axial–[Co(SnCl₃)₂(CO)₃]⊖

Formula Unicode styled:

Compound name(s):

(tricarbonyl-bis(trichloro-tin)-cobalt(1-)

Central atom:

Cobalt

Charge on formula unit (QN):

1–

Attached groups:

SnCl₃ (trichlorostannyl)

CO (carbonyl)

Compound type:

Molecular

DOI link to literature report:

10.1016/0022-328X(90)85383-A

Crystal data CSD link:

vepwoc

Crystal data ICSD link:

Valence Number (VN) = 𝘹 + 2𝘻 :

VN: 1

Coordination Number (CN, sum of attached group denticities):

CN: 5

Oxidation Number (ON) (Roman numerals):

ON: (-III)

Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:

EN: 18

Bond number (BN) = 𝘹 + 𝘭 + 𝘻:

[MLXZ]𝘲 class:

[MX₂L₃]^-

MLXZ class (ENC, equivalent neutral class):

MX₁L₄

Summary of calculated classifications:

Co«V¹C⁵O^-IIIE¹⁸B⁵Z⁰X²L³»^⊖

Geometry:

5-coordinate: trigonal bipyramid (TBPY-5)

Isomer label:

axial

𝘥-electron configuration = 𝘮 – VN:

d⁸

𝘥-electron configuration = 𝘮 – ON:

d¹⁰

𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:

d⁸

Attached atoms:

C₃Sn₂

Phase:

Solid

InChIKey (see www.inchi-trust.org):

ZUENCYYDJJIPRB-UHFFFAOYSA-H