom: 
Tungsten
Charge on formula unit (QN): 
0
Attached groups: 
SPh (phenylthio)
O (oxo ⭀O X₂L)
Phen (phenanthroline)
Compound type: 
Molecular
DOI link to literature report: 
10.1021/ja00100a049
Crystal data CSD link: 
heywaj
Crystal data ICSD link: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 4
Coordination Number (CN, sum of attached group denticities): 
CN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 16
Bond number (BN) = 𝘹 + 𝘭 + 𝘻: 
7
[MLXZ]𝘲 class: 
[MX4L3]
MLXZ class (ENC, equivalent neutral class): 
MX4L3
Summary of calculated classifications: 
W«V4C5OIVE16B7Z0X4L3»
Geometry: 
6-coordinate: octahedron (OC-6)
Isomer label: 
cis,cis,trans
𝘥-electron configuration = 𝘮 – VN: 
d2
𝘥-electron configuration = 𝘮 – ON: 
d2
𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲: 
d2
Attached atoms: 
N2O1S2
Phase: 
Solid
InChIKey (see www.inchi-trust.org): 
OTEZEKCUNQJTTN-UHFFFAOYSA-L