cis–[Cr(Cl)₂([14]aneS₄-κ⁴S)]⊕

Formula Unicode styled: 
cis–[Cr(Cl)₂([14]aneS₄-κ⁴S)]⊕
Compound name(s): 
Dichloro-(1,4,8,11-tetrathiacyclotetradecane)-chromium(1+)
Central atom: 
Chromium
Charge on formula unit (QN): 
1+
Attached groups: 
Cl (chloro)
[14]aneS₄ (1,4,8,11-tetrathiocyclotetradecane-κ⁴S)
Compound type: 
Molecular
DOI link to literature report: 
10.1021/ic00105a061
Crystal data CSD link: 
yikvuj
Crystal data ICSD link: 
Valence Number (VN) = 𝘹 + 2𝘻 : 
VN: 3
Coordination Number (CN, sum of attached group denticities): 
CN: 6
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭: 
EN: 15
Bond number (BN) = 𝘹 + 𝘭 + 𝘻: 
6
[MLXZ]𝘲 class: 
[MX2L4]+
MLXZ class (ENC, equivalent neutral class): 
MX3L3
Summary of calculated classifications: 
Cr«V3C6OIIIE15B6Z0X2L4»⊕
Geometry: 
6-coordinate: octahedron (OC-6)
Isomer label: 
cis
𝘥-electron configuration = 𝘮 – VN: 
d3
𝘥-electron configuration = 𝘮 – ON: 
d3
𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲: 
d3
Attached atoms: 
Cl2S4
Phase: 
Solid
InChIKey (see www.inchi-trust.org): 
XSOOJLOSKNGZER-UHFFFAOYSA-L