Formula Unicode styled:
[S(Ph){Mn(CO)₂Cp}₂]⊕
Compound name(s):
bis(dicarbonyl-η⁵₋cyclopentadienyl-manganese)-phenyl-sulfur(1+)
Central atom:
Charge on formula unit (QN):
1+
Attached groups:
Compound type:
Notes:
The two metal groups each receive two electrons from the sulfur in σ bonds (the metal groups are Z). The sulfur receives two electrons from the two metal groups that act together as a set classified as an L π function. This takes the EN for sulfur to 8.
DOI link to literature report:
Crystal data CSD link:
Crystal data ICSD link:
Valence Number (VN) = 𝘹 + 2𝘻 :
Coordination Number (CN, sum of attached group denticities):
Oxidation Number (ON) (Roman numerals):
Electron Number (EN) = 𝘮 + 𝘹 +2𝘭:
Bond number (BN) = 𝘹 + 𝘭 + 𝘻:
4
[MLXZ]𝘲 class:
[MX1L1Z2]+
MLXZ class (ENC, equivalent neutral class):
MX2Z2
Summary of calculated classifications:
S«V6C4OOE8B4X1L1Z2»⊕
𝘥-electron configuration = 𝘮 – VN:
𝘥-electron configuration = 𝘮 – ON:
𝘥-electron configuration = 𝘮 – VN – 𝘲 from [MLXZ]𝘲:
Attached atoms:
C1Mn2
Phase:
InChIKey (see www.inchi-trust.org):
CXUQZPCLUBNOOK-UHFFFAOYSA-N